Equation of state of MgGeO3 perovskite to 65 GPa: comparison with the post-perovskite phase

The equation of state of MgGeO₃ perovskite was determined between 25 and 66 GPa using synchrotron X-ray diffraction with the laser-heated diamond anvil cell. The data were fit to a third-order Birch–Murnaghan equation of state and yielded a zero-pressure volume (V ₀) of 182.2 ± 0.3 Å³ and bulk modulus (K ₀) of 229 ± 3 GPa, with the pressure derivative (K′₀ = (?K ₀/?P) _T ) fixed at 3.7. Differential stresses were evaluated using lattice strain theory and found to be typically less than about 1.5 GPa. Theoretical calculations were also carried out using density functional theory from 0 to 205 GPa. The equation of state parameters from theory (V ₀ = 180.2 Å³, K ₀ = 221.3 GPa, and K′₀ = 3.90) are in agreement with experiment, although theoretically calculated volumes are systematically lower than experiment. The properties of the perovskite phase were compared to MgGeO₃ post-perovskite phase near the observed phase transition pressure (～65 GPa). Across the transition, the density increased by 2.0(0.7)%. This is in excellent agreement with the theoretically determined density change of 1.9%; however both values are larger than those for the (Mg,Fe)SiO₃ phase transition. The bulk sound velocity change across the transition is small and is likely to be negative [?0.5(1.6)% from experiment and ?1.2% from theory]. These results are similar to previous findings for the (Mg,Fe)SiO₃ system. A linearized Birch–Murnaghan equation of state fit to each axis yielded zero-pressure compressibilities of 0.0022, 0.0009, and 0.0016 GPa^?1 for the a, b, and c axis, respectively. Magnesium germanate appears to be a good analog system for studying the properties of the perovskite and post-perovskite phases in silicates.     

Benthic foraminifers in upper Quaternary sediments of the southern Bering Sea: Distribution and paleoceanographic interpretations

Composition and distribution of benthic foraminifers, being coupled with isotopic-geochemical data on Upper Pleistocene and Holocene sediments from the southern Bering Sea (Core GC-11; 53°31′ N, 178°51′E, water depth 3060 m), demonstrate variations in bottom water properties during the last 54 kyr. Their abundance increased to some extent during short periods corresponding to warm Dansgaard-Oeshger interstadials 14, 12, 8, and 2 of marine isotopic stages (MIS) 3 and 2. The first and second deglaciation phases separated by the Younger Dryas cooling episode are marked by significant abundance peaks of benthic foraminifers (an order magnitude higher than in the glacial period), although their share in community of benthic and planktonic foraminifers taken together decreases. Species typical of stable high-productivity areas gain the dominant position. A significant proportion of agglutinated species in the Holocene sediments is indicative of Ca ions deficiency that accelerates dissolution of carbonate tests up to their disappearance approximately 2.5–3 ka ago.     

Secular variations of the upper crust composition: Implication of geochemical data on the Upper Precambrian shales from the Southern Urals western flank and Uchur-Maya region

In the mid-1980s, it was concluded based on geochemical study that Th, Sc, La concentrations and ratios Th/Sc, La/Sc and Eu/Eu* did not wary significantly in the post-Archean time. It was impossible to judge about compositional variations of upper crust during the Riphean and Vendian, because data of that time characterized a limited number of samples from the post-Archean basins of Australia, New Zealand, and Antarctic. Considered in this work are variations of Eu/Eu*, LREE/HREE, Th/Sc, and La/Sc ratios in Upper Precambrian fine-grained siliciclastic rock of the Southern Urals western flank (Bashkirian meganticlinorium) and Uchur-Maya region (Uchur-Maya plate and Yudoma-Maya belt). As is established, only the Eu anomaly in the studied siliciclastic rocks is practically identical to this parameter of the average post-Archean shale. Three other parameters plot on the Riphean-Vendian variation curves with positive and negative excursions of diverse magnitude, which do not coincide always in time. It is assumed that these excursions likely mark stages of local geodynamic activity, destruction of pre-Riphean cratons, and progressing recycling of sedimentary material during the Riphean.     

