Petrogenesis and Tectonic Implications of A-type Granites in Zhaheba in the East Junggar Region of Xinjiang, China: Evidence from Geochronology, Geochemistry and Sr-Nd Isotopic Compositions

The magma source, petrogenesis, tectonic setting and geochronology of the late Paleozoic A-type granites widely exposed in the Zhaheba area, East Junggar, have thus far not been well-constrained. A better understanding of these issues will help to reveal the magmatic processes and continental growth of Central Asia. The A-type granites in Zhaheba include the Ashutasi alkaline granites and the Yuyitasi syenogranites, which were emplaced at 321.5 ± 4.8 Ma and 321.7 ± 0.6 Ma, respectively. The major rock-forming minerals are orthoclase, perthite, arfvedsonite and quartz, which exhibit the following principal geochemical characteristics of A2-type granites. (1) Their REE distribution curves each exhibit a ‘V’-shaped pattern and a marked depletion in Eu. They are rich in large-ion lithophile elements Rb, Th and U as well as high-field-strength elements Nb, Ta, Zr and Hf, but significantly depleted in Ba, Sr, P and Ti. (2) Their (87Sr/86Sr)i values (0.7021–0.7041), εNd(t) values (4.57–5.16) and REE distribution patterns are in basic agreement with those of the Kalamaili A-type granite belt in East Junggar. The TDM2 values of the alkaline granites and syenogranites range from 661 to 709 Ma. The A-type granites may be the products of upwelling asthenosphere-triggered partial melting of immature lower crust. The alkaline granites were late-stage products of crystallization and differentiation. Compared to the syenogranites, the alkaline granites are significantly lower in K2O, Na2O, Al2O3, FeO, MgO and CaO, but significantly higher in incompatible elements (e.g., SiO2, Rb, and Sr). The magmatic crystallization temperatures of the syenogranites and alkaline granites are 874°C and 819°C, respectively. As their age gradually decreases (peak ages: 322 Ma and 307 Ma, respectively), there is a gradual decrease in the TDM2 of the A-type granites and a gradual increase in the εNd(t) value from the Ulungur belt to the Kalamaili belt in East Junggar. The study of A-type granites is therefore one of the keys to understanding the laws and mechanisms of crustal accretion during the Phanerozoic period, as well as also being of great significance for understanding the Paleozoic accretion.     

西藏南冈底斯叶巴火山弧的构造-地层属性及其演化

南冈底斯岩浆岩带出露的一套早—中侏罗世火山-沉积建造经历了多期构造变形,致使这套火山-沉积层序发生了强烈的面理置换,形成了典型的构造-岩石地层。依据造山带地层划分方法将叶巴火山弧厘定为叶巴岩群,并根据内部岩性组合特征和构造变形特征将其进一步划分为邦堆岩组、叶巴岩组、甲玛岩组。运用构造解析原理划分了3期构造变形事件。第一期构造变形为脆-韧性剪切变形,剪切方式为纯剪占优的一般剪切变形,透入性面理S₁普遍置换层理S₀(S₁∥S₀),伴生倾伏向85°~100°陡倾的拉伸线理,运动学指示顶面朝西运动,存在左行和右行两个方向的剪切旋转碎斑共存的现象;EBSD实验结果显示变形的温度≤380 ℃,石英颗粒细粒化明显,重结晶方式为亚颗粒旋转重结晶;⁴⁰Ar-³⁹Ar年代学结果表明该期构造变形时代约为79 Ma,其可能代表新特提斯洋板片低角度(平板式)俯冲引起在弧后挤压背景下形成的挤出构造。第二期构造变形表现为S₁面理发生纵弯褶皱变形形成的轴面劈理S₂,轴面产状倾向北或南,倾角40°~70°,枢纽向西或北西西倾伏;结合区域地质演化特征,认为其可能是在晚白垩世(79~68 Ma)南北向持续的挤压应力条件下,南冈底斯弧后盆地整体向上挤出,引发上地壳缩短、加厚进而导致褶皱作用的发生。第三期主要为浅层次膝折构造和近东西向正断层,最大主压应力方向为铅直向,最小主压应力方向(伸展方向)为近南北向;结合区域构造演化特征,认为该期变形可能代表渐新世末—中新世初期(23.74~21.1 Ma),印度岩石圈或青藏高原岩石圈或两者组合的拆沉作用引起冈底斯岩基隆升(主要动力学机制)和GCT活动并共同作用导致近南北向伸展滑覆事件发生。     

