微波消解―ICP―MS法测土壤和水系沉积物样品中的碘

介绍了用微波消解处理土壤和水系沉积物样品,用电感耦合等离子质谱仪(ICP-MS)快速高效测试碘的方法。方法的检出限为0. 012μg/g。所选的12个土壤和水系沉积物国家一级标准物质12次测定,除GBW07307a的RSD小于10%外,其余RSD值均小于5%,12次测试的平均值和标准值对数差绝对值均小于0. 05。方法加标回收率在98. 6%104. 6%之间。     

Numerical analysis of effect of baffle configuration on impact force exerted from rock avalanches

In mountainous areas, channelized rock avalanches swarm downslope leading to large impact forces on building structures in residential areas. Arrays of rock avalanche baffles are usually installed in front of rigid barriers to attenuate the flow energy of rock avalanches. However, previous studies have not sufficiently addressed the mechanisms of interaction between the rock avalanches and baffles. In addition, empirical design approaches such as debris flow (Tang et al., Quat Int 250:63–73, 2012), rockfall (Spang and Rautenstrauch, 1237–1243, 1988), snow avalanches (Favier et al., 14:3–15, 2012), and rock avalanches (Manzella and Labiouse, Landslides 10:23–36, 2013), which are applied in natural geo-disasters mitigation cannot met construction requirements. This study presents details of numerical modeling using the discrete element method (DEM) to investigate the effect of the configuration of baffles (number and spacing of baffle columns and rows) on the impact force that rock avalanches exert on baffles. The numerical modeling is firstly conducted to provide insights into the flow interaction between rock avalanches and an array of baffles. Then, a modeling analysis is made to investigate the change pattern of the impact force with respect to baffle configurations. The results demonstrate that three crucial influencing factors (baffle row numbers, baffle column spacing, and baffle row spacing) have close relationship with energy dissipation of baffles. Interestingly, it is found that capacity of energy dissipation of baffles increases with increasing baffle row numbers and baffle row spacing, while it decreases with increasing baffle column spacing. The results obtained from this study are useful for facilitating design of baffles against rock avalanches.     

A nonlinear multiparameter prestack seismic inversion method based on hybrid optimization approach

Multiparameter prestack seismic inversion is one of the most powerful techniques in quantitatively estimating subsurface petrophysical properties. However, it remains a challenging problem due to the nonlinearity and ill-posedness of the inversion process. Traditional regularization approach can stabilize the solution but at the cost of smoothing valuable geological boundaries. In addition, compared with linearized optimization methods, global optimization techniques can obtain better results regardless of initial models, especially for multiparameter prestack inversion. However, when solving multiparameter prestack inversion problems, the application of standard global optimization algorithms maybe limited due to the issue of high computational cost (e.g., simulating annealing) or premature convergence (e.g., particle swarm optimization). In this paper, we propose a hybrid optimization-based multiparameter prestack inversion method. In this method, we introduce a prior constraint term featured by multiple regularization functions, intended to preserve layered boundaries of geological formations; in particular, to address the problem of premature convergence existing in standard particle swarm optimization algorithm, we propose a hybrid optimization strategy by hybridizing particle swarm optimization and very fast simulating annealing to solve the nonlinear optimization problem. We demonstrate the effectiveness of the proposed inversion method by conducting synthetic test and field data application, both of which show encouraging results.     

嫩江科洛地区晚侏罗世深熔花岗岩对嫩江-黑河构造带的响应

通过对嫩江-黑河构造带内的岩石建造研究,在嫩江科洛地区识别出一套深熔花岗岩体,岩石宏观上为一套具非典型花岗岩结构的深熔型侵入岩,具交代结构、斑杂状构造和眼球状构造。对深熔花岗岩进行了锆石LA-ICP-MS U-Pb年龄测试,获得了3组不谐和的U-Pb年龄: 390 Ma、157~163 Ma和113 Ma。其中,113 Ma年龄代表了岩石遭受后期变质热事件年龄; 157~163 Ma的年龄代表了原岩结晶年龄。综合分析深熔花岗岩成因,认为其主要与嫩江-黑河断裂深部韧性剪切热效应作用下发生的深熔有关,深熔花岗岩的划分和厘定为深入研究嫩江-黑河断裂带在中生代的活动提供了新的素材。     