New data on Sr-and C-isotopic chemostratigraphy of the Upper Riphean type section (Southern Urals)

New data on Sr-and C-isotopic systematics of carbonate rocks from the Upper Riphean stratotype (Karatau Group of the southern Urals) are obtained for several southwestern sections of the Bashkirian meganticlinorium, which have not been studied before. The results obtained supplement the Sr-and C-isotopic information for the group upper horizons thus detailing chemostratigraphic characterization of the entire succession. Limestone and dolostone samples used to analyze the Sr isotope composition satisfy strict geochemical criteria of the isotopic system retentivity and have been subjected to preliminary treatment in ammonium acetate to remove secondary carbonate phases. Data on 255 samples of carbonate rocks (171 studied for the first time) show that δ¹³C value varies in the Karatau Group succession from ?2.8 to +5.9 ‰ V-PDB with several in-phase excursions from the general trend in all the sections studied in the area 90 × 130 km. The δ¹³C variation trend demarcates several levels in the carbonate succession of the Karatau Group suitable for objectives of regional stratigraphy and for C-isotope chemostratigraphic subdivision of the Upper Riphean. The results of Sr isotopic analysis of 121 samples (51 unstudied before) from the Karatau Group imply that rocks in its lower part (the Katav Formation and basal horizon of the Inzer Formation) experienced considerable secondary alterations, while limestones and dolostones of the overlying interval of the group are frequently unaltered. In the “best” samples satisfying geochemical criteria of the isotopic system retentivity, the ⁸⁷Sr/⁸⁶Sr initial ratio increases from 0.70521–0.70532 in the lower Inzer deposits to 0.70611 in the upper Min’yar carbonates, decreasing to <0.70600 near the top of the latter. Above the regional hiatus separating the Min’yar and Uk formation, this ratio grows from 0.70533 to 0.70605–0.70609 in the limestone succession of the last formation.     

Diversity and stages in evolution of conodontophorids and bivalve mollusks in Triassic seas of Siberia and the Far East

Comparative analysis of taxonomic diversity dynamics of condontophorids from Boreal (Arctic regions of Russia) and Tethyan (Northwest Pacific) paleobasins showed that they had most favorable habitat environments in tropical seas. In the Boreal realm, condontophorids went through three stages of evolution comprising probably four substages and four phases, whereas three stages with six substages and twelve phases are distinguished in the Tethyan realm. The most important abiotic factors that controlled development of conodontophorids are paleotemperature of seawater and paleogeographic settings. Renewals in taxonomic composition conodontophorids and diversification of their assemblages have been confined to moments of paleotemperature and/or sea level rise. The comparative analysis of stages in evolution of conodontophorid and bivalve assemblages has been carried out. As is established, the peak taxonomic diversity of bivalves in Boreal seas was in the Late Triassic after the diversity minimum of the Early Triassic time. In contrast, conodontophorids were most diverse in the Olenekian Age.     

Alteration, evaluation and use of extremaduran granite residues

The necessity of eliminating debris from a granite quarry has awakened an interest in applications of by-products, called “marginal arids”, in different fields, like construction and foundations for roadways, restoration, material for the manufacture of artificial rocks, and artesian products etc. Conclusions obtained from the results of tests carried out by X-ray diffraction of granite quarry by-products in Extremadura, Spain, submitted to different treatments, are established. Test pieces from two quarries are analyzed and compared generally and specifically, for commercial use. Finally, conclusions relating to essays in test pieces and mineral dynamics of marginal arid granite are exposed.     