稀有金属矿物溶解度对花岗伟晶岩成矿作用的制约

花岗伟晶岩型矿床是稀有金属矿床重要的类型之一。在花岗伟晶岩中,稀有金属元素Li、Be、Nb和Ta主要以独立矿物的形式存在,前人对稀有金属独立矿物在硅酸盐熔体中的溶解度及其影响因素展开了系统研究。本文综合分析了已有的实验数据,其结果表明,影响稀有金属独立矿物溶解度最为重要的2个参数是温度(T)和铝饱和指数(ASI)。因此本文建立了稀有金属独立矿物,尤其是铌锰矿和钽锰矿溶解度,与温度(T)和铝饱和指数(ASI)之间的定量关系: lg [w(Li)/10^-6]=-0.37×[1 000/(T/K)]+4.56,R²=0.44 lg [w(BeO)/10^-6]=-4.21×[1 000/(T/K)]+6.86,R²=0.91 lg [K_sp(Nb)/(mg²·kg^-2)]=-(2.86±0.14)×ASI_(Mn+Li)-(4.95±0.31)×[1 000/(T/K)]+(4.20+0.28),R²=0.86 lg [K_sp(Ta)/(mg²·kg^-2)]=-(2.46±0.11)×ASI_(Mn+Li)-(4.86±0.30)×[1 000/(T/K)]+(4.00+0.30),R²=0.80 式中,温度T为热力学温度,ASI_(Mn+Li)(ASI=Al₂O₃/(CaO+Na₂O+K₂O+Li₂O+MnO),摩尔分数比)和T的适用范围分别为0.6~1.2和1 073~1 373 K的范围内。上述公式为估算硅酸盐熔体中稀有金属含量提供了便利,为量化花岗伟晶岩成矿模型提供了基础。 稀有金属独立矿物溶解度随温度降低和铝饱和指数的增加而急剧降低,因此,在岩浆演化过程中,由岩浆侵位、分离结晶以及流体作用等因素引起的岩浆温度降低和铝饱和指数的增加,是导致稀有金属独立矿物结晶的主要机制。     

基于机器学习模型的淮河流域中长期径流预报研究

准确可靠的中长期径流预报是支撑水资源科学调配、提高水资源利用效率的关键。本研究采用AdaBoost模型(AdB)、随机森林模型(RF)和支持向量机模型(SVM)进行淮河流域王家坝和蚌埠站当年11月至次年10月共12个月的中长期径流预报研究。采用置换准确度重要性度量法从130项气象-气候因子及前期降雨/流量构建的1 562个因子变量中筛选出影响各月径流的关键因子,构建了基于AdB、RF和SVM模型的各月径流预报模型,模型参数采用随机搜索技术并结合交叉验证方式确定。采用变幅误差合格率和等级(五级)预报合格率指标对模型的预报精度进行了评估。变幅误差合格率指标表明,王家坝12个月的平均合格率分别为99.8%(AdB)、96.6%(RF)和95.9%(SVM),蚌埠站分别为100%(AdB)、94.8%(RF)和93.8%(SVM);等级预报合格率指标表明,王家坝12个月的平均合格率分别为79.0%(AdB)、76.4%(RF)和79.9%(SVM),蚌埠站分别为81.0%(AdB)、75.6%(RF)和76.6%(SVM)。模型均具有较好的预报效果,但RF和SVM模型对于高流量值的预报存在偏低现象,AdB模型整体上优于RF和SVM模型。     

