Intercomparison of measurements of stratospheric hydrogen fluoride

Observations of the vertical profile of hydrogen fluoride (HF) vapor in the stratosphere and of the vertical column amounts of HF above certain altitudes were made using a variety of spectroscopic instruments in the 1982 and 1983 Balloon Intercomparison Campaigns. Both emission instruments working in the far infrared spectral region and absorption instruments using solar occultation in the 2.5m region were employed. No systematic differences were seen in results from the two spectral regions. A mean profile from 20–45 km is presented, with uncertainties ranging from 20% to 50%. Total columns measured from ground and from 12 km are consistent with the profile if the mixing ratio for HF is small in the tropophere and low stratosphere.     

Numerical study of droplet size dependent chemistry in oceanic,wintertime stratus cloud at southern mid-latitudes

Cloud droplet chemistry is modelled for the first 150 m of rise in a wintertime, mid-latitude, marine stratus cloud using observations made at and near the Cape Grim Baseline Station as a source of input parameters. The emphasis in this work was to study the variation in droplet chemistry as a function of both droplet size and nucleus composition, with a particular focus on the way in which oxidation of dissolved sulfur dioxide varied.At 150 m above the condensation level, solute concentration as a function of droplet size was found to increase by as much as 2 to 3 orders of magnitude for only a factor of 2 increase in droplet radius, primarily as a consequence of the 1/r dependence in the droplet growth equation. This type of size dependence exists at all levels in the model cloud, and has a significant influence on oxidation rate of sulfur dioxide in droplets growing on sulfate nuclei, oxidation by ozone being favoured in the smallest droplets, but oxidation by hydrogen peroxide being favoured in the larger droplets. Oxidation by ozone is favoured at all sizes in droplets formed on sea-salt nuclei as a result of the initially high alkalinity of these droplets, and in the cloud overall is calculated to be the more important oxidation pathway. Although based on a simplified chemical scheme, these results suggest that both size-dependent and nucleus-dependent chemistry of cloud droplets may need to be considered explicitly in cloud modelling work.Volume-weighted mean pH values in the range 5 to 6 were predicted from sensitivity studies in which input variables were varied over reasonable ranges, in agreement with two sets of bulk cloud-water pH data obtained by aircraft near Cape Grim.     

Carbon isotopic fractionation between CO2 vapour,silicate and carbonate melts: an experimental study to 30 kbar

The carbon isotopic fractionation between CO₂ vapour and sodamelilite (NaCaAlSi₂O₇) melt over a range of pressures and temperatures has been investigated using solid-media piston-cylinder high pressure apparatus. Ag₂C₂O₄ was the source of CO₂ and experimental oxygen fugacity was buffered at hematite-magnetite by the double capsule technique. The abundance and isotopic composition of carbon dissolved in sodamelilite (SM) glass were determined by stepped heating and the ¹³C of coexisting vapour was determined directly by capsule piercing. CO₂ solubility in SM displays a complex behavior with temperature. At pressures up to 10 kbars CO₂ dissolves in SM to form carbonate ion complexes and the solubility data suggest slight negative temperature dependence. Above 20 kbars CO₂ reacts with SM to form immiscible Na-rich silicate and Ca-rich carbonate melts and CO₂ solubility in Na-enriched silicate melt rises with increasing temperature above the liquidus. Measured values for carbon isotopic fractionation between CO₂ vapour and carbonate ions dissoived in sodamelilite melt at 1200°–1400° C and 5–30 kbars average 2.4±0.2, favouring¹³C enrichment in CO₂ vapour. The results are maxima and are independent of pressure and temperature. Similar values of 2 are obtained for the carbon isotopic fractionation between CO₂ vapour and carbonate melts at 1300°–1400° C and 20–30 kbars.     

High-resolution spectroscopy of gamma-ray bursts

We report on results from the Goddard germanium Gamma-Ray Burst Spectrometer flown on the ISEE-3 spacecraft. Spectral and temporal studies of two events on 4 and 19 November, 1978 are presented. The power law spectral indices were found to be respectively –1.82 and –1.31, the latter being the hardest event thus far detected. Evidence for two lines in the 4 November event is presented — a broad feature at 420 keV and a narrower one at 740 keV. These are consistent with a common redshift if the parent lines are assumed to be the positron annihilation line (511 keV) and the first excited state of iron (847 keV). If this interpretation is correct, it is shown that additional lines from higher levels of iron and possibly other nuclei are expected and that they may represent a significant contribution to the total spectrum above 1 MeV.Paper presented at the Symposium on Cosmic-Ray Bursts, held at Toulouse, France, 26–29 November, 1979.     

