Stable isotope systematics and geochemical signatures constraining groundwater hydraulics in the mining environment of the Korba Coalfield,Central India

The present study explores the use of stable isotopes and major ion chemistry of various water sources such as mine water, groundwater, river water, and rainwater to identify the dominant hydrogeochemical process that controls the water quality in the active opencast coal mining area of the Korba Coalfield, India. Different hydrochemical models have revealed that the study area is mostly characterized by two facies alongside a dominance by ion exchange: i.e., a slightly mineralized Ca²⁺–Mg²⁺–Cl^? and a meteorically derived Ca²⁺–HCO₃^? fresh water facies. In the isotope bivariate plot, the samples plot to the right of the LMWL and slopes observed in pre (4.94) and post-monsoon (5.85) seasons are not as steep as the LMWL (7.95) and this warrants the suggestion that meteoric water is the major source that replenishes the dynamic groundwater resource in the study area after being subjected to evaporation. The negative d-excess values (<?0) and enrichment of the δ¹⁸O ratio observed at some locations suggests a non-equilibrium process and a “mechanism of mixing”. A noteworthy fact is that isotopically river water is in tandem with the mine water samples for both seasons and testifies to a hydraulic connectivity between Hasdeo River water and mine water through a major fault. It is substantiated by mine inflows assessed by the sump test for Kusmunda and Gevra, which is two times higher than the predicted values by Darcy’s law. The wide variation in the isotopic composition is attributed to different vapor sources viz., southwest monsoon (SW) that originates in the Arabian Sea and locally driven air moisture from surface water bodies.     

Identification of suitable sites for groundwater recharge in Awaspi watershed using GIS and remote sensing techniques

Groundwater is a valuable natural resource for drinking, domestic, livestock use, and irrigation, especially in arid and semi-arid regions like the Garmiyan belt in Kurdistan region. The Awaspi watershed is located 50 km east of Kirkuk city, south Kurdistan, Iraq; and covers an area of 2146 km². The paper presents result of a study aimed at: (1) mapping and preparing thematic layers of factors that control groundwater recharge areas, and (2) determination of sites suitable for groundwater recharge. We used available data such as geological map, groundwater depth map, digital elevation model (DEM), Landsat 8 imagery, and tropical rainfall measuring mission (TRMM) data for this study. These data, supplemented by slope features, lithology, land use land cover, rainfall, groundwater depth, drainage density, landform, lineament density, elevation and topographic position index, were utilized to create thematic maps to identify suitable areas of groundwater recharge, using GIS and remote sensing techniques. Analytic hierarchy process (AHP) was applied to weight, rank, and reclassify these maps in the ArcGIS 10.3 environment, to determine the suitable sites for groundwater recharge within the Awaspi watershed. Fifty-five percent of the total area of the watershed was found to be suitable for groundwater recharge; whereas 45% of the area was determined to have poor suitability for groundwater recharge, but can be used for surface water harvesting.     

Macrophytes’ Performance in Floating Treatment Wetlands for the Remediation of Ciprofloxacin-Contaminated Water

The presence of trace antibiotics in domestic and industrial effluents poses a risk of toxicity to fauna and flora. The application of floating treatment wetlands (FTWs) is a low-cost and sustainable approach to remediate wastewater. In this study, the performance of different macrophytes vegetated in FTWs for the remediation of ciprofloxacin (CIP)-contaminated water is investigated. Six macrophytes, Brachia mutica, Typha domingensis, Phragmites australis, Canna indica, Cyperus laevigatus, and Leptochloa fusca, are vegetated in FTWs for the removal of CIP (50 mg L⁻¹) from water. The FTWs show the potential to remove 30–43.58 mg L⁻¹ CIP from water in 28 days. They also reduce the chemical oxygen demand (118–138 mg L⁻¹) and biochemical oxygen demand (35–45 mg L⁻¹) of water. Among the macrophytes, C. indica removes maximum (43.58 mg L⁻¹) and T. domingensis minimum (30 mg L⁻¹) CIP. Canna indica and T. domingensis exhibit the maximum and minimum increase (30% and 12% of dry biomass) in growth, respectively. This study reveals that the FTWs vegetated with different plant species exhibit varying performances in removing CIP from water. This investigation is a step forward toward sustainable bioremediation of water contaminated with antibiotics.     

