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Thermodynamic conditions of framework grain dissolution of clastic rocks and its application in Kela 2 gas field 总被引:2,自引:2,他引:2
LAI Xingyun YU Bingsong CHEN Junyuan CHEN Xiaolin LIU Jianqing MEI Mingxiang JING Weiguang & CHENG Suhua School of Earth Sciences Mineral Resources China University of Geosciences Beijing China Key Laboratory of Lithospheric Tectonics Deep-level Process Exploration of Ministry of Education Beijing China 《中国科学D辑(英文版)》2005,48(1):21-31
Feldspar and clastic debris are the most important constituent framework grains of sedimentary clastic rocks and their chemical dissolution plays an essential role in the formation and evolution of the secondary pore in the reservoir rocks. On the basis of thermodynamic phase equilibrium, this study investigates the chemical equilibrium relationships between fluid and various plagioclase and K-feldspar in diagenesis of the sediments, particularly, the impact of temperature and fluid compositions (pH, activity of K+, Na+, Ca2+ and so on) on precipitation and dissolution equilibria of feldspars. Feldspar is extremely easily dissolved in the acid pore water with a low salinity when temperature decreases. The dissolution of anorthite end-member of plagioclase is related to the Ca content of the mineral and the fluid, higher Ca either in the mineral or in the fluid, easier dissolution of the feldspar. Moreover, the dissolution of albite end-member of plagioclase is related to Na of both the mineral and fluid, 相似文献
294.
SHA Liqing ZHENG Zheng TANG Jianwei Wang Yinghong ZHANG Yiping CAO Min WANG Rui Liu Guangren WANG Yuesi SUN Yang 《中国科学D辑(英文版)》2005,48(Z1)
With the static opaque chamber and gas chromatography technique, from January 2003 to January 2004 soil respiration was investigated in a tropical seasonal rain forest in Xishuangbanna, SW China. In this study three treatments were applied, each with three replicates: A (bare soil), B (soil+litter), and C (soil+litter+seedling). The results showed that soil respiration varied seasonally, low from December 2003 to February 2004, and high from June to July 2004. The annual average values of CO2 efflux from soil respiration differed among the treatments at 1% level, with the rank of C (14642 mgCO2· m-2. h-1)>B (12807 mgCO2· m-2. h-1)>A (9532 mgCO2· m-2. h-1). Diurnal variation in soil respiration was not apparent due to little diurnal temperate change in Xishuangbanna. There was a parabola relationship between soil respiration and soil moisture at 1% level. Soil respiration rates were higher when soil moisture ranged from 35% to 45%. There was an exponential relationship between soil respiration and soil temperature (at a depth of 5cm in mineral soil) at 1% level. The calculated Q1o values in this study,ranging from 2.03 to 2.36, were very near to those of tropical soil reported. The CO2 efflux in 2003was 5.34 kgCO2· m-2. a-1 from soil plus litter plus seedling, of them 3.48 kgCO2· m-2. a-1 from soil (accounting for 62.5%), 1.19 kgCO2· m-2. a-1 from litter (22.3%) and 0.67 kgCO2·m-2. a-1 from seedling (12.5%). 相似文献
295.
Major reactive species of ambient volatile organic compounds (VOCs) and their sources in Beijing 总被引:1,自引:0,他引:1
Volatile organic compounds (VOCs) are important precursors of atmospheric chemical processes. As a whole mixture, the ambient VOCs show very strong chemical reactivity. Based on OH radical loss rates in the air, the chemical reactivity of VOCs in Beijing was calculated. The results revealed that alkenes, accounting for only about 15% in the mixing ratio of VOCs, provide nearly 75% of the reactivity of ambient VOCs and the C4 to C5 alkenes were the major reactive species among the alkenes. The study of emission characteristics of various VOCs sources indicated that these alkenes are mainly from vehicle exhaust and gasoline evaporation. The reduction of alkene species in these two sources will be effective in photochemical pollution control in Beijing. 相似文献
296.
通过对引江济太调水试验工程水质、水量的实测,以同步监测所得数据为基础,分析了其对水境的影响程度,阐述了引江济太对锡澄东部地区的利与弊,提出了引江济太应注意的一些问题。 相似文献
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Wen−Cheng Liu 《Environmental Geology》2005,47(4):535-546
Settling velocities of suspended cohesive sediment in estuaries vary over a range of several orders in magnitude. Variations in the suspended sediment concentration are often considered as the principal cause. Turbulence and the suspended sediment concentration, as well as other factors such as salinity, dissolved organic substances, flocculation ability, and the rate of floc growth affect setting velocities. A laterally–averaged finite difference model for hydrodynamics and cohesive sediment transport is developed and applied in the Tanshui River estuary, Taiwan. The model has been calibrated and verified with water surface elevation, longitudinal velocity, salinity, and cohesive sediment measured. The overall performance of the model is in qualitative agreement with the available data. The model is used to investigate the influence of settling velocity on cohesive sediment transport dynamics. The simulation indicates that the turbidity maximum zone is near Kuan–Du. When settling velocities increase the surface cohesive sediment concentration at Kuan–Du station trends to decrease and bottom cohesive sediment concentration increases. Both surface and bottom cohesive sediment concentrations decrease at Taipei Bridge and Pa–Ling Bridge. This implies that suspended sediment advected seaward and deposited. There is consequently a net seaward flux of suspended sediment near surface, and a net landward flux near the bed. 相似文献
299.
为了探索复杂滑坡轨迹结构演化及其稳定性定量分析计算的新途径,本文利用分形分维理论,分析三峡库区巴东县城附近滑坡边界轨迹的几何分形结构,并采用盒维数法分别求得巴东县城附近11个滑坡边界轨迹的分维值,计算结果表明:每个滑坡的轨迹结构具有其特征性的分维值,轨迹结构越复杂,结构层次越清楚,分维值越高;其中,榨房坪滑坡和黄腊石滑坡的分维值最高,分别为1.50和1.483,西壤口和谭家湾滑坡的分维值最低,分别为0.925和0.732;而黄土坡和赵树岭滑坡的分维值介于二者之间,分别为1.111和1.091。结合典型滑坡边界轨迹结构演化与滑坡稳定性关系的定性分析及前期滑坡稳定性定量计算和模拟分析,初步揭示:滑坡边界轨迹结构与稳定性是密切相关的,滑坡边界轨迹宏观扩展增值越明显,轨迹结构越复杂,分维值越高,其稳定性条件也越差,因此,分数维可作为衡量滑坡轨迹结构复杂性和稳定性的重要标志;滑坡边界轨迹宏观扩展变形存在一个极限,超过这个极限滑坡的局部失稳就转化为整体滑动;而滑坡边界轨迹则记录了滑坡变形扩展现象和信息,因此,相对应地滑坡轨迹分形结构的分维值也应存在一个极值,在极值点滑坡体处于临滑状态;滑坡边界轨迹结构的极限分维值大致为1.4~1.5,此时滑坡接近于整体极限失稳状态,而分维值在1.1~1.3之间则表示滑坡处于整体稳定,局部存在潜在失稳状态,分维值小于1则表示滑坡处于相对稳定状态。 相似文献
300.