Elpasolite from hyperalkaline pegmatite of the Khibiny pluton, Kola Peninsula. Symmetry of elpasolite

Elpasolite, K₂NaAlF₆, has been found for the first time in a pegmatite related to peralkaline foid syenite at Mt. Koashva, Khibiny alkaline pluton, Kola Peninsula, Russia, as pale pink octahedral crystals up to 2 mm in size within cavities in the natrolite core of pegmatite in association with amicite, sodalite, aegirine, pectolite, catapleiite, sitinakite, lemmleinite-K, and vinogradovite. The chemical composition determined with an electron microprobe is as follows, wt %: 31.53 K; 9.22 Na; 11.20 Al; 47.21 F; total is 99.16. The empirical formula is K_1.96Na_0.98Al_1.01F_6.05. The infrared spectrum is given. The crystal structure has been refined to R = 0.030, space group Fm $ \bar 3 Elpasolite, K₂NaAlF₆, has been found for the first time in a pegmatite related to peralkaline foid syenite at Mt. Koashva, Khibiny alkaline pluton, Kola Peninsula, Russia, as pale pink octahedral crystals up to 2 mm in size within cavities in the natrolite core of pegmatite in association with amicite, sodalite, aegirine, pectolite, catapleiite, sitinakite, lemmleinite-K, and vinogradovite. The chemical composition determined with an electron microprobe is as follows, wt %: 31.53 K; 9.22 Na; 11.20 Al; 47.21 F; total is 99.16. The empirical formula is K_1.96Na_0.98Al_1.01F_6.05. The infrared spectrum is given. The crystal structure has been refined to R = 0.030, space group Fm m, a = 8.092 ?. The result of a special X-ray powder diffraction study confirmed the suggestion made by Morss (1974) that reflections violating space group Fm m in some published X-ray powder patterns of natural elpasolite are Kβ-lines. Original Russian Text ? I.V. Pekov, N.V. Chukanov, N.N. Kononkova, N.V. Zubkova, M.Kh. Rabadanov, D.Yu. Pushcharovsky, 2007, published in Zapiski Rossiiskogo Mineralogicheskogo Obshchestva, 2007, No. 6, pp. 76–84.     

Rare earth elements in tourmaline and chlorite from tin-bearing assemblages: Factors controlling fractionation of REE in hydrothermal systems

The REE distribution in minerals from tin-bearing ore-magmatic systems of the Russian Far East, including the Komsomolsk, Khingan, and Badzhal districts in the Amur region and the Kavalerovo, Lesozavodsk, Voznesenka, Furmanovo, and other districts in Primorsky krai, has been studied. The main attention was focused on tourmaline and chlorite; in addition, associated biotite, feldspar, apatite, fluorite, and carbonates were examined. The major factors affecting the REE distribution in the studied minerals are the temperature, Eh, and pH of the mineral-forming medium; crystal chemistry; partition coefficients of REE between fluid and minerals; and complexation that disturbs the coherent behavior of REE. Fluid evolution at different stages is characterized.     

Normative quartz as an indicator of the mass transfer intensity during the postmagmatic alteration of the Botuobinskaya pipe kimberlites (Yakutia)

The intensity of postmagmatic processes in the Botuobinskaya pipe kimberlites was estimated from the calculated content of normative secondary quartz (Q). Several simple algorithms are proposed to calculate the Q content from chemical analyses of kimberlites. Ten groups of altered kimberlites have been recognized from the Q contents. The contents of MgO, some trace elements, and LREE in the groups, the contents of Cr and Ca of crimson garnets, the diamond contents of kimberlites, and the average weight of diamonds decrease as the Q content increases. It is shown that the negative SiO₂–MgO correlation is the most effective indicator of the postmagmatic alteration of kimberlites. As the degree of their secondary alteration increases, the kimberlites transform into an assemblage of quartz and clay minerals enriched in some trace elements and almost completely lacking REE and diamonds.     

The Seyfert 1 galaxy Ark 120. Spectral variability in 1992–2005

We have studied the variability of the Hβ line and the adjacent continuum in the spectrum of the Seyfert galaxy Ark 120, based on spectral observations of the galaxy’s nucleus obtained in the Crimea in 1992–2005, supplemented by published data for 1988–1996. Irregular variability on various timescales (years to days) can be accompanied by periodic brightness variations in both the continuum and the Hβ line, with a period of P ～ 430 days and an amplitude of Δm ～ 0.2 ^m in the continuum, which were traced for more than 13 cycles. In total, in 1988–2005, the flux variations in the line lag those in the continuum by 55 ± 9 days if calculated from the peak of the cross correlation function, or by 72 ± 7 days, if calculated from the centroid of the CCF. The delay is correlated with the continuum brightness, increasing when the continuum flux increases. The Hβ line profiles indicate both a high degree of diversity and the presence of features that recur after various extended time intervals. Analysis of the evolution of the differences between each individual normalized line profile and the mean normalized profile indicates systematic motion of excesses relative to the average profile from negative to positive radial velocities. In contrast, parts of the Hβ line with low radiation relative to the mean normalized profile evolve in the opposite direction (from the red to the blue Hβ wing). This pattern is also typical for the rotating broad-line region, if this region has the form of a disk. The rotation period exceeds 9000–10000 days, or 25–27 years. The size of the broad-line region calculated form this period corresponds to a reverberation time of no fewer than 30 days, consistent with the results of cross-correlation analysis.     