陕西略阳张家山金矿成矿作用及Au-Se矿物形成物理化学条件研究

陕西略阳煎茶岭金矿矿集区中的张家山金矿主要由破碎蚀变岩型、角砾岩型和含金石英黄铁矿脉型矿石组成。含金石英-黄铁矿脉型矿石产于断层下盘的石英菱镁岩中。黄铁矿发育富As黄铁矿边,环边受As含量的变化呈现一定的韵律变化,自然金赋存在富As黄铁矿中。在断裂发育形成断层角砾岩的过程中,流体充填破碎石英菱镁岩的裂隙中形成热液矿物,包括硫化物、硒化物以及自然金。石英菱镁岩发生破碎形成的网状裂隙被含金石英-方解石-黄铁矿脉充填。破碎蚀变岩型矿石中,自然金主要分布在含金石英-黄铁矿脉的石英之中或靠近热液脉的菱镁矿或石英间隙。随着大量方解石脉沿裂隙贯入,进一步促进石英菱镁岩的破碎及岩石角砾的分离,形成由石英菱镁岩碎屑、石英和褐铁矿组成的复成分角砾岩,自然金和硒化物呈浸染状分布在角砾岩中。笔者在角砾岩型矿石中发现了灰硒汞矿、直硒镍矿、硒铅矿等硒化物,这些硒化物往往与自然金密切共生。结合矿物组合以及相关化学反应关系,通过热力学计算,构建了该矿床在不同温度条件下的热力学相平衡关系图,限定了硒化物与其他相关矿物稳定存在的物理化学条件。硒化物一般与自然金和石英共生,高的f(Se2)值和f(Se2)/f(S2)比值是控制硒化物形成的关键因素。     

巴音戈壁盆地南部塔木素铀矿床水岩作用特征及其与铀成矿关系研究

在较封闭的环境中,塔木素铀矿床高矿化度(平均矿化度为35.4 g/L)NaCl型地下水中的Na+替换了斜长石中的Ca2+,使斜长石由更长石(An≈13)转变为钠长石(An≈1),被替换出的Ca_2+(以CaO计,约占斜长石总质量的4.5%)与地下水中的HCO_3~-、CO_3~(2-)及Mg~(2+)等结合形成了白云石等碳酸盐胶结物。在此过程中发生了脱碳作用,促使地下水中以[UO_2(CO_3)_3]~(4-)、[UO_2(CO_3)_3]~(2-)等碳酸铀酰络合离子及Mg CO_3·Na_2UO_2(CO_3)_2复盐发生分离而形成了铀的沉淀,并受扩散作用影响,水中的铀趋向于向水岩作用相对强烈地段迁移,从而促使铀在特定的层位集中、富集。同时,斜长石因水岩作用(溶解、溶蚀等),在解理面及表面形成了次生的缝隙及孔洞等,为铀沉淀提供了空间。成岩后,含SO_4~(2-)等的酸性地表水沿层间下渗,溶解了砂岩中碳酸盐胶结物而形成了溶洞,为后期再次迁移的铀提供了沉淀空间,并形成了铀的进一步叠加、富集。     

车排子凸起与沙湾凹陷过渡带的构造模型

车排子凸起位于准噶尔盆地扎伊尔山前,是夹持在南部四棵树凹陷和东部沙湾凹陷之间的三角构造带。然而对这个三角构造带是原地掩伏构造,山前推覆构造,还是走滑构造控制形成的认识存在争议。目前对于车排子凸起与沙湾凹陷过渡带的构造变形特征以及变形机制的认识尚不清楚。而过渡带是研究该区构造变形与演化的良好区域,精细研究该区域构造几何学与运动学对于揭示其构造变形机制以及认识盆山之间的关系具有积极作用,并对于该区油气勘探具有重要意义。本文以研究区的连片三维地震资料为基础,运用不整合面识别、轴面分析及平衡剖面等方法,对车排子凸起与沙湾凹陷过渡带进行精细的构造解析、建模与构造复原。研究表明,过渡带发育下二叠统（P₁j-P₁f）,中二叠统（P₂x-P₂w）,上二叠统（P₃w）,三叠系（T）,侏罗系（J）,白垩系（K）与古近系-第四系（E-Q）7个构造变形层序。发育佳木河组底部及石炭系内部滑脱层。深部（前二叠系）构造楔发育于整个过渡带,其个数和几何学形态的变化直接影响了上覆背斜形态。构造楔在早二叠世开始楔入,挤压作用持续至三叠纪末期。晚三叠世发育生长地层,显示了P-T构造层褶皱变形的时间,随后三叠纪末期,过渡带受到来自西北缘造山带方向的逆冲推覆构造的叠加作用,表现在后缘发育一系列叠瓦构造,推覆距离约为8 km,南部逆冲断层上盘二叠系-三叠系被剥蚀完全,北部残余少量下二叠统佳木河组。     