Climate and paleoclimate: What we can learn about solar luminosity variations

The Earth's climate is not constant, and has experienced major changes in the past on all timescales. The causes of these changes, although still incompletely understood, vary according to the timescale considered. Some of the most important causal mechanisms include continental drift, changes in the Earth's orbital parameters, volcanic activity and solar variations. Solar variations have been invoked to explain climatic change on almost all timescales from 1 to 10⁹ yr. Unfortunately, even though the Sun is a prime candidate for explaining many changes in past climate, the use of past climate as a proxy for solar luminosity changes is fraught with difficulty. For example:

1. In many cases observed changes in climate can be adequately explained without recourse to solar variations as a causal factor. In fact, on the longest timescales the Earth's climate was remarkably similar to today in spite of a considerably lower solar output.
2. For most timescales of climatic change there are, as yet, no plausible theories giving similar timescale variations in solar activity, so that a vital link between cause and effect is missing.
3. There are considerable uncertainties in the record of past climates.
4. On short timescales many proposed solar activity-climate links have failed to stand up to rigorous statistical analysis.

This paper reviews past changes in climate and proposed causal mechanisms on timescales of from 1 to 10⁹ yr. The evidence for solar activity-climate links is discussed with special reference to the above points.     

Near-infrared spectrophotometry of the satellites and rings of Uranus

New spectrophotometry from 1.5 to 2.5 μm is reported for the Uranian satellites Titania, Oberon, and Umbriel. A spectrum of the rings of Uranus from 2.0 to 2.4 μm is also reported. No evidence is found for frost covering the surface of the ring material, consistent with the low albedo of the rings (P_K = 0.03) previously reported by Nicholson and Jones (1980). The surfaces of the satellites are found to be covered by dirty water frost. Assuming albedos of the frost and gray components covering the Uranian satellites to be the same as the light and dark faces of Iapetus, radii are derived that are roughly twice those inferred from the assumption of a visual albedo of 0.5.     

Additional measurements of the high-latitude sunspot rotation rate

We report measurements of the sunspot rotation rate at high sunspot latitutdes for the years 1966–1968. Ten spots at ¦latitude¦ 28 deg were found in our Mees Solar Observatory H patrol records for this period that are suitable for such a study. On the average we find a sidereal rotation rate of 13.70 ± 0.07 deg day^-1 at 31.05 ± 0.01 deg. This result is essentially the same as that obtained by Tang (1980) for the succeeding solar cycle, and significantly larger than Newton and Nunn's (1951) results for the 1934–1944 cycle. Taken together, the full set of measurements in this latitude regime yield a rotation rate in excellent agreement with the result =14^°.37₇–2^°.77 sin², derived by Newton and Nunn from recurrent spots predominatly at lower latitudes throughout the six cycles from 1878–1944.Summer Research Assistant.     

The jump of the second derivative of the Moon's elongation

We present some results of new calculations ofD(t)-the second derivative of the Moon's elongation as a function of time. The paper contains an explanation of the well-known R. Newton's effecthe rapid decline inD(t) from about 700 yr to about 1300 yr. The new graph ofD is based on the revised dates of the ancient eclipses and has a qualitatively different character; in particular, the decline inD(t) vanishes completely andD(t) oscillates at a roughly constant value, which coincides with the modern one. This fact agrees with the independent chronological results in the author's [7] paper.     

The center-to-limb behavior of Ca i λ6573 and [Ca ii] λ7324

Center-to-limb measurements of the Ca i 6573 intercombination line and the Ca ii 7324 forbidden line are compared with synthetic profiles based on a simple representation of the non-LTE Ca-Ca⁺ ionization equilibrium. The effects of photoionizations from low lying excited states of neutral calcium are found to reduce the sensitivity of the 6573 center-to-limb behavior as a thermal structure diagnostic. The synthetic center-to-limb behavior is also sensitive to uncertainties in the nonthermal broadening. Nevertheless, the measured center-to-limb behavior of 6573 favors a cool photospheric model similar to the Vernazza, Avrett, and Loeser model M over hotter models based on the Ca ii K wings. The non-LTE calcium abundance obtained from the disk center equivalent widths of 6573 and 7324 using the best fit model is A _Ca2.1±0.2 × 10^-6 (by number relative to hydrogen). Applications of these lines as diagnostics of the Ca-Ca⁺ ionization equilibrium in other stars are briefly discussed.Visiting Astronomer, Kitt Peak National Observatory.Operated by the Association of Universities for Research in Astronomy, Inc. under contract with the National Science Foundation.