Experimental study of the heterogeneous reactivity between atomic chlorine and palmitic acid films

The present study focuses on the heterogeneous reaction between gaseous atomic chlorine and solid palmitic acid films, used as a proxy of the fatty acids detected in atmospheric airborne particles. This reaction is investigated in a coated wall flow tube reactor coupled to a molecular beam mass spectrometer. The reactive surfaces were prepared by coating the inner surface of the reactor. The initial Cl˙ and Cl₂ uptake coefficient measured for these heterogeneous reactions is found to be fast: γ_o ^Cl?=?0.07. The rapid formation of hydrogen chloride corresponding with the disappearance of atomic chlorine is highlighted. Furthermore, the formation of new chlorinated species on the solid substrate has been detected by TOF SIMS analysis leading to an ageing process of the surface. A heterogeneous recombination of Cl atoms to Cl₂ molecules was observed for aged surfaces.     

Stark Broadening in Compact Stars: Xe VI Lines

We will consider Stark broadening of non hydrogenic spectral lines in the impact approximation in compact stars: pre-white dwarf and white dwarf atmospheres. In order to show an example, Stark broadening parameters have been calculated, using the impact semiclassical perturbation approach for four Xe VI spectral lines. Obtained results have been used to demonstrate the influence of Stark broadening in DA and DB white dwarf atmospheres.     

Criteria for the identification of ventifacts in the geological record: A review and new insights

Ventifacts (wind-worn stones) are typical of terrestrial environments remained very long without any vegetation, under hot or cold climates. Therefore, within the sedimentary record, they can allow recognizing desert conditions, even where no aeolian dune deposits are preserved. There seems that, in the recent literature, pebbles and cobbles from various palaeoenvironments were mistaken for ventifacts. This may partly be explained by the scatter and relative scarcity of illustrations to which refer. The aim of this paper is to help recognizing ventifacts in the sedimentary record, based on a critical review of the diagnostic properties generally used, and on new studies permitting to suggest additional criteria. After an evaluation of the sedimentary contexts favourable to preserving ventifacts, the distinctive characters that could be seen on each one are treated in order of increasing alteration of the original appearance: surface features, medium-scale features (new types of pit especially), and general shape. Finally, the problem of distinguishing between ventifacts and aquafacts is approached.     

How do Local People Value Rural Waterways? A Study in the Upper Catchments of South East Queensland’s Rivers

In Integrated Catchment (or Watershed) Management, the impacts of upstream conditions and actions on downstream environments and people is a key issue. Knowing upstream people’s values towards waterways is, therefore, important for community engagement and the development of publicly acceptable management approaches. This qualitative study applies Kellert’s framework of relational values to explore the types and diversity of people’s values towards the upper catchments of South East Queensland, Australia, and tests the “universality” of Kellert’s framework. We found the full range of values identified by Kellert with some variations and elaborations in content. People living, working, and enjoying recreation in the upper catchments have affection for their local waterways and a moral inclination to protect them. This extends our understanding of how people value these waterways, which is more often depicted in terms of utilitarian and economic value. The findings provide managers with new opportunities for engaging with local communities and waterway users.     

Volcanisme de l'ı̂le aux Pingouins,archipel Crozet,témoin de l'hétérogénéité du manteau fertile au sud de l'océan IndienPenguins Island,Crozet archipelago,volcanic evidence for a heterogeneous mantle in the southern Indian Ocean

Despite its small area (5.6 km²), the Penguins Island brings magmatic information concerning mantle geochemical heterogeneities in southwestern Indian Ocean. The volcanism that built the island was firstly associated with marine deposits, and secondly with aerial, giving then abundant volcanic breccias and lava flows. The rocks are weakly differentiated and result of magmatic fractionation from picritic to tephritic types. KAr ages are near 1.1 Ma. The magmatic source may be related to a HIMU reservoir or to EMI ± EMII ones, depending on the geochemical evidences that are taken into account. However, comparisons with the Marion Island, on the same oceanic plateau and far to the west, as well as with Kerguelen Islands, far to the east, suggest a very heterogeneous mantle source. To cite this article: A. Giret et al., C. R. Geoscience 334 (2002) 481–488.     

Size discontinuity between interstellar and chondritic aromatic structures: A high-resolution transmission electron microscopy study

Polyaromatic hydrocarbons (PAHs) are often considered as abundant and widespread organic structures in the universe and such structures are known to build the macromolecular network of the organic matter in carbonaceous chondrites. Assuming that interstellar PAHs are properly identified from infrared bands, these meteoritic aromatic moieties can be compared with their interstellar counterpart. The main structural parameters of the aromatic units of the insoluble organic matter of the Orgueil and Murchison chondrites are directly determined through high resolution transmission electron microscopy along with image analysis. These aromatic moieties appear weakly organized and of a smaller size than those present in the interstellar medium (containing ∼30 and ∼150 C atoms). Provided chondritic and interstellar polyaromatic hydrocarbons are derived from a similar organosynthesis, the smaller units were selectively preserved in meteorites, likely thanks to their fast accumulation on grains, which would protect them from solar UV photodissociation at the surface of the protosolar disk.     

