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991.
Heavy metals in sediments of the Tecate River, Mexico 总被引:1,自引:0,他引:1
F. T. Wakida D. Lara-Ruiz J. Temores-Peña J. G. Rodriguez-Ventura C. Diaz E. Garcia-Flores 《Environmental Geology》2008,54(3):637-642
Ten sites along the Tecate River, Mexico were sampled to evaluate the cadmium, lead, nickel and chromium concentrations in
sediments. The result shows contamination for cadmium in most of the sites, where two sites were class 4 (polluted to strongly
polluted) according to geoaccumulation index proposed by Muller. Two sites were found polluted for all the heavy metals analyzed
(Cr, Cd, Pb and Ni), indicating the effect of anthropogenic activities. A correlation between Ni and Cd concentration had
been found indicating a common source. These metals are usually used in electroplating industry. The results of this study
can be used for decision makers to prioritize measures to control the pollution for these metals. 相似文献
992.
Cu-bearing pyroxene, Mg(Cu.56,Mg.44)Si2O6, has been synthesized by a flux method and crystal structure refinement has been performed by single crystal X-ray diffraction. It is found that the crystal structure is orthorhombic (space group Pbca) with unit cell dimensions of a=18.221(4), b=8.890(1), c=5.2260(7)Å and the cell volume of 846.5( )3Å3. In the M2-site one of the M-O bonds(M-O3B) is extremely expanded from 2.444(2) in enstatite to 2.732(2), thus the coordination polyhedron around M2-site is regarded as square pyramidal rather than square planar or octahedral. It is also found that the M1-site in the pyroxene structure is occupied almost exclusively by Mg, while the M2-site is almost evenly occupied by Mg and Cu. The observed extreme site preference shown by Cu2+ is unusual among the divalent cations with similar ionic sizes. 相似文献
993.
STRESS-METAMORPHISM AND ISOTOPIC AGE OF SHEAR ZONE GRANITOID TECTONITES OF IRTYSH SHEAR ZONE (ALTAI REGION) 总被引:1,自引:0,他引:1
B.M.Chikov V.A.Ponomachuk S.V.Zinoviev B.N.Lapin A.T.Titov A.V.Travin S.V.Palessky 《大地构造与成矿学(英文版)》2002,26(1):36-51
The Irtysh shear zone (ISZ) of Altai region is the lineament structure of the collision-suture type, where granites of Kalba complex and granodiorites of Zmeinogorsk complex are exposed to regional gneiss-formation and stress-metamorphic alterations. This study is based on detailed structural observations at special grounds using optical and electron microscopy, and on the behavior analysis of isotopic systems from altered granitoids.Within the ISZ area we have established the continuous rows of granitoid stress-metamorphism from initial recrystallization of protolite, its cataclasis and mechanical flaring up to complete recrystallization with alteration of mineral composition and formation of the streaky complexes of granite tectonites of blastomylonite and blastocataclasite types. The directed alteration of rocks has several impulse and is expressed by a change in morphology of mineral grains and their relations, magnification of deformation component in the rock structure, and formation of new mineral phases on the basis of initial ones without surface fluidization. At transformation of isotopic systems from granitoid, their feldspars,biotite and hornblende, we can observe “rejuvenation“ of the rock substrate from 270- 290 Ma for Kalba granitoids to 220-235 Ma for their tectonites, and for Rudny Altai granodiorites, their ages changes from 285-317 Ma to 232-257 Ma for their tectonites. 相似文献
994.
995.
Carlos Pecharromán T. González-Carreño Juan E. Iglesias 《Physics and Chemistry of Minerals》1995,22(1):21-29
The infrared complex permittivity functions of three varieties of maghemite, γ-Fe2O3, having different degrees of vacancy ordering, have been determined from their IR reflectance spectra, measured at near to normal incidence on pressed powder pellets. The optical constants therefrom obtained have been verified by using them in the simulation of the corresponding absorption spectra for KBr-diluted pellets, and these are in excellent agreement with the experimental spectra. All calculations are based on a procedure for the estimation of the effective dielectric function of a mixture, which incorporates percolation features, recently developed by the authors. 相似文献
996.