不同氧化还原条件下铅锌矿尾砂中重金属元素活化迁移规律

以广西大厂镇鲁塘铅锌矿尾砂为研究对象,通过淋滤实验研究了不同氧化还原条件下尾砂中Cu、Cd、Zn、Pb和As等元素的活化和迁移规律。结果表明：经高浓度氧化、高浓度还原条件处理的尾矿表现为pH<7的酸性环境,经低浓度氧化环境条件处理的尾砂呈现pH>7的弱酸性至弱碱性环境;尾砂中Cu、Cd元素活化迁移受pH值的影响明显,即高浓度还原和高浓度氧化条件可以促进Cu和Cd元素的迁移,酸性条件对Cu和Cd元素的迁移起到促进作用;Zn与Cd元素存在竞争吸附关系,但二者仍有明显差别;Pb和As元素受到还原条件的影响,能有效促进Pb和As元素的释放迁移。在淋滤实验前期,铅锌矿的表面阻力较小,由于环境酸碱性的改变,初始尾砂对重金属元素的吸附位能发生变化,重金属元素初期迁移能力得到加强;淋滤后期,矿物颗粒表面由于发生氧化还原反应,促使颗粒表面的阻力增加,重金属元素的溶出量减少,迁移能力受到抑制。     

Fractional derivative modelling for rheological consolidation of multilayered soil under time-dependent loadings and continuous permeable boundary conditions

Acta Geotechnica - This paper investigates the one-dimensional rheological consolidation problem of multilayered soils subjected to different time-dependent loadings and continuous permeable...     

基于InSAR技术的川西高山峡谷区地质灾害早期识别研究——以小金川河流域为例

采用短基线集时序干涉测量(small baseline subset InSAR,SBAS-InSAR)技术,利用多时相合成孔径雷达数据,对川西高山峡谷区开展地表多时相、长时序形变监测与地质灾害隐患早期识别研究。介绍了时序InSAR方法原理,梳理了数据处理流程,分析了小金川河流域雷达可视性,利用2018-11—2019-12共26期的Sentinel-1A历史存档数据开展了流域内地表形变监测,结果表明: 流域内雷达视线方向的年平均形变速率为-51.12~75.28 mm/a; 依据形变异常分布规律,共判译出4处形变异常区与11处潜在地质灾害隐患点,其中6处隐患点为已知地质灾害点,其余5处隐患点尚不为人知。以隐患点P1(阿娘寨滑坡)为典型案例,开展了长时序监测分析与验证,评估利用InSAR技术开展地质灾害隐患早期识别的可靠性,证明了SBAS-InSAR技术在地质灾害早期识别中的优势及有效性,其技术成果在川西高山峡谷区具有大范围推广应用的潜力。     

Tectonic evolution and geodynamics of the Neo-Tethys Ocean

The Neo-Tethys Ocean was an eastward-gaping triangular oceanic embayment between Laurasia to the north and Gondwana to the south.The Neo-Tethys Ocean was initiated from the Early Permian with mircoblocks rifted from the northern margin of Gondwana.As the microblocks drifted northwards,the Neo-Tethys Ocean was expanded.Most of these microblocks collided with the Eurasia continent in the Late Triassic,leading to the final closure of the Paleo-Tethys Ocean,followed by oceanic subduction of the Neo-Tethys oceanic slab beneath the newly formed southern margin of the Eurasia continent.As the splitting of Gondwana continued,African-Arabian,Indian and Australian continents were separated from Gondwana and moved northwards at different rates.Collision of these blocks with the Eurasia continent occurred at different time during the Cenozoic,resulting in the closure of the Neo-Tethys Ocean and building of the most significant Alps-Zagros-Himalaya orogenic belt on Earth.The tectonic evolution of the Neo-Tethys Ocean shows different characteristics from west to east:Multi-oceanic basins expansion,bidirectional subduction and microblocks collision dominate in the Mediterranean region;northward oceanic subduction and diachronous continental collision along the Zagros suture occur in the Middle East;the Tibet and Southeast Asia are characterized by multi-block riftings from Gondwana and multi-stage collisions with the Eurasia continent.The negative buoyancy of subducting oceanic slabs can be considered as the main engine for northward drifting of Gondwana-derived blocks and subduction of the Neo-Tethys Ocean.Meanwhile,mantle convection and counterclockwise rotation of Gondwana-derived blocks and the Gondwana continent around an Euler pole in West Africa in non-free boundary conditions also controlled the evolution of the Neo-Tethys Ocean.     

