Bizarre geochemistry of komatiites from the Crixás greenstone belt,Brazil

Komatiite lava flows in the Crixás greenstone belt, Goiás, Brazil, have textures and volcanic structures typical of Archean komatiites, but are geochemically most unusual. The flows are porphyritic and massive, or layered with spinifex upper parts and olivine cumulate lower parts. MgO contents range from 18 to 40%. In such lavas, only olivine (and minor chromite) can have crystallized, but neither major nor trace elements fall on olivine control lines. In MgO variation diagrams, CaO and Sr fall on lines with slopes steeper than olivine control lines; SiO₂, FeO, Na₂O, K₂O and Y show little systematic variation; Zr shows a large variation that does not correlate with MgO; and Al₂O₃ decreases markedly with decreasing MgO. The aberrant behaviour is highlighted by the REE (rare earth elements) in spinifex and olivine cumulate layers from three flows: in the spinifex layers, chondrite-normalized REE patterns are hump-shaped with maxima at Nd or Sm ((La/Sm)_N=0.6, (Gd/Yb)_N=1.6–2.3), whereas cumulate zones in the same flows have steadily sloping patterns, with LREE enriched relative to HREE ((La/Sm)_N=1.3, (Gd/Yb)_N=1.4). Neither normal magmatic processes acting during emplacement of the komatiites, nor thermal erosion and wall-rock assimilation can explain these effects, and we speculate that elements commonly thought of as “immobile” (e.g. Al, Zr, REE) migrated during hydrothermal alteration or metamorphism. A Pb-Pb whole rock isochron gave an age of 2,728±140 Ma and selected Sm-Nd analyses an apparent isochron age of 2,825±98 Ma (ɛ_Nd≈0). The Pb-Pb age is believed to be the approximate time of emplacement. Interpretation of the Sm-Nd data is complicated by the evidence of mobility of REE.     

The biogeochemical sulfur cycle in the marine boundary layer over the Northeast Pacific Ocean

The major components of the marine boundary layer biogeochemical sulfur cycle were measured simultaneously onshore and off the coast of Washington State, U.S.A. during May 1987. Seawater dimethylsulfide (DMS) concentrations on the continental shelf were strongly influenced by coastal upwelling. Concentration further offshore were typical of summer values (2.2 nmol/L) at this latitude. Although seawater DMS concentrations were high on the biologically productive continental shelf (2–12 nmol/L), this region had no measurable effect on atmospheric DMS concentrations. Atmospheric DMS concentrations (0.1–12 nmol/m³), however, were extremely dependent upon wind speed and boundary layer height. Although there appeared to be an appreciable input of non-sea-salt sulfate to the marine boundary layer from the free troposphere, the local flux of DMS from the ocean to the atmosphere was sufficient to balance the remainder of the sulfur budget.     

Axisymmetry in protoplanetary nebulae – II. A near-infrared imaging polarimetric survey

In an imaging polarimetry survey of candidate post-AGB stars, scattering envelopes are detected around 20 objects. These envelopes represent the final mass-loss phases at the end of the AGB. In all cases, evidence for axisymmetry in the dust density is seen, suggesting that the presence of an axisymmetric outflow may be a ubiquitous phenomenon of the AGB to post-AGB transition. We use the polarized flux images to classify the objects into detached shell, bipolar and unresolved targets. Modelling based on a simple axisymmetric shell geometry supports the contention that post-AGB objects fall into one of two classes that differ in the amount of dust in the circumstellar environment: the detached shells correspond to stars with an optically thin expanding circumstellar envelope (CSE) whereas the bipolar and unresolved targets have optically thick dust structures, probably in the form of discs, which remain bound to the star, rather than partaking in the expansion of the AGB CSE. It is suggested that this bifurcation in morphology is rooted in the presence or absence of a binary companion, which determines whether or not a disc forms. Because the detached shell objects also appear axisymmetric, an additional mechanism for generating the axisymmetry, such as a magnetically shaped outflow, is needed if they do indeed have single star progenitors.     

Orbital Evolution of Příbram and Neuschwanstein

The orbital evolution of the two meteorites Příbram and Neuschwanstein on almost identical orbits and also several thousand clones were studied in the framework of the N-body problem for 5,000 years into the past. The meteorites moved on very similar orbits during the whole investigated interval. We have also searched for photographic meteors and asteroids moving on similar orbits. There were five meteors found in the IAU MDC database and six NEAs with currently similar orbits to Příbram and Neuschwanstein. However, only one meteor 161E1 and one asteroid 2002 QG46 had a similar orbital evolution over the last 2,000 years.     

Dissolved oxygen variations in alpine glacial meltwaters

Recent models of chemical weathering in alpine glacial meltwaters suggest that sulphide oxidation is a major source of solute in the distributed component of the subglacial hydrological system. This reaction requires O₂, and may lower dissolved oxygen levels to below saturation with respect to the atmosphere. This should result in an inverse association between SO₇^2- and dissolved oxygen saturation. However, measurements of O₂ saturation in bulk meltwaters draining the Haut Glacier d'Arolla, Switzerland, show that there is a positive association between SO₄^2- and O₂ saturation. The O₂ content of glacial meltwaters depends on the initial content of snow and icemelt, which may be controlled by the rate of melting, and the kinetic balance between O₂ losses (e.g. sulphide oxidation, microbial respiration) and gains (e.g. diffusion of O₂ into solution).     

Nature of the small main belt Asteroid 3169 Ostro

We present a set of rotational lightcurve measurements of the small main belt Asteroid 3169 Ostro. Our observations reveal an unambiguous, double-peaked rotational lightcurve with a peak-to-peak variation up to 1.2±0.05 mag and a synodic period of 6.509±0.001 h. From the large flux variation and the overall shape of the lightcurves, we suggest that 3169 Ostro could be a tightly bound binary or a contact binary, similar to the Trojan Asteroid 624 Hektor. A shape model of this system is proposed on the assumption that 3169 Ostro is a Roche binary described by a pair of homogeneous elongated bodies, with a size ratio of 0.87, in hydrostatic equilibrium and in circular synchronous motion around each other. The direction of the spin axis is determined modulo 180° by its J2000 ecliptic coordinates λ₀=50±10°, β₀=±54±5°. The binary interpretation and the pole solution adequately fit the earlier photometric observations made in 1986 and 1988. However, additional supporting lightcurves are highly desirable especially in the next mutual events occurrence of 2008 and 2009 in order to remove the pole ambiguity and to confirm unambiguously the binary nature of 3169 Ostro.     

Allochthonous and autochthonous organic matter in surface waters in Karelia

A relationship between indirect chemical indices of organic matter content of surface waters and light absorption in the visible and ultraviolet ranges is discussed. The allochthonous and autochthonous types of organic matter are found to essentially differ in the rate of light absorption. Techniques are proposed for the calculation of the concentrations of allochthonous and autochthonous organic matter by the integral rate of light consumption in the visible region and the bichromate oxidability of water, as well as by three indirect indices: chemical oxygen demand, permanganate oxidability, and water color index. The mean concentrations of allochthonous and autochthonous organic matter in large lakes (Ladoga, Onega, and Baikal) and in rivers and smaller water bodies in Karelia (>300 water objects) are analyzed. Allochthonous organic matter was found to predominate in most surface waters of Karelia (>80%), while allochthonous organic matter predominates only in lakes with a small specific catchment area (supposedly, <5) and in highly eutrophic lakes.