Simulation of diagenesis and permeability variation in two-dimensional rock structure

A model is suggested to simulate the physical aspect of diagenesis in porous rocks. A bidisperse ballistic deposition model with relaxation of deposited grains is used to generate the porous structure. Sedimentation and erosion are allowed to restructure the pore space as a fluid flows through the rock. The effect of this restructuring of the pore space on permeability is studied. The Navier–Stokes equation is solved numerically by the finite difference method to determine the pressure and velocity distributions in the pore space. We find that though deposition is the dominant process in our model of diagenesis, reducing the porosity, the permeability may increase dramatically in some cases. These are when the erosion takes place at a single narrow constriction in the pore channel.     

Velocity and Density Heterogeneities of the Tien-Shan Lithosphere

—The Tien-Shan orogene is a region in which the earth’s crust undergoes considerable thickening and tangential compression. Under these conditions the lithosphere heterogeneities (composi tion, rheological) create the prerequisites for the development of various phenomena of tectonic layering (lateral shearing, different deformation of layers). To study the distribution of velocity, density and other elastic parameters, the results from a seismic tomography study on P-wave as well as S-wave velocities were used. Using empirical as well as theoretical formulas on the relationship between velocity, density and silica content in rocks, their distribution in the Tien-Shan’s lithosphere has been calculated. In addition, other elastic parameters, such as Young’s modulus, shear modulus, Poisson’s ratio and coefficient of general compressions have been determined. Zoning of different types of crust was carried out for the region investigated. The characteristics of the "crust-mantle" transition have been investi gated. Large blocks with different types of the earth’s crust were distinguished. Layers with inverse values of velocity, density and shear and Young modulus are revealed in the Tien-Shan lithosphere. All of the above described features open new ways to solve geodynamics problems.     

Long-wavelength MHD instability in the prefront of collisionless shocks with accelerated particles

Collisionless shocks in turbulent space plasmas accelerate particles by the Fermi mechanism to ultrarelativistic energies. The interaction of accelerated particles with the plasma inflow produces extended supersonic MHD flows of multicomponent plasma. We investigate the instabilities of a flow of three-component turbulent plasma with relativistic particles against long-wavelength perturbations with scales larger than the accelerated particle transport mean free path and the initial turbulence scales. The presence of turbulence allows us to formulate the system of single-fluid equations, the equation of motion for the medium as a whole, and the induction equation for the magnetic field with turbulent magnetic and kinematic viscosities. The current of accelerated particles enters into the induction equation with an effective magnetic diffusion coefficient. We have calculated the local growth rates of the perturbations related to the nonresonant long-wavelength instability of the current of accelerated particles for MHD perturbations in the WKB approximation. The amplification of long-wavelength magnetic field perturbations in the flow upstream of the shock front can affect significantly the maximum energies of the particles accelerated by a collisionless shock and can lead to the observed peculiarities of the synchrotron X-ray radiation in supernova remnants.     

Assessment of dissolved nutrients dispersal derived from offshore fish-farm using nitrogen stable isotope ratios (δ15N) in macroalgal bioassays

In this study, the dispersal of wastes from offshore fish farms was evaluated by analyzing nitrogen stable isotope ratios (δ¹⁵N) in macroalgae incubated in the water column at sites located at an increasing distance from the fish cages. Bioassays were performed at three fish farms situated in separate localities with different nutritional conditions (Canary Islands, Murcia and Catalonia) and varying in size, species of fish reared and annual production. Macroalgal bioassays were carried out in two different directions (DI and DII) and they were replicated at each distance in order to evaluate the effect of small-scale variability on the spatial extent of fish farm wastes. The results obtained with δ¹⁵N contribute to a better understanding of the application of nitrogen stable isotopes ratios in macroalgae as an effective bioindicator for tracing the dispersion of offshore fish farm wastes, and demonstrate that fish farm wastes can be traced even over distances of some km from the pollution source. In the Canary Islands, the maximum distance obtained for detection of fish farm wastes was between 450 and 700 m. Of the three installations studied, Murcia presented the greatest distance for detection of fish farm waste influence, ranging from between 1550 and 2450 m, whilst in Catalonia this distance was less than 120 m. In Catalonia, the results were masked by the influence of other sources of nitrogen, and thus fish farm wastes were detected at more reduced distances than expected. These results confirm that fish farm wastes can be traced using the nitrogen stable isotope ratios of macroalgae and that this method can also be useful for identifying areas of potential risk to some sensitive ecosystems, and as an early signal that changes in the community structure might occur.     