柴达木盆地昆特依盐湖沉积特征及其盐类资源评价

昆特依盐湖位于柴达木盆地西北部,是一个相对独立的沉积盆地,可反映盆地西北部的演化历史,对研究盆地内盐湖演化有重要意义。基于研究区已有的研究成果,总结和评价了昆特依盐湖沉积与盐类矿产资源,并得到以下结论:1)昆特依湖自1 925～774 ka期间以暖湿型气候为主,其后呈干冷与暖湿气候交替出现,最早成盐期为1150 ka,最终于30.6 ka成为干盐湖。昆特依盆地早期沉积的细碎屑沉积物沉积速率(0.22 mm/a)慢于晚期沉积的石盐层(0.33 mm/a);2)昆特依盐湖液体KCl储量为1.32×10~8 t,MgCl储量为2.79×10~8 t,NaCl储量为24.15×10~8 t;3)估算出赋存于昆特依盐湖石盐矿中的锂资源量达39×10~4 t,同时估算出液体中的锂资源量约有74×10~4 t,二者总量达百万吨;4)昆特依矿田的成因属典型的内陆湖相沉积,成矿控制因素以构造作用为主,其次为气候及物质来源。关于昆特依盐湖沉积特征与盐类矿产资源特征的研究,有利于对本地区地质演化更全面的认识,对合理开发利用盐类资源有重要意义。     

Experimental insights into Stannern-trend eucrite petrogenesis

The incompatible trace element-enriched Stannern-trend eucrites have long been recognized as requiring a distinct petrogenesis from the Main Group-Nuevo Laredo (MGNL) eucrites. Barrat et al. ( 2007 ) proposed that Stannern-trend eucrites formed via assimilation of crustal partial melts by a MGNL-trend magma. Previous experimental studies of low-degree partial melting of eucrites did not produce sufficiently large melt pools for both major and trace element analyses. Low-degree partial melts produced near the solidus are potentially the best analog to the assimilated crustal melts. We partially melted the unbrecciated, unequilibrated MGNL-trend eucrite NWA 8562 in a 1 atm gas-mixing furnace, at IW-0.5, and at temperatures between 1050 and 1200 °C. We found that low-degree partial melts formed at 1050 °C are incompatible trace element enriched, although the experimental melts did not reach equilibrium at all temperatures. Using our experimental melt compositions and binary mixing modeling, the FeO/MgO trend of the resultant magmas coincides with the range of known Stannern-trend eucrites when a primary magma is contaminated by crustal partial melts. When experimental major element compositions for eucritic crustal partial melts are combined with trace element concentrations determined by previous modeling (Barrat et al. 2007 ), the Stannern-trend can be replicated with respect to both major, minor, and trace element concentrations.     

Cooling rates of type I chondrules from Renazzo: Implications for chondrule formation

Cooling rates are one of the few fundamental constraints on models of chondrule formation. In this study, we used Cu and Ga diffusion profiles in metal grains to determine the cooling rates of type I chondrules in the Renazzo CR2 chondrite. To improve previous estimations of cooling rates obtained using this method, we used CT scanning and serial polishing of our sections to analyze equatorial sections of large metal grains. Through the cores of these metal grains situated at the surface of chondrules, the cooling rates calculated range from 21 to 86 K h⁻¹ for a peak temperature T_p ~ 1623–1673 K. A metal grain embedded in the core of a chondrule exhibits a cooling rate of 1.2 K h⁻¹ at a T_p ~ 1573 K. We also measured Cu-Ga diffusion profiles from nonequatorial sections of metal grains and calculated a lower range of cooling rates of 15–69 K h⁻¹ for T_p ~ 1473–1603 K compared to our results from equatorial sections. The high cooling rates inferred from the lightning model (several thousand K h⁻¹) are clearly at odds with the values obtained in this work. The X-wind model predicts cooling rates (~6–10 K h⁻¹) lower than most of our results. The cooling rates calculated here are in close agreement with those inferred from shock wave models, in particular for temperatures at which olivine crystallizes (from ~10 to several hundreds K h⁻¹ between 1900 and 1500 K). However, the chemical compositions of metal grains in Renazzo are consistent with the splashing model, in which a spray of metal droplets originated from a partially molten planetesimal. Volatile siderophile element depletion is explained by evaporation before metal was engulfed within silicate droplets. Liquid metal isolated from the liquid silicate crystallized during cooling, reacted with the ambient gas, and then re-accreted within partially molten chondrules.     

Origin of Boron in the Gas Hure Salt Lake of NorthwesternQaidam Basin,China: Evidence from Hydrochemistry andBoron Isotopes

The Gas Hure Salt Lake(GHSL) in the northwestern Qaidam Basin, western China, is rich in boron(B)resources, but its B-resource origin is hardly known. Hydrochemical compositions and B isotope characteristics of different waters were collected around the GHSL, including the river water, stream water, spring water, salt-lake brine,intercrystalline brine, well water, drilling brine, and solar pond brine. The hydrochemical signatures suggest that silicates,carbonates and evaporates are the main B-bearing rocks during the water dynamic. The reservoir estimation of B resources shows that the Kulamulekesay River(KLMR) and the Atekan River(ATKR) contribute annually 18.3 tons and 22.84 tons of B, respectively, with a total amount of 11.72 × 10~4 tons of B during the past 5.7 ka. In comparison with the known B reservoir(32.96 × 10~4 tons) in the GHSL, a significant amount of B in the GHSL was probably recharged from deep fluids and sediments around the GHSL. The B concentration and B-enrichment degree are shaped by the evaporation process,which are highly elevated at the carnallite and bischofite stages.