Time-dependent stress change during failure of rocks

The energy balance of a solid subject to fracture has been explored using heat and mass transfer equations with regard to the volumetric and superficial components. In the suggested model, brittle fracture of a cracked solid considered as a heterogeneous two-phase medium is described by an equation analogous to the Griffith’s criterion for propagation of a single crack. The derived equation is used, together with estimates of relative change in specific interface area, to study the respective change of free strain energy and pressure in rocks associated with failure.     

MT Ser, a binary blue subdwarf

We have classified and determined the parameters of the evolved close binary MT Ser. Our moderate-resolution spectra covering various phases of the orbital period were taken with the 6-m telescope of the Special Astrophysical Observatory. The spectra of MT Ser freed from the contribution of the surrounding nebula Abell 41 contained no emission lines due to the reflection effect. The radial velocities measured from lines of different elements showed them to be constant on a time scale corresponding to the orbital period. At the same time, we find effects of broadening for the HeII absorption lines, due to the orbital motion of two hot stars of similar types. As a result, we classify MT Ser as a system with two blue subdwarfs after the common-envelope stage. We estimate the component masses and the distance to the object from the Doppler broadening of the HeII lines. We demonstrate that the age of the ambient nebula, Abell 41, is about 35 000 years.     

Tidal and Meteorological Forcing of Suspended Sediment Flux in a Muddy Mesotidal Estuary

Although the supply and fate of suspended sediment is of fundamental importance to the functioning and morphological evolution of muddy estuaries, reliable sediment budgets have been established in only a few cases. Especially for smaller estuaries, inadequate bathymetric surveys and a lack of intertidal sedimentation data often preclude estimation of the sediment budget from morphological change, while instrument-derived residual fluxes typically lie well within the errors associated with measurement of much larger gross tidal transports. Given suitably long-term records of continuously monitored suspended sediment concentration (SSC), however, analysis of the major scales of variation in sediment transport and their relation to hydrodynamic and meteorological forcing permits qualitative testing of hypotheses suggested by directly measured residual fluxes. This paper analyzes data from a 1-year acoustic Doppler profiler deployment in the Blyth estuary, a muddy mesotidal barrier-enclosed system on the UK east coast. Flux calculations indicate a small sediment import equivalent to just 1.5% of the gross flood tide transport. Little confidence can be assigned to either the magnitude or direction of such a small residual when considered in isolation. However, the inference that the sediment regime is finely balanced is qualitatively supported by the close similarity between flood-tide and ebb-tide SSC values. Singular spectrum analysis of the SSC time series shows the expectedly large contributions to the variance in SSC at intratidal and subtidal (semimonthly and monthly) scales but also picks out intermittent variability that is initially attributed to a combination of non-tidal surge and wind stress forcing. Closer examination of the data through cross-correlograms and event-scale analysis indicates that local meteorological forcing is the major factor. Acting through the resuspension of intertidal mudflat sediments at times of strong westerlies, meteorological forcing is directly implicated in episodic sediment export from the estuary. Thresholding of tide-averaged fluxes using a range of critical wind stress values further indicates that ‘tide-dominated’ (i.e., low wind stress) and ‘wave-dominated’ (high wind stress) conditions are associated with sediment import and export. Sediment balance is potentially sensitive to the frequency of high wind stress events, since the associated sediment exports are several times larger than the average import under calm conditions. Intermittent meteorological forcing may thus exert an important control on the sedimentary balance of otherwise tidally dominated muddy estuarine systems, and the role of wind climate should not be overlooked in studies of estuary response to environmental change.     

Mineral assemblages of titanium-zirconium sands at the Central deposit,the east European platform

The study of mineral assemblages at the Central deposit allowed us to substantially refine the evolutionary model of the deposit and reveal the two main factors that control the variability of its mineralic space: (1) heterogeneity of the ore layer, consisting of a sublittoral bottom placer (the lower part) and a subaerial dune complex partly reworked in the course of a new transgression (the upper part), and (2) postore epigenetic alteration of the ore constituent of sands, which affected the quality of ore concentrates. The results obtained will be used in geological and technological mapping and development of the production program.     

Geochemical types of Volkhovites and possible diamond resource potential of areas occupied by Holocene fluidisites

Volkhovites—tektite-like glasses—have been detected in the Holocene glacial drift along the right bank of the Volkhov River. A cryptomagmatic model of their formation and pre-Holocene age of volkhovite melts, cinder, and frothed glasses has been suggested (Skublov et al., 2007). Four geochemical types of volkhovites are distinguished: (1) manganous (Mn, Fe, Cr, V, Si, Nb, Pb, H), (2) magnesian (Mg, Al, Ti, F, B), (3) potassic (K, Rb, Cs), and (4) calcic (Ca, REEs, Ba, U, Th, Ta, Hf, Y, Sc, Cl). In light of the geochemical data, volkhovites are regarded as natural silicate glasses of kimberlite-carbonatite composition. Their types are called kimberlitic (Mn type), kimberlitic-carbonatitic (Mg type), lamproitic-carbonatitic (K type), and carbonatitic (Ca type). Volkhovites are suggested to be indicators of undiscovered diamond mineralization of kimberlite or carbonatite (Chagatai) types.     

Temporal variations in the position of the heliospheric equator

It is shown that the centroid of the heliospheric equator undergoes quasi-periodic oscillations. During the minimum of the 11-year cycle, the centroid shifts southwards (the so-called bashful-ballerina effect). The direction of the shift reverses during the solar maximum. The solar quadrupole is responsible for this effect. The shift is compared with the tilt of the heliospheric current sheet.