Differences in organotin accumulation in relation to life history in the white-spotted charr Salvelinus leucomaenis

To examine the accumulation pattern of organotins (OTs) in relation to the migration of diadromous fish, tributyltin (TBT) and triphenyltin (TPT) and their derivatives were determined in the muscle tissue of both sea-run (anadromous) and freshwater-resident (nonanadromous) types of the white-spotted charr Salvelinus leucomaenis. Ontogenic changes in otolith strontium (Sr) and calcium (Ca) concentrations were examined along life history transect to discriminate migration type. Mean Sr:Ca ratio from the core to the edge of the otolith in sea-run individuals was significantly higher than those in freshwater-resident one. There were no significant correlations in S. leucomaenis between OT accumulation and various biological characteristics. It is noteworthy that TBT and TPT concentrations in sea-run type were significantly higher than those in freshwater-resident individuals, although they are both of the same species. These results suggest that sea-run S. leucomaenis have a higher ecological risk of OT exposure than freshwater-residents during their life histories.     

Hollow fiber liquid-phase microextraction as clean-up step for the determination of organophosphorus pesticides residues in fish tissue by gas chromatography coupled with mass spectrometry

Hollow fiber liquid-phase microextraction (HF-LPME) technique was used as a clean-up procedure for the determination of organophosphorus pesticides (OPPs) in fish tissue. In this study, eight OPPs were first extracted with acetone from fish sample, the organic extract after rotatory evaporation was then redissolved with water-methanol (95:5, v/v) solution, followed by polyvinylidene difluoride (PVDF) HF-LPME. Experimental HF-LPME and other sample preparation conditions were carefully investigated and optimized. Under the optimum conditions, good linearity were observed in the range of 20-500 ng/g, limits of detections (LODs) were in the range of 2.1-4.5 ng/g. The repeatability and recovery of the method also showed satisfactory results. Compared with traditional sample preparation method for the determination of OPPs in fish tissue, the method developed in this study eliminated the solid phase extraction (SPE) step, simplified the sample preparation procedure and lowered the cost of analysis.     

A cleaner river: long term use of semipermeable membrane devices demonstrate that concentrations of selected organochlorines and PAHs in the Brisbane River estuary, Queensland have reduced substantially over the past decade

We first used semipermeable membrane devices as samplers to evaluate concentrations of organochlorines and PAHs in the Brisbane River in 1998. Here we revisit this work and repeat the study a decade later in the same season (summer), also taking account of results from a similar study involving PAHs in the summer of 2001-2002. The accumulation of organochlorines and most PAHs in the samplers in the recent assessment was substantially less than in the 1998 deployment, suggesting that the ambient concentrations of these chemicals have decreased considerably over the last decade. In all cases there was high reproducibility of the mass of chemicals accumulated in the sampler. We used performance reference compounds in the later deployment, and assuming that the kinetics were similar in both deployment periods, we estimate that the concentration of dieldrin, the organochlorine found at highest concentrations, decreased from approximately 3.9 ng/L to about 1.4 ng/L. The decrease of most other analytes of interest including DDE and DDD was greater, potentially indicating that dieldrin is still entering the Brisbane River through run-off from urban areas where it was used widely for treatment of termites until 1995. DDT use in Australia ceased in the mid 1980s.     

Occurrence of the toxic dinoflagellate Ostreopsis cf. ovata in relation with environmental factors in Monaco (NW Mediterranean)

To study environment characteristics favoring the toxic benthic dinoflagellate Ostreopsis cf. ovata, a survey was conducted in Monaco (NW Mediterranean Sea), in summers 2007 and 2008. Epiphytic and planktonic blooms occurred almost simultaneously and a high variation of abundances at low spatial scales was observed. An early and very marked bloom occurred in 2007, compared to a later and less abundant development in 2008. These distinct patterns in bloom timing corresponded with very different hydroclimatic scenarios in 2007 (hot spring and relatively cold summer) and 2008 (standard year compared to the median year profile estimated with data from 1995 to 2008). No clear impacts of summer seawater temperature, rainfall or nutrient concentrations were evident. Strong wind may favor the dispersal of benthic and planktonic cells. Our study suggests that further investigations are needed to examine the potential role of Ostreopsis nutritional mode (i.e. autotrophy vs. mixotrophy).     

Contamination status of POPs and BFRs and relationship with parasitic infection in finless porpoises (Neophocaena phocaenoides) from Seto Inland Sea and Omura Bay, Japan

Contamination status of brominated flame retardants (BFRs) and persistent organic pollutants (POPs) in blubber of finless porpoises (Neophocaena phocaenoides) stranded along the coasts of Seto Inland Sea and Omura Bay in Japan were investigated. Levels of PCBs, DDTs and CHLs were significantly higher than those of HCHs, HCB, PBDEs and HBCDs. Concentrations of PBDEs and HBCDs, as well as organochlorine compounds in males increased with body length (p<0.05). Among 14 PBDE congeners analyzed, BDE-47 was the predominant, which is similar to those generally reported in biota. PBDEs, HBCDs and PCBs showed no obvious temporal trend in concentrations during the study period, suggesting continuous environmental release of these chemicals. On the other hand, levels of DDT, CHLs and HCHs have decreased. Concentrations of PCBs in liver trematode infected individuals were significantly higher than those in not infected individuals, implying there could be a relationship between contaminant levels and parasitic infection.     