Constraints from Thorium/Lanthanum on Sediment Recycling at Subduction Zones and the Evolution of the Continents 总被引:20,自引:3,他引:20
Arc magmas and the continental crust share many chemical features,but a major question remains as to whether these features arecreated by subduction or are recycled from subducting sediment.This question is explored here using Th/La, which is low inoceanic basalts (<0·2), elevated in the continents(>0·25) and varies in arc basalts and marine sediments(0·090·34). Volcanic arcs form linear mixingarrays between mantle and sediment in plots of Th/La vs Sm/La.The mantle end-member for different arcs varies between highlydepleted and enriched compositions. The sedimentary end-memberis typically the same as local trench sediment. Thus, arc magmasinherit their Th/La from subducting sediment and high Th/Lais not newly created during subduction (or by intraplate, adakiteor Archaean magmatism). Instead, there is a large fractionationin Th/La within the continental crust, caused by the preferentialpartitioning of La over Th in mafic and accessory minerals.These observations suggest a mechanism of fractionation& foundering, whereby continents differentiate intoa granitic upper crust and restite-cumulate lower crust, whichperiodically founders into the mantle. The bulk continentalcrust can reach its current elevated Th/La if arc crust differentiatesand loses 2560% of its mafic residues to foundering. KEY WORDS: arc magmatism; continental crust; delamination; thorium; sediment subduction 相似文献
997.
N. T. Arndt N. A. Teixeira W. M. White 《Contributions to Mineralogy and Petrology》1989,101(2):187-197
Komatiite lava flows in the Crixás greenstone belt, Goiás, Brazil, have textures and volcanic structures typical of Archean
komatiites, but are geochemically most unusual. The flows are porphyritic and massive, or layered with spinifex upper parts
and olivine cumulate lower parts. MgO contents range from 18 to 40%. In such lavas, only olivine (and minor chromite) can
have crystallized, but neither major nor trace elements fall on olivine control lines. In MgO variation diagrams, CaO and
Sr fall on lines with slopes steeper than olivine control lines; SiO2, FeO, Na2O, K2O and Y show little systematic variation; Zr shows a large variation that does not correlate with MgO; and Al2O3 decreases markedly with decreasing MgO. The aberrant behaviour is highlighted by the REE (rare earth elements) in spinifex
and olivine cumulate layers from three flows: in the spinifex layers, chondrite-normalized REE patterns are hump-shaped with
maxima at Nd or Sm ((La/Sm)N=0.6, (Gd/Yb)N=1.6–2.3), whereas cumulate zones in the same flows have steadily sloping patterns, with LREE enriched relative to HREE ((La/Sm)N=1.3, (Gd/Yb)N=1.4). Neither normal magmatic processes acting during emplacement of the komatiites, nor thermal erosion and wall-rock assimilation
can explain these effects, and we speculate that elements commonly thought of as “immobile” (e.g. Al, Zr, REE) migrated during
hydrothermal alteration or metamorphism. A Pb-Pb whole rock isochron gave an age of 2,728±140 Ma and selected Sm-Nd analyses
an apparent isochron age of 2,825±98 Ma (ɛNd≈0). The Pb-Pb age is believed to be the approximate time of emplacement. Interpretation of the Sm-Nd data is complicated
by the evidence of mobility of REE. 相似文献
998.
Hajer Farroukh T. Mnif F. Kamoun L. Kamoun F. Bennour 《Arabian Journal of Geosciences》2018,11(23):760
Phosphogypsum and cement have been reported to improve the physicochemical properties of clayey soils. The present study aimed to investigate the behavior of various soils with different particle sizes and chemical and mineralogical compositions in the presence of phosphogypsum and cement mixed at various proportions. These hydraulic binders were assayed on three different soil samples, and their effects were examined using a battery of standardized tests, including the Atterberg limit, uniaxial compressive strength, Californian Bearing Rate (CBR) test, thermogravimetric analysis (TGA), microstructure observation (SEM), and X-ray diffraction tests. The results revealed a significant effect associated with the variation of phosphogypsum content in the soils. Keeping the cement content constant in the mixture, the continuous addition of phosphogypsum was noted to allow shifting the domain of plasticity to the highest water contents, which reduces the sensitivity of the soil to water and to increase the strength of soil. An increase of CBR index with the addition of phosphogypsum and cement is obtained. This treatment could have positively influenced the optimum moisture content and the maximal dry density. The mixture of soil-phosphogypsum and cement could give new forms such as ettringite and hydrate indicators of the improvement of the mechanical properties of the soil. This improvement varies from one soil to another, depending on its granularity and its mineralogy. The mineralogical composition of the soil, particularly kaolinite, amount, and size grading, have direct effects on the physical and mechanical properties of the soils under investigation. 相似文献
999.
