Metamorphism in Archaean greenstone belts: calculated fluid compositions and implications for gold mineralization

An inescapable consequence of the metamorphism of greenstone belt sequences is the release of a large volume of metamorphic fluid of low salinity with chemical characteristics controlled by the mineral assemblages involved in the devolatilization reactions. For mafic and ultramafic sequences, the composition of fluids released at upper greenschist to lower amphibolite facies conditions for the necessary relatively hot geotherm corresponds to those inferred for greenstone gold deposits (X_CO2= 0.2–0.3). This result follows from the calculation of mineral equilibria in the model system CaO–MgO–FeO–Al₂O₃–SiO₂–H₂O–CO₂, using a new, expanded, internally consistent dataset. Greenstone metamorphism cannot have involved much crustal over-thickening, because very shallow levels of greenstone belts are preserved. Such orogeny can be accounted for if compressive deformation of the crust is accompanied by thinning of the mantle lithosphere. In this case, the observed metamorphism, which was contemporaneous with deformation, is of the low-P high-T type. For this type of metamorphism, the metamorphic peak should have occurred earlier at deeper levels in the crust; i.e. the piezothermal array should be of the ‘deeper-earlier’type. However, at shallow crustal levels, the piezothermal array is likely to have been of ‘deeper-later’type, as a consequence of erosion. Thus, while the lower crust reached maximum temperatures, and partially melted to produce the observed granites, mid-crustal levels were releasing fluids prograde into shallow crustal levels that were already retrograde. We propose that these fluids are responsible for the gold mineralization. Thus, the contemporaneity of igneous activity and gold mineralization is a natural consequence of the thermal evolution, and does not mean that the mineralization has to be a consequence of igneous processes. Upward migration of metamorphic fluid, via appropriate structurally controlled pathways, will bring the fluid into contact with mineral assemblages that have equilibrated with a fluid with significantly lower X_CO2. These assemblages are therefore grossly out of equilibrium with the fluid. In the case of infiltrated metabasic rocks, intense carbonation and sulphidation is predicted. If, as seems reasonable, gold is mobilized by the fluid generated by devolatilization, then the combination of processes proposed, most of which are an inevitable consequence of the metamorphism, leads to the formation of greenstone gold deposits predominantly from metamorphic fluids.     

Response of circular footings and anchor plates in non-homogeneous elastic soils

The axisymmetric elastic response of circular footings and anchor plates in a linearly non-homogeneous elastic soil is analysed. It is assumed that footings/anchors are flexible and subjected to axisymmetric vertical loads. The response of the footing/anchor is modelled by using the classical Poisson–Kirchhoff thin plate theory. A variational technique is used to analyse the interaction problem. A representation for the contact stress is established by using a fundamental solution corresponding to a unit vertical pressure acting over an annular region in the interior of the non-homogeneous soil. The fundamental solution can be derived by using rigorous analytical procedures. The influence of the footing flexibility and the degree of soil non-homogeneity on the displacements, bending moments and contact stresses of a surface footing is examined over a wide range of governing parameters. In the case of anchor plates the influence of depth of embedment, degree of soil non-homogeneity and anchor flexibility on the anchor displacement is investigated.     

A high resolution,multiproxy Late‐glacial record of climate change and intrasystem responses in northwest England

A lacustrine carbonate sequence from Hawes Water, Lancashire, UK, has been studied using stable isotopic, lithological, pollen and mineral magnetic analysis. The data reveal four abrupt climatic oscillations in the Late‐glacial Interstadial leading up to the onset of the Loch Lomond Stadial. The data also point to climatic warming relatively early within the stadial, ca. 12 500 GRIP yr, prior to the onset of the Holocene. The oxygen isotope record is taken as a signature of climate forcing against which the response of the lake‐system can be monitored. By adopting this approach it is revealed that the response of the biological system to the rapid climatic oscillations is non‐linear and primarily a function of the antecedent conditions. A significant end‐Devensian isotopic excursion (A) is matched by only minor changes in the cold‐adapted floras and faunas. During the warmer interstadial, the response of the biological ecosystem (events B–D) is clearly influenced by thresholds: major changes in the catchment vegetation associated with relatively minor oscillations in the isotopic signature. The stratigraphical patterns reveal significant lag effects between the onset of climate deterioration and resulting changes in vegetation. Copyright © 2002 John Wiley & Sons, Ltd.     

Sources and sinks of sea salt in a newfoundland blanket bog

Over an oceanic peatland, the concentration of Na in fog averaged 38.1 mgl^?1 compared with 1.8 mgl^?1 in rain, resulting in a significant flux of mineral elements to the surface. Between 16 May and 20 June 1990 the average mass flux of Na to the bog surface by fog, rain, and dry deposition was 21.9, 10.4 and 7.0 mg m^?2 d^?1. There was little long-term storage of Na within the peatland system, where Na losses measured in stream runoff averaged 34.8 mg m² d^?1, and deep groundwater losses 4 mg m^?2 d^?1. Calcium and Mg were preferentially retained in the organic soil, whereas K was relatively mobile. Potassium tended to become concentrated in the unsaturated zone. Stream runoff had a consistently higher pH than groundwater, corresponding to higher Ca and Mg concentrations, which may have been from mineral sources in the headwater ponds. Otherwise, the stream water chemistry was closely related to groundwater in the upper layers of the peat deposit.     

