Early Mesozoic Southward Subduction of the Eastern Mongol–Okhotsk Oceanic Plate: Evidence from Zircon U–Pb–Hf Isotopes and Whole‐rock Geochemistry of Triassic Granitic Rocks in the Mohe Area,NE China

In this paper, we present new U–Pb zircon ages, Hf isotope data and major and trace elements for Early Mesozoic granitic rocks in Mohe area in the Erguna Massif of northeast China to elucidate the southward subduction of the eastern Mongol–Okhotsk Oceanic plate in Early Mesozoic. Zircons from two representative intrusions, syenogranites and monzogranites, in the Mohe area are euhedral–subhedral in shape, display oscillatory growth zoning in cathodoluminescence (CL) images, and have Th/U ratios of 0.10–0.72, and in combination these features indicating that the zircons are of igneous origin. U–Pb zircon dating results demonstrate that the syenogranites formed at 245.1 ± 1.4 Ma and monzogranites formed at 212.2 ± 1.7 Ma. These granitic rocks are characterized by high SiO₂, Al₂O₃ and (Na₂O + K₂O), low TFeO, MgO, TiO₂ and P₂O₅ concentrations, belonging to the high‐K calc‐alkaline series. They are enriched in LREE and large ion lithophile elements (e.g., Rb, K, and Sr), depleted in HREE and high field strength elements (e.g., Nb, Ta, Th, and Ti), as well as very weak negative Eu anomalies (Eu/Eu* = 0.48 ~ 1.01). Their zircon εHf(t) values range from −7.9 to −2.0 and range from 0.20 to 0.49, in response to their two‐stage Hf model ages (T_DM2) range from 1.40 Ga to 1.77 Ga range from 0.94 Ga to 1.24 Ga, respectively, indicating that primary magmas of syenogranites were derived from partial melting of newly accreted juvenile crustal material that formed from the enriched mantle during the Mesoproterozoic, monzogranites are generated by partial melting of newly accreted juvenile crustal material that formed from the depleted mantle during the Meso‐ to Neoproterozoic. We conclude, therefore, that the early Mesozoic granitic rocks of the Mohe area are associated with the continuous southward subduction of the Mongol–Okhotsk oceanic plate rather than the Paleo‐Asian and circum‐Pacific tectonic regimes.     

桂西地区二叠系合山组铝土岩的沉积环境*

桂西地区二叠系合山组铝土岩的沉积环境存在海相、陆相之争。通过对桂西二叠系铝土岩的区域调查及钻孔样品微量元素地球化学数据的分析,认为桂西二叠系铝土岩产出于陆相环境。从铝土岩分布情况看,桂西二叠纪各孤立碳酸盐岩台地上均广泛分布铝土岩沉积,该区域产出特征证明矿层是在碳酸盐岩台地全部暴露地表的环境下形成的。从铝土岩层与下伏茅口组灰岩的接触关系来看,铝土岩层底部存在茅口组灰岩砾石,在部分剖面尚见下伏茅口组灰岩中充填铝土岩等现象,说明铝土岩矿化过程直接于茅口组灰岩的古喀斯特面上完成。此外,在矿层中发现古植物根茎化石也是铝土岩形成于陆相环境的有力证据。从微量元素地球化学结果来看,来自铝土岩层样品的硼含量均小于10×10^-6,Sr/Ba值范围为0.29~1.61,平均值为0.92,Rb/K值范围为0.0011~0.0025,平均值为0.0017,以上指标结合V/Zr-Zr/Cu图解的判别,结果均指示铝土岩形成于陆相淡水环境。     

Characterization,dissolution and solubility of the hydroxypyromorphite–hydroxyapatite solid solution [(Pb<Subscript>x</Subscript>Ca<Subscript>1−x</Subscript>)<Subscript>5</Subscript>(PO<Subscript>4</Subscript>)<Subscript>3</Subscript>OH] at 25 °C and pH 2–9

Background

The interaction between Ca-HAP and Pb²⁺ solution can result in the formation of a hydroxyapatite–hydroxypyromorphite solid solution [(Pb_xCa_1?x)₅(PO₄)₃(OH)], which can greatly affect the transport and distribution of toxic Pb in water, rock and soil. Therefore, it’s necessary to know the physicochemical properties of (Pb_xCa_1?x)₅(PO₄)₃(OH), predominantly its thermodynamic solubility and stability in aqueous solution. Nevertheless, no experiment on the dissolution and related thermodynamic data has been reported.