A gridded sea surface salinity data set for the tropical Pacific with sample applications (1950–2008)

We present a gridded data set of Sea Surface Salinity (SSS) for the tropical Pacific (120°E–70°W; 30°N–30°S), with a grid resolution of 1° longitude, 1° latitude and 1 month, from 1950 to 2008. The product, together with its associated error field, is derived from an objective analysis of about 10 million validated SSS records, with most of the data originating from Voluntary Observing Ships, TAO/TRITON moorings and Argo profilers (during the most recent period). We expect this product to benefit studies in oceanography, meteorology and paleoceanography. As examples of applications, we analyse: (a) the seasonal and ENSO (El Niño Southern Oscillation) modes of observed SSS variability, (b) the ability of 23 coupled models used in the Intergovernmental Panel for Climate Change 4th Assessment Report (IPCC AR4) to simulate the mean SSS and these two time varying modes, and (c) the usefulness of the SSS product and of its associated error field in calibrating and validating the paleo-salinity time series. We anticipate improvements and regular updates to our product, as more SSS data become available from in situ networks and from the ongoing and near-future satellite-derived observations by SMOS (Soil Moisture and Ocean Salinity) and Aquarius.     

Characterization of dissolved organic matter across the Subtropical Convergence off the South Island,New Zealand

Dissolved organic matter (DOM) was investigated along a gradient across the Subtropical Convergence (STC) off the South Island, New Zealand. Ultrahigh resolution electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR-MS), excitation emission matrix fluorescence (EEM) spectroscopy, and molecular lignin analysis techniques were used to study this DOM. The analysis revealed a group of compounds found only in the coastal DOM samples, which were also characterized by an elevated terrestrial DOM fluorescence pattern and elevated lignin content if compared to the offshore samples. This group exhibited a high degree of carbon unsaturation, as evident from high double bond equivalence minus oxygen values (DBE-O > 9) and maximum fluorescence intensity. Sulfur-containing molecular formulae for summer DOM samples were much more abundant across the entire transect of the STC compared to winter and exhibited distinctly different hydrogen:carbon and oxygen:carbon elemental ratios, suggesting a possible correlation between biological activity and sulfur compounds. The molecular formulae common to all STC samples were compared with those calculated for DOM extracted from freshwater collected from a stream discharging into Doubtful Sound (West Coast, New Zealand). ESI-FT-ICR-MS measurements undertaken in negative electrospray ionization (ESI?) mode indicated that 30% of the molecular formulae were present in both types of DOM, while in positive ESI mode (ESI+) over 90% of the formulae were present in all samples. Hence, a significant portion of the molecular formulae assigned to the solid-phase extractable DOM pool (SPE-DOM) appear to be identical in oceanic and freshwater samples.     

Kinematic structure and mesoscale variability of the rim current near the coast of Crimea (according to the data of instrumental measurements in September 2008)

By using the results of processing of the instrumental data with high space resolution obtained in September 2008, we analyze the structure of the Rim Current in the upper 100-m layer near the coast of Crimea. We determine the statistical characteristics of the mesoscale fluctuations of currents according to the data of 1165 vertical probes. It is shown that the kinetic energy of intense mesoscale perturbations observed in the vicinity of the Rim Current is of the same order of magnitude as the kinetic energy of the mean current.     

Residual deformations and seismic hazard of fault zones in underground workings

The results of long-term measurements of residual deformations in the area of the Severomuiskii tunnel during its construction are given. Comparison of spatial and temporal distributions between deformations and earthquakes shows that they are interrelated. The nonlinear behavior of disintegrated and waterlogged rocks within tectonic fault zones should be taken into account even for moderate intensity earthquakes, since they are accompanied by ground subsidence. Underground workings within such sites are subjected to loads that are greater than expected according to current hypotheses, which are the basis for calculations of rock pressure. It is established that the most probable mechanism of ground subsidence and residual deformation in underground workings could be the gravity load of the overlying strata of disintegrated and waterlogged rocks within a fault zone, which leads to instability of the rocks. Approximate stress estimations are made on the basis of the results of measurements of residual deformations of roof supports (linings).