A 70 Ma record of suprasolidus conditions in the large,hot, long‐duration Grenville Orogen

Petrochronology of magmatic monazite and apatite from a single paragneiss leucosome derived by in situ partial melting documents the thermal evolution of the Allochthonous Belt of the central Grenville Province. Monazite records suprasolidus metamorphism from ca. 1080 to 1020 Ma under high temperature up to 850°C. Apatite from the same leucosome yields an age of 960 Ma, consistent with cooling of this crustal segment down to subsolidus conditions of ca. 450°C. A pegmatitic granite dyke, with lobate contacts, previously dated at ca. 1005 Ma (Turlin et al., 2017 ) is interpreted to intrude the paragneisses at a temperature of ca. 650°C close to the wet‐solidus. These data document slow cooling at a rate of 2–6°C/Ma for the middle crust of this part of the Grenville hinterland marked by protracted suprasolidus conditions for at least 70 Ma. It supports the definition of the Grenville Orogen as a large, hot, long‐duration orogen.     

The Morcles microgranite (Aiguilles Rouges,Swiss Alps): geochronological and geochemical evidences for a common origin with the Vallorcine intrusion

The Morcles microgranite is located in the N–E termination of the Aiguilles Rouges massif (External Crystalline Massifs, Switzerland). It outcrops as dykes, a few meters to 150 m in thickness, intruding the Aiguilles Rouges polymetamorphic basement, and presents variation of texture from granophyric to rhyolitic. We present here for the first time, in situ U–Pb zircon dating of the Morcles microgranite/rhyolite based on laser-ablation—inductively coupled plasma—mass spectrometry (LA-ICP-MS) data. Results indicate late Variscan emplacement ages at ~303 and ~309–312 Ma, a major Caledonian inherited component age at ~445–460 Ma, and secondary inherited ages ranging from Pan-African (550–1000 Ma) to Paleoproterozoic (2.3 Ga). Geochronological and geochemical data indicate that the Morcles microgranite/rhyolite shares a common origin with the higher (or “H”) facies of the neighbouring Vallorcine granitic intrusion. This close affinity is further corroborated by the geographical alignment of both intrusive bodies on either side of the Rhone Valley. The fine-grained texture of the microgranite groundmass and the rhyolite indicates a very rapid cooling rate and emplacement close to the surface, suggesting that the Morcles microgranite/rhyolite may constitute the shallow-level counterpart of the Vallorcine granite. The mineralogical assemblages observed in the Morcles microgranite/rhyolite support the idea of high-temperature melting conditions provided by underplating of mantle-derived magmas during the Carboniferous extension of the Variscan cordillera.     

Petrographical and geochemical characterization of Comblanchien limestone (Bourgogne,France): A fingerprint of the building stone provenance

The Comblanchien limestone is a well-known building stone that deserves a quantitative characterization in order to be able to certify its origin. We compare petrographical and geochemical characteristics of limestones commercialized under the name of Comblanchien to those of one of their competitors (VATC, a Portuguese coated grain-bearing limestone). From macroscopic and microscopic observations, the distinction is somehow difficult but the coated grain-bearing Comblanchien samples have δ¹³C values (from +1.75 to +2.25‰) different from those of the VATC sample (negative δ¹³C value). As an example of application of these results, three samples from a building site near Paris are also studied in order to verify their provenance. We conclude that they do not come from quarries from the Comblanchien area, but likely from Portugal. The study shows that a detailed analysis of building limestones may provide a robust tool for discriminating between currently mined stones of different provenances, and thus open the possibility to attach to a given limestone a fingerprint, an identity card, and if required a commercial label.     

Apodized Lyot coronagraph for SPHERE/VLT

SPHERE (which stands for Spectro-Polarimetric High-contrast Exoplanet REsearch) is a second-generation Very Large Telescope (VLT) instrument dedicated to high-contrast direct imaging of exoplanets which first-light is scheduled for 2011. Within this complex instrument one of the central components is the apodized Lyot coronagraph (ALC). The present paper reports on the most interesting aspects and results of the whole numerical study made during the design of the ALC for SPHERE/VLT. The method followed for this study is purely numerical, but with an end-to-end approach which is largely fed by a number of instrumental feedbacks. The results obtained and presented in this paper firstly permit to finalize the optical design before laboratory performance testing of the ALC being built for SPHERE/VLT (see paper II ??Laboratory tests and performances??), but will also hopefully help conceiving future other instruments alike, for example within the very promising extremely large telescope perspective.