Results

Dissolution of the hydroxypyromorphite–hydroxyapatite solid solution [(Pb_xCa_1?x)₅(PO₄)₃(OH)] in aqueous solution at 25 °C was experimentally studied. The aqueous concentrations were greatly affected by the Pb/(Pb + Ca) molar ratios (X_Pb) of the solids. For the solids with high X_Pb [(Pb_0.89Ca_0.11)₅(PO₄)₃OH], the aqueous Pb²⁺ concentrations increased rapidly with time and reached a peak value after 240–720 h dissolution, and then decreased gradually and reached a stable state after 5040 h dissolution. For the solids with low X_Pb (0.00–0.80), the aqueous Pb²⁺ concentrations increased quickly with time and reached a peak value after 1–12 h dissolution, and then decreased gradually and attained a stable state after 720–2160 h dissolution.

Conclusions

The dissolution process of the solids with high X_Pb (0.89–1.00) was different from that of the solids with low X_Pb (0.00–0.80). The average K _sp values were estimated to be 10^?80.77±0.20 (10^?80.57–10^?80.96) for hydroxypyromorphite [Pb₅(PO₄)₃OH] and 10^?58.38±0.07 (10^?58.31–10^?58.46) for calcium hydroxyapatite [Ca₅(PO₄)₃OH]. The Gibbs free energies of formation (ΔG _f ^o ) were determined to be ?3796.71 and ?6314.63 kJ/mol, respectively. The solubility decreased with the increasing Pb/(Pb + Ca) molar ratios (X_Pb) of (Pb_xCa_1?x)₅(PO₄)₃(OH). For the dissolution at 25 °C with an initial pH of 2.00, the experimental data plotted on the Lippmann diagram showed that the solid solution (Pb_xCa_1?x)₅(PO₄)₃(OH) dissolved stoichiometrically at the early stage of dissolution and moved gradually up to the Lippmann solutus curve and the saturation curve for Pb₅(PO₄)₃OH, and then the data points moved along the Lippmann solutus curve from right to left. The Pb-rich (Pb_xCa_1?x)₅(PO₄)₃(OH) was in equilibrium with the Ca-rich aqueous solution.

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Graphical abstractLippmann diagrams for dissolution of the hydroxypyromorphite–hydroxyapatite solid solution [(Pb_xCa_1?x)₅(PO₄)₃OH] at 25??C and an initial pH of 2.00.

     

淤泥质潮滩地貌演变中的水动力及生物过程研究进展

淤泥质潮滩对于海岸防护、增加土地资源、保持生物多样性等具有重要作用。从淤泥质潮滩演变的主要驱动因子——潮流、波浪、生物作用及地下过程四个方面回顾和总结了潮滩演变动力地貌过程的相关研究进展,提出应关注潮滩短期演变规律、波浪与浮泥作用机理、生物生长与潮滩演变定量关系,以及地下过程作用机理等。     

南海某导管架海洋平台倒塌分析

针对在役老龄导管架平台进行倒塌计算分析,确定极限承载力进而评估老龄导管架的安全裕度。采用非线性有限元方法,考虑平台的波流载荷及桩-土的非线性相互作用,利用SACS软件建立导管架整体三维有限元计算分析模型,并用逐步加载的方式,对南海某导管架平台进行了全过程非线性倒塌分析。计算分析表明,该导管架平台极限强度很高,具有较大的安全裕度;导管架倒塌过程呈逐步破坏形式,先是撑杆屈服,造成局部结构破坏,然后是钢桩发生屈服,降低结构承载力,最后节点逐步失效,造成结构倒塌。揭示了导管架平台结构失效倒塌的机理,给出了倒塌分析的可行方法和步骤。     