Comparison of results from several AOGCMs for global and regional sea-level change 1900–2100

 Sea-level rise is an important aspect of climate change because of its impact on society and ecosystems. Here we present an intercomparison of results from ten coupled atmosphere-ocean general circulation models (AOGCMs) for sea-level changes simulated for the twentieth century and projected to occur during the twenty first century in experiments following scenario IS92a for greenhouse gases and sulphate aerosols. The model results suggest that the rate of sea-level rise due to thermal expansion of sea water has increased during the twentieth century, but the small set of tide gauges with long records might not be adequate to detect this acceleration. The rate of sea-level rise due to thermal expansion continues to increase throughout the twenty first century, and the projected total is consequently larger than in the twentieth century; for 1990–2090 it amounts to 0.20–0.37 m. This wide range results from systematic uncertainty in modelling of climate change and of heat uptake by the ocean. The AOGCMs agree that sea-level rise is expected to be geographically non-uniform, with some regions experiencing as much as twice the global average, and others practically zero, but they do not agree about the geographical pattern. The lack of agreement indicates that we cannot currently have confidence in projections of local sea-level changes, and reveals a need for detailed analysis and intercomparison in order to understand and reduce the disagreements. Received: 1 September 2000 / Accepted: 20 April 2001     

Grain boundary diffusion in enstatite

We have investigated grain boundary diffusion rates in enstatite by heating single crystals of quartz packed in powdered San Carlos olivine (Mg_0.90Fe_0.10)₂SiO₄ at controlled oxygen fugacities in the range 10^?5.7 to 10^?8.7?atm and temperatures from 1350° to 1450?°C for times from 5 to 100?h at 1?atm total pressure. Following the experiments, the thickness of the coherent polycrystalline reaction rim of pyroxene that had formed between the quartz and olivine was measured using backscatter scanning imaging in the electron microprobe. Quantitative microprobe analysis indicated that the composition of this reaction phase is (Mg_0.92Fe_0.08)₂Si₂O₆. The rate of growth of the pyroxene increases with increasing temperature, is independent of the oxygen fugacity, and is consistent with a parabolic rate law, indicating that the growth rate is controlled by ionic diffusion through the pyroxene rim. Microstructural observations and platinum marker experiments suggest that the reaction phase is formed at the olivine-pyroxene interface, and is therefore controlled by the diffusion of silicon and oxygen. The parabolic rate constants determined from the experiments were analyzed in terms of the oxide activity gradient across the rim to yield mean effective diffusivities for the rate-limiting ionic species, assuming bulk transport through the pyroxene layer. These effective diffusivities are faster than the lattice diffusivities for the slowest species (silicon) calculated from creep experiments, but slower than measured lattice diffusivities for oxygen in enstatite. Thus, silicon grain boundary diffusion is most likely to be the rate-limiting process in the growth of the pyroxene rims. Also, as oxygen transport through the pyroxene rims must be faster than silicon transport, diffusion of oxygen along the grain boundaries must be faster than through the lattice. The grain boundary diffusivity for silicon in orthopyroxenite is then given by D¯gbSiδ=(3.3±3.0)×10^?9f0.0O₂e^?400±65/RT?m³s^?1, where the activation energy for diffusion is in kJ/mol, and δ is the grain boundary width in m. Calculated growth rates for enstatite under these conditions are significantly slower than predicted by an extrapolation from similar experiments performed at 1000?°C under high pressure (hydrous) conditions by Yund and Tullis (1992), perhaps due to water-enhancement of diffusion in their experiments.     

An experimental study in forming a long synthetic aperture at sea

The testing of a synthetic aperture technique, the ETAM algorithm, is extended and its performance for CW pseudorandom signals and broadband ship noise is examined. The results show the limitations of the technique and are of special interest for operational systems development. In the CW experiments, the transmitted signal was generated with high temporal coherence, and loss of the spatial and temporal coherence of the received signal was introduced only by the medium and the stability of the towed array. In the experiments that included the pseudorandom signal and the ship noise, the temporal coherence of the transmitted signals was deliberately chosen to be poor in order to study the effects and the performance of this algorithm with broadband signals. The related experimental results show that for received signals, which have their segments over the synthesizing period highly cross-correlated, a synthetic aperture array gain was achieved that corresponds to the length of an equivalent fully populated array     

A techno-economic comparison of power systems for autonomousunderwater vehicles

This paper compares lead-acid batteries, sodium-sulfur batteries, solid polymer fuel cells and closed-cycle diesel engines for autonomous underwater vehicle (AUV) applications. The service is described in terms of a parametric mission and life cycle. A generic AUV is used as a basis for comparison. Power systems are evaluated by two criteria: (1) submerged endurance capability and (2) life cycle cost. This study determines categories of service for which each power system is preferred. The solid polymer fuel cell can provide greater submerged endurance than other power systems examined. For extremely long duration AUV missions, the fuel cell is the required system, indicating a possible market niche for today's fuel cell technology. Considering cost projections for each power system, the results also show that the SPFC can become cost-competitive with conventional technologies, particularly for services characterized by high levels of utilization     

Geophysical investigations over a segment of the Central Indian Ridge, Indian Ocean

 Swath bathymetric, gravity, and magnetic studies were carried out over a 55 km long segment of the Central Indian Ridge. The ridge is characterized by 12 to 15 km wide rift valley bounded by steep walls and prominent volcanic constructional ridges on either side of the central rift valley. A transform fault at 7°45′S displaces the ridge axis. A mantle Bouguer anomaly low of −14 mGals and shallowing of rift valley over the middle of the ridge segment indicate along axis crustal thickness variations. A poorly developed neovolcanic zone on the inner rift valley floor indicate dominance of tectonic extension. The off-axis volcanic ridgs suggest enhanced magmatic activity during the recent past. Received: 24 May 1996 / Rivision received: 13 January 1997