D. Szymanowski B. S. Ellis J. F. Wotzlaw Y. Buret A. von Quadt I. Peytcheva I. N. Bindeman O. Bachmann 《Contributions to Mineralogy and Petrology》2016,171(12):106
Understanding the processes of differentiation of the Yellowstone–Snake River Plain (YSRP) rhyolites is typically impeded by the apparent lack of erupted intermediate compositions as well as the complex nature of their shallow interaction with the surrounding crust responsible for their typically low O isotopic ratios. A pair of normal-δ18O rhyolitic eruptions from the Heise eruptive centre in eastern Idaho, the Wolverine Creek Tuff and the Conant Creek Tuff, represent unique magmatic products of the Yellowstone hotspot preserving abundant vestiges of the intermediate differentiation steps leading to rhyolite generation. We address both shallow and deep processes of magma generation and storage in the two units by combining high-precision ID–TIMS U–Pb zircon geochronology, trace element, O and Hf isotopic studies of zircon, and Sr isotopic analyses of individual high-Mg# pyroxenes inherited from lower- to mid-crustal differentiation stages. The zircon geochronology confirms the derivation of both tuffs from the same rhyolitic magma reservoir erupted at 5.5941 ± 0.0097 Ma, preceded by at least 92 ± 14 ky of continuous or intermittent zircon saturation approximating the length of pre-eruptive magma accumulation in the upper crust. Some low-Mg# pyroxenes enclosing zircons predate the eruption by at least 45 ± 27 ky, illustrating the co-crystallisation of major and accessory phases in the near-liquidus rhyolitic melts of the YSRP over a significant period of time. Coeval zircon crystals are isotopically heterogeneous (two populations at εHf ~?5 and ?13), requiring the assembly of isotopically distinct melt pockets directly prior to, or during, the eruption. The primitive Mg# 60–90 pyroxenes are out of isotopic equilibrium with the host rhyolitic melt (87Sr/86Sri = 0.70889), covering a range of 87Sr/86Sri = 0.70705–0.70883 corresponding to ratios typical of the most radiogenic YSRP basalts to the least radiogenic YSRP rhyolites. Together with the low εHf in zircon, the Sr isotopic ratios illustrate limited assimilation dominated by radiogenic Archean crustal source materials incorporated into variably evolved YSRP melts as they progress towards rhyolitic compositions by assimilation–fractional crystallisation. 相似文献
1000.
The ability of an atmospheric general circulation model to reproduce fundamental features of the wintertime extratropical Southern Hemisphere (SH) circulation is evaluated with emphasis on the daily variability of the SH mean flow and the mean flow-transient perturbations interaction. Two 10-year simulations using a new version of the LMDZ GCM with a stretched grid scheme centered at 45 °S and forced by climatological SST are performed: a high (144Ꮡ) and low (64Ꭹ) horizontal resolution runs. The performance of both simulations was determined by comparing several simulated fields (zonal wind, temperature, kinetic energy, transient eddy momentum and heat fluxes, Eliassen-Palm fluxes, Eady growth rate and baroclinic conversion term) against the European Centre for Medium Range Weather Forecast reanalyses (ERA). High and low-resolution simulations are similar in many respects; in particular, both experiments reproduce the main patterns of the southern extratropical large-scale circulation satisfactorily. Increasing resolution does not improve universally some spurious aspects of the low resolution simulation (e.g. the cold bias in the high polar troposphere, the debilitated subtropical jet, the low baroclinic conversion rate). Those aspects present little sensitivity to the model resolution. The interaction between transient eddies and zonal mean flow are examined. The low-resolution experiment is able to qualitatively represent the acceleration/deceleration of the mean flow by transient perturbations, south/north of 30 °S with an accuracy similar to that of the high-resolution experiment. Although both experiments represent the baroclinic structure of the mean flow satisfactorily, the model underestimates some transient properties due to the underestimation of the baroclinic conversion term in middle latitudes. Such misrepresentation does not improve with increasing resolution and is related to the relatively weak meridional temperature gradient and the inadequate geographical distribution of the eddy heat fluxes. In particular, the eddy kinetic energy is always underestimated. Eddy kinetic energy does not improve convincingly with increasing resolution, suggesting that the adequate representation of the storm tracks is highly influenced by the physical parametrizations. 相似文献