基于地理格网分级法提取的中国传统村落空间分布

中国传统村落真实地记录了建筑、民俗民风和较原始的民居空间形态,是千百年来人类与自然和谐共存的生活基础。随着城市化进程加快,传统村落的存续受到了很大的挑战,为了更好地保护利用传统村落,对其进行多视角的研究尤为重要,除了微观层面的具体保护措施外,还应加强宏观层面的空间分布研究。地理格网是表达复杂地理现象、综合分析自然与人文数据、模拟地理系统功能与行为的基本方法。本文从百度影像地图提取村落坐标,并截取遥感影像作为村落点数据的判断补充,在此基础上,运用地理格网的分级法,对国家公布的三批中国传统村落(2555个)数据进行空间格局分析,结果表明：这些村落主要分布在中国东南部,如落在一级格网Ⅰ18、Ⅰ19就分别有586、781个村落,占三批传统村落总数的96.6%。通过对二级和三级格网的村落分布离散性进行分析,使传统村落的空间分布数据结构更加系统和清晰有序,为合理构建其数据库提供了框架基础。     

格尔木河流域河水钾硼锂元素分布特征及富集规律

在柴达木格尔木河流域,随着内陆流域水系的产生与地表径流的消亡,从山区至盐湖区钾(K)硼(B)锂(Li)等有益元素的分布可以划分为淋溶-径流区、径流-蒸发区与溶滤-蒸发浓缩富集区3个具有显著特点的水文化学分带。河水中,K、B、Li含量随矿化度升高而升高,且呈正相关关系。在盐湖区,K、B、Li等资源性元素明显富集。研究发现,格尔木河东部主流(秀水河)是格尔木河水中B和Li的主要贡献者。     

曾昭璇先生对南海地理研究的重要贡献

曾昭璇先生是中国著名的地理学家,地貌学家和教育家.他在学术生涯的不同阶段对地貌学,自然地理学,历史地理学,人类地理学等学科领域均有积极的探索,他对南海地理问题的研究贯穿他的一生,为中国南海地理研究作出重要贡献.他深入研究南海海岸地貌,珊瑚礁地貌,主张采用"地形类型分析法"划分海岸类型,将中国海岸类型划分为山地港湾岸,台地岸与平原岸;他与梁景芬等合著《中国珊瑚礁地貌研究》,系统论述中国珊瑚礁探测史和石珊瑚的种属,生态,地貌特征与发育,并将中国珊瑚礁划分为四大区,六种地貌类型;他完善了珊瑚礁地貌土地名分类,根据《更路簿》划分南海珊瑚岛礁分布区,绘制珊瑚岛礁探测图;他利用历史文献资料考证"石塘"等南海诸岛古地名;他从地质学与地貌学角度论证南海诸岛与中国大陆的陆缘关系,还利用历史地理与地方志等资料佐证了南海诸岛自古以来就是中国的固有领土.     

上海中心城就业中心体系测度————基于手机信令数据的研究

利用手机信令数据识别上海市域内手机用户的工作地和居住地,获取就业者的通勤数据,测度上海中心城的就业中心体系.首先用就业者工作地数据生成就业密度分布图,基于中心城的就业密度识别就业中心.随后,用就业者工作地和居住地数据分别从就业密度和通勤联系两方面测度各中心的能级,分析各中心的腹地和势力范围.研究发现:① 上海中心城的就业中心呈主中心强大的弱多中心体系;② 就业密度越高的中心与其他地区的通勤联系一般也越强,但通勤联系在各中心间的差异更显著;③ 能级越高的中心腹地面积越大,但势力范围不一定越大;④ 相比于能级,职住功能混合度对职住平衡的影响更大;⑤缺少就业中心的地区势力范围呈交替状.本研究一定程度上能有助于解决既往就业中心体系研究因空间单元较大,缺少通勤数据在中心识别,通勤联系测度等方面受到的局限,希望能为构建上海中心城就业多中心体系提供帮助.