塔里木盆地和田河气田周缘寒武系盐下白云岩油气勘探潜力分析

塔里木盆地塔西南地区和田河气田周缘寒武系中统发育厚层膏盐岩,其下白云岩溶蚀裂缝-孔洞型储层发育条件好。多个层系具备烃源岩发育条件,除寒武系下统玉尔吐斯组外,震旦系、南华系也是可能的重要生油层系,油气资源丰富。盐下发育多个规模较大的构造圈闭,且由于膏盐岩层的滑脱作用,断裂很难断穿盐层,后期保存条件好。因此,寒武系中统膏盐岩与下伏白云岩组成本区重要的储盖组合,勘探领域具有非常好的前景。     

青藏高原北缘前寒武纪地质演化：进展与讨论

青藏高原北缘前寒武纪块体主要出露于塔里木盆地南缘的铁克里克和阿尔金、祁连山及柴达木盆地周缘等地区。这些古老块体分布于相对年轻的古生代秦祁昆造山带之中,大多经历了古生代造山事件的改造叠加。近10年来,对该地区前寒武纪地层时代格架、物质组成和构造属性研究取得了许多进展：1）揭示铁克里克、北阿尔金、全吉和阿拉善地块具有相似的2.5～2.2 Ga、2.1～1.7 Ga的基底演化和1.7 Ga之后的盖层沉积记录,反映塔里木克拉通、全吉地块和华北克拉通在Columbia 超大陆中具有相关和相似性。2）一系列地层时代被重新厘定,为建立新的前寒武纪地层划分方案提供了依据;3）厘定出铁克里克新元古代裂谷火山—沉积盆地,其可以与华北克拉通南缘1 000～830 Ma的裂解事件对比,它们在新元古代早期可能构成同一个克拉通裂解边缘;4）在南阿尔金与祁连、柴达木等地块识别出性质相似的新元古代岩浆作用和变质作用,它们可能共同代表一个新元古代早期活动大陆边缘的构造杂岩,为古生代汇聚、增生于塔里木克拉通或华北克拉通南缘的外来地块,存在于秦祁昆造山带之中。目前关于青藏高原北缘前寒武纪块体的物质组成、时代格架、构造属性和古环境变化研究还存在许多问题,仍需要开展进一步的大量工作。     

Rainfall threshold determination for flash flood warning in mountainous catchments with consideration of antecedent soil moisture and rainfall pattern

Flash flood disaster is a prominent issue threatening public safety and social development throughout the world, especially in mountainous regions. Rainfall threshold is a widely accepted alternative to hydrological forecasting for flash flood warning due to the short response time and limited observations of flash flood events. However, determination of rainfall threshold is still very complicated due to multiple impact factors, particular for antecedent soil moisture and rainfall patterns. In this study, hydrological simulation approach (i.e., China Flash Flood-Hydrological Modeling System: CNFF-HMS) was adopted to capture the flash flood processes. Multiple scenarios were further designed with consideration of antecedent soil moisture and rainfall temporal patterns to determine the possible assemble of rainfall thresholds by driving the CNFF-HMS. Moreover, their effects on rainfall thresholds were investigated. Three mountainous catchments (Zhong, Balisi and Yu villages) in southern China were selected for case study. Results showed that the model performance of CNFF-HMS was very satisfactory for flash flood simulations in all these catchments, especially for multimodal flood events. Specifically, the relative errors of runoff and peak flow were within?±?20%, the error of time to peak flow was within?±?2 h and the Nash–Sutcliffe efficiency was greater than 0.90 for over 90% of the flash flood events. The rainfall thresholds varied between 93 and 334 mm at Zhong village, between 77 and 246 mm at Balisi village and between 111 and 420 mm at Yu village. Both antecedent soil moistures and rainfall temporal pattern significantly affected the variations of rainfall threshold. Rainfall threshold decreased by 8–38 and 0–42% as soil saturation increased from 0.20 to 0.50 and from 0.20 to 0.80, respectively. The effect of rainfall threshold was the minimum for the decreasing hyetograph (advanced pattern) and the maximum for the increasing hyetograph (delayed pattern), while it was similar for the design hyetograph and triangular hyetograph (intermediate patterns). Moreover, rainfall thresholds with short time spans were more suitable for early flood warning, especially in small rural catchments with humid climatic characteristics. This study was expected to provide insights into flash flood disaster forecasting and early warning in mountainous regions, and scientific references for the implementation of flash flood disaster prevention in China.