We report the results of an experiment that produced a residue which closely matches the hydrocarbon component of the Murchison carbonaceous chondrite. This experiment suggests that the parent material of the meteoritic component originated as polycyclic aromatic hydrocarbon species in carbon stars during their later stages of evolution. The experiments also indicate that the pathway from those formation sites to eventual incorporation into the meteorite parent body involved hydrogenation in a plasma in the solar nebula or in H II regions prior to the solar nebula. This model is consistent with what is known about the meteoritic hydrocarbon component including deuterium abundance, the observation of cosmic infrared emission bands best attributed to polycyclic aromatic hydrocarbon molecules, and the inherent stability of these molecules that allows their formation in stars and subsequent survival in the interstellar medium. 相似文献
Earlier models of compressible, rotating, and homogeneous ellipsoids with gas pressure are generalized to include the presence of radiation pressure. Under the assumptions of a linear velocity field of the fluid and a bounded ellipsoidal surface, the dynamical behaviour of these models can be described by ordinary differential equations. These equations are used to study the finite oscillations of massive radiative models with masses 10M and 30M in which the effects of radiation pressure are expected to be important.Models with two different degrees of equilibrium are chosen: an equilibrium (i.e., dynamically stable) model with an initial asymmetric inward velocity, and a nonequilibrium model with a nonequilibrium central temperature and which falls inwards from rest. For each of these two degrees of equilibrium, two initial configurations are considered: rotating spheroidal and nonrotating spherical models.From the numerical integration of the differential equations for these models, we obtain the time evolution of their principal semi-diametersa1 anda3, and of their central temperatures, which are graphically displayed by making plots of the trajectories in the (a1,a3) phase space, and of botha1 and the total central pressurePc against time.It is found that in all the equilibrium radiative models (in which radiation pressure is taken into account), the periods of the oscillations of botha1 andPc are longer than those of the corresponding nonradiative models, while the reverse is true for the nonequilibrium radiative models. The envelopes of thea1 oscillations of the equilibrium radiative models also have much longer periods; this result also holds for the nonequilibrium models whenever the envelope is well defined. Further, as compared to the nonradiative models, almost all the radiative models collapse to smaller volumes before rebouncing, with the more massive model undergoing a larger collapse and attaining a correspondingly larger peakPc.When the mass is increased, the dynamical behavior of the radiative model generally becomes more nonperiodic. The ratio of the central radiation pressure to the central gas pressure, which is small for low mass models, increases with mass, and at the center of the more massive model, the radiation pressure can be comparable in magnitude to the gas pressure. In all the radiative models, the average periods as well as the average amplitudes of both thea1 andPc oscillations also increase with mass.When either rotation or radiation pressure effects or both are included in the equilibrium nonradiative model, the period of the envelope of thea1 oscillations is increased. The presence of rotation in the equilibrium radiative model, however, decreases this period.Some astrophysical implications of this work are briefly discussed. 相似文献
Using more than three million Landsat satellite images, this research developed the first global impervious surface area (GISA) dataset from 1972 to 2019. Based on 120,777 independent and random reference sites from 270 cities all over the world, the omission error, commission error, and F-score of GISA are 5.16%, 0.82%, and 0.954, respectively. Compared to the existing global datasets, the merits of GISA include: (1) It provided the global ISA maps before the year of 1985, and showed the longest time span (1972–2019) and the highest accuracy (in terms of a large number of randomly selected and third-party validation sample sets); (2) it presented a new global ISA mapping method including a semi-automatic global sample collection, a locally adaptive classification strategy, and a spatio-temporal post-processing procedure; and (3) it extracted ISA from the whole global land area (not from an urban mask) and hence reduced the underestimation. Moreover, on the basis of GISA, the long time series global urban expansion pattern (GUEP) has been calculated for the first time, and the pattern of continents and representative countries were analyzed. The two new datasets (GISA and GUEP) produced in this study can contribute to further understanding on the human’s utilization and reformation to nature during the past half century, and can be freely download from http://irsip.whu.edu.cn/resources/dataweb.php.
Summary Geochemical characteristics were systematically determined for Early Cretaceous samples of carbonatitic rocks from Eastern Paraguay (Rio Apa, Amambay and Central Provinces). The data show that all the occurrences have an enriched isotopic signature and that the carbonatites have negligible or absent crustal signature. A petrogenetic model (parent liquids, fractional crystallization, hydrothermal interactions and weathering) is proposed as a function of incompatible trace element, stable (O-C) and radiogenic (Sr-Nd) isotope variations with the aim to test the significance of carbonatitic complexes as a marker of the metasomatized subcontinental lithospheric mantle. The results indicate that the carbonatites and primary carbonates from eastern Paraguay, and those from the north eastern Paraná Basin (SE Brazil), were affected by metasomatic events distinct in time and composition.
Karbonatite aus Ost-Paraguay und ihre genetische Beziehung zu Kalium-Magmatismus: C O, Sr und Nd isotope
Zusammenfassung Die geochemischen Charakteristika von frühkretazischen Karbonatitproben aus Ostparaguay (Rio Alpa, Amambay und Zentrale Provinzen) wurden untersucht. Die Daten belegen, daß alle Vorkommen eine isotopische Anreicherungssignatur zeigen und daß ihnen eine entsprechende Krustensignatur fehlt. Ein Petrologisches Modell (Ausgangsschmelze, fraktionierte Kristallisation, hydrothermale Interaktion und Verwitterung) wird auf Grund der Verteilung der inkompatiblen Spurenelemente, der stabilen (C-O) und radiogenen (Sr-Nd) Isotope vorgeschlagen. Es versucht die Bedeutung der Karbonatitkomplexe als Markerhorizonte des metasomatischen subkontinentalen Mantels zu überprüfen. Die Ergebnisse zeigen, daß die Karbonatite und die primären Karbonate in Ostparaguay, und jene aus dem Paraná Becken SüdostBrasiliens durch zeitlich und zusammensetzungsmäßig unterschiedliche metasomatische Prozesse erfaßt wurden.
The unit-cell dimensions and crystal structure of sillimanite at various pressures up to 5.29 GPa have been refined from single-crystal X-ray diffraction data. As pressure increases, a and b decrease linearly, whereas c decreases nonlinearly with a slightly positive curvature. The axial compression ratios at room pressure are βa:βb:βc=1.22:1.63:1.00. Sillimanite exhibits the least compressibility along c, but the least thermal expansivity along a (Skinner et al. 1961; Winter and Ghose 1979). The bulk modulus of sillimanite is 171(1) GPa with K′=4 (3), larger than that of andalusite (151 GPa), but smaller than that of kyanite (193 GPa). The bulk moduli of the [Al1O6], [Al2O4], and [SiO4] polyhedra are 162(8), 269(33), and 367(89) GPa, respectively. Comparison of high-pressure data for Al2SiO5 polymorphs reveals that the [SiO4] tetrahedra are the most rigid units in all these polymorphic structures, whereas the [AlO6] octahedra are most compressible. Furthermore, [AlO6] octahedral compressibilities decrease from kyanite to sillimanite, to andalusite, the same order as their bulk moduli, suggesting that [AlO6] octahedra control the compression of the Al2SiO5 polymorphs. The compression of the [Al1O6] octahedron in sillimanite is anisotropic with the longest Al1-OD bond shortening by ~1.9% between room pressure and 5.29 GPa and the shortest Al1-OB bond by only 0.3%. The compression anisotropy of sillimanite is primarily a consequence of its topological anisotropy, coupled with the compression anisotropy of the Al-O bonds within the [Al1O6] octahedron. 相似文献