Ballooning instability and oscillations of coronal loops

The excitation of the ballooning instability by the eigenoscillations of coronal loops is analyzed using the energy method. The second variation of the potential energy for the case of a plasma—plasma boundary is obtained via the linearized ideal MHD equations. It is shown that the eigenmodes of a magnetic tube and of a toroidal coronal loop coincide in a first approximation. The bending oscillations of the loops are able to excite the ballooning instability when β ? 1. The effects of the instability in solar coronal loops are discussed.     

Relations between climatic variability and hydrologic time series from four alluvial basins across the southwestern United States

Hydrologic time series of groundwater levels, streamflow, precipitation, and tree-ring indices from four alluvial basins in the southwestern United States were spectrally analyzed, and then frequency components were reconstructed to isolate variability due to climatic variations on four time scales. Reconstructed components (RCs), from each time series, were compared to climatic indices like the Pacific Decadal Oscillation (PDO), North American Monsoon (NAM), and El Niño-Southern Oscillation (ENSO), to reveal that as much as 80% of RC variation can be correlated with climate variations on corresponding time scales. In most cases, the hydrologic RCs lag behind the climate indices by 1–36 months. In all four basins, PDO-like components were the largest contributors to cyclic hydrologic variability. Generally, California time series have more variation associated with PDO and ENSO than the Arizona series, and Arizona basins have more variation associated with NAM. ENSO cycles were present in all four basins but were the largest relative contributors in southeastern Arizona. Groundwater levels show a wide range of climate responses that can be correlated from well to well in the various basins, with climate responses found in unconfined and confined aquifers from pumping centers to mountain fronts.     

Mineralogy and PT formation conditions of lead-zinc ore at the Dzhimidon deposit, north Ossetia

The mineralogy and PT formation conditions of the Dzhimidon Pb-Zn deposit in the Sadon ore district are considered. The deposit is localized in metamorphic rocks of the Buron Formation, which pertain to the pre-Jurassic basement (lower structural stage) and are cut through by Upper Paleozoic granitoids, and in the Lower Jurassic terrigenous sequence (upper structural stage). Orebodies as quartz-sulfide veins are mainly hosted in the metamorphic rocks. Galena, sphalerite, chalcopyrite, pyrite, pyrrhotite, and arsenopyrite are the most abundant sulfides, while quartz, carbonates, chlorite, sericite, and feldspar are gangue minerals. The bismuth mineralization identified at this deposit for the first time is represented by diverse phases of the Ag-Pb-Bi-S system. Five stages of the ore deposit formation are recognized: a premineral stage (quartz-feldspar), three ore-bearing stages (pyrite-arsenopyrite, pyrrhotite-chalcopyrite-sphalerite, and arsenopyrite-sphalerite-galena), and a postmineral stage (quartz-calcite); each stage comprises one or several mineral assemblages. The study of fluid inclusions in quartz, calcite, and sphalerite of the premineral, ore-forming, and postmineral stages has shown that the ore was deposited mainly from Na chloride solution with a salinity varying from >22 to <1.0 wt % NaCl equiv at a temperature from 460 to ～120°C and 430–290 bars pressure. The third stage was characterized by an abrupt increase in temperature and by the appearance of Mg(Fe,Ca) chloride solutions equally with Na chloride fluids, presumably owing to the emplacement of granite porphyry.     

Apparent angular sizes of the sources of microwave subsecond pulses and electron-density fluctuations in the lower solar corona

Data on the visible angular sizes of sources of microwave subsecond pulses (MSPs) obtained using the Siberian Solar Radio Telescope are analyzed assuming a dominant role for scattering on small-scale electron-density inhomogeneities in the solar corona. The observed dependence of the angular sizes of MSPs on the distance from the solar-disk center confirms that the MSP sources are localized in low layers of the solar corona. Both absolute and fractional levels of small-scale electron-density fluctuations have been estimated. These estimates suggest that flicker-noise-type turbulence power spectra are formed in the lower corona, and are preserved in the solar-wind acceleration region. A composite dependence of the scattering angle of a sounding radio wave on distance from the Sun is presented.