Contamination status and spatial distribution of organochlorine compounds in fishes from Nansei Islands, Japan

Two species of fishes (n=52; tilapia and mullet) from industrialized and urbanized areas of Okinawa Island (Manko-Noha river, Hija river and Shikaza river) and from a remote area of Ishigaki Island (Anparu mudflat), Japan were collected between August 2005 and July 2006, and analyzed for five organochlorine compounds (OCs), viz., DDTs, PCBs, CHLs, HCHs and HCB. Concentrations and the contamination patterns of OCs in fishes varied between locations. Considerable residue levels of OCs, especially CHLs and DDTs were found in both fishes from the main Okinawa Island. These levels were relatively higher than the reported values for seafood from Japanese coasts, indicating that even now pollution sources of these contaminants still exist in this region. On the other hand, lower concentrations of OCs were detected in fishes from Ishigaki Island waters than those of other Japanese coastal waters, suggesting that this region is less contaminated by OC contaminants.     

Accumulation of trace elements in harp seals (Phoca groenlandica) from Pangnirtung in the Baffin Island, Canada

Nineteen trace elements were determined in liver, muscle, kidney, gonads, and hair of 18 harp seals (Phoca groenlandica) from Pangnirtung in the Baffin Island, Canada. Concentrations of V, Mn, Fe, Cu, Mo, Ag, and Hg in the liver, Co, Cd, and Tl in the kidney, and Ba and Pb in the hair were significantly higher than those in other tissues. Significant positive correlations between Hg concentrations in the hair, and liver, kidney and testis imply usefulness of the hair sample for non-destructive monitoring of Hg in the harp seals. It is suggested that whereas Hg preferentially accumulates in the liver, the accumulation in other tissues is induced at higher hepatic Hg levels. In contrast, Se may not be accumulated in other tissues compared with the liver even at higher hepatic Hg levels because of the presence of excess Se for Hg detoxification in other tissues.     

岩石破裂以及破裂前信号的演变

地震是大量的岩石破裂事件.很多大地震之前都存在瞬态信号:电磁信号、磁场变化、电离层扰动、土壤导电率的变化以及其他震前信号.令监测人员奇怪的是,在震前短时间内一些震前信号会衰弱甚至消失不见.岩石中应力活化电流的发现提供了一个可能的解释,应力能够激活岩石中的移动电荷载体,即电子空位缺陷(electron vacancy d...     

高密度地震观测揭示的2004年新潟县中部地震的凹凸体和障碍体

使用由极密集的临时地震台台网观测的余震到时,阐明了2004年新潟县中部地震主震断层的高分辨率速度结构。评估了速度结构与滑动、应力变化及余震分布的空间关系。根据运动学滑动模型,结合三维地壳结构,计算了断层上静态应力降的分布。具有低余震活动性的高速体十分接近主震的震源,并扩展到了断层的东北侧。该高速体大致与凹凸体重合,其同震滑动量和静态应力降高于周边地区。相比之下,在该高速体的浅外围观测到了负应力降区,沉积厚度向西南方向急剧增加且该区余震活动频繁。我们认为断层破坏区周围围岩的结构非均匀性具有控制主震断层动态破裂过程的显著潜势。     

日本南海弧前西端之下俯冲的九州—帕劳海岭的地震构造意义

作为菲律宾海板块残余岛弧的九州—帕劳海岭正沿着日本南海海槽的最西端俯冲于欧亚板块之下。沿走向布设的地震反射剖面显示出沿弧前增生楔前缘俯冲的九州—帕劳海岭70km宽的构造影像。地磁异常特征、海底地形特征、广角折射数据和陆地地貌证据等使得我们能够将俯冲海岭在弧前的延伸段一直追踪至九州岛的东部。正在俯冲的九州—帕劳海岭携带有大量冗余物质,可能具有相对较大浮力,因此在深部俯冲时与上覆板块的碰撞具有较大的抗性。有鉴于此,我们推测在俯冲海岭和上覆板块基底的接触区之间存在局部大应力构造。此局部大应力区人们已标出有历史冲断层型中等级别地震(6~7级)。当九州—帕劳海岭俯冲至深部时,漂浮的俯冲海岭其两侧的翼部更容易被撕裂而形成板块破裂。我们认为,俯冲的九州—帕劳海岭在深部不仅起到地震凹凸体的作用,而且产生板块破裂作为地震障碍体抑制邻近的日向段巨大逆冲地震的破裂传播。