西藏甲玛矿床磁黄铁矿微量元素特征及其与金富集沉淀的耦合机制

【研究目的】甲玛矿床是西藏冈底斯成矿带最重要的斑岩成矿系统之一,具有斑岩、矽卡岩、角岩、脉状金矿四位一体矿体结构,形成了丰富的矿物种类和多样的金属矿化。其中,磁黄铁矿作为重要的金属矿物之一,其矿物地球化学特征以及与金矿化的耦合关系一直不明确。【研究方法】此次,以甲玛斑岩成矿系统外围和远端的不同产状的磁黄铁矿为研究对象,基于详细的野外地质调查和镜下鉴定,通过激光剥蚀电感耦合等离子质谱分析方法（LAICP-MS）对不同产状的磁黄铁矿开展测点分析和扫描分析,详细揭示其地球化学特征。【研究结果】结果显示,甲玛矿床磁黄铁矿主要富集Co、Ni、Cu、Zn、Ge、Se,弱富集Pb、Bi、Sb、Te、Ag、As,而Mo、Cd、In、Sn、Ba、W、Au、Tl、Th、U等元素含量较低。其中,矽卡岩中的磁黄铁矿具有较高的Co/Ni比值,能有效揭示其岩浆热液成因,而角岩中磁黄铁矿可能继承了一定的沉积特征。【结论】甲玛矿区磁黄铁矿的Cu、Zn、Pb含量变化特征与矿床空间矿化规律一致。矽卡岩中的块状磁黄铁矿与金矿化关系密切,金主要呈他形、不规则的独立金矿物产于磁黄铁矿的孔隙和粒间。同时,金的富集和沉淀可能与富铋的熔体有关。创新点：磁黄铁矿是甲玛超大型斑岩成矿系统中典型的金属矿物之一,其微区原位分析清晰揭示其微量元素地球化学特征和矿物成因,同时,证实矽卡岩中磁黄铁矿的高品位金与成矿流体中的富铋熔体有关。     

南太行邯邢地区白涧矽卡岩型铁矿中磁铁矿与赤铁矿交代现象对矿床成因的启示

对邯邢地区白涧铁矿中磁铁矿与赤铁矿进行成因矿物学研究,精细刻画了铁的成矿过程。在岩相学观察过程中作者发现该矿床中存在2个期次的赤铁矿,其分别交代磁铁矿或被磁铁矿交代。根据磁铁矿和赤铁矿的交代关系,我们将赤铁矿划分为早、晚2个期次,并根据成矿流体的演化,将铁矿化过程划分为4个阶段。成矿流体从岩浆中分离并交代碳酸盐围岩形成矽卡岩,同时形成接触带矿(第1成矿期),随着接触带磁铁矿的形成,具有更高氧逸度的演化的流体沿着断裂带充填和交代碳酸盐地层形成早期赤铁矿(第2成矿期)。随着赤铁矿形成,氧逸度降低至磁铁矿-赤铁矿缓冲线之下,形成层间的磁铁矿(第3成矿期),SO42-转化成HS-,同时形成大量自由氧,导致成矿流体的氧逸度进一步升高,从而形成晚期赤铁矿(第4成矿期),伴随温度和氧逸度的进一步降低,成矿作用进入硫化物形成时期。整个成矿过程中氧逸度控制了成矿过程及其产物,对矽卡岩型铁矿的形成起到了主导作用。