Aragonite and calcite preservation in sediments from Lake Iznik related to bottom lake oxygenation and water column depth

This study examines the forcing mechanisms driving long‐term carbonate accumulation and preservation in lacustrine sediments in Lake Iznik (north‐western Turkey) since the last glacial. Currently, carbonates precipitate during summer from the alkaline water column, and the sediments preserve aragonite and calcite. Based on X‐ray diffraction data, carbonate accumulation has changed significantly and striking reversals in the abundance of the two carbonate polymorphs have occurred on a decadal time scale, during the last 31 ka cal bp . Different lines of evidence, such as grain size, organic matter and redox sensitive elements, indicate that reversals in carbonate polymorph abundance arise due to physical changes in the lacustrine setting, for example, water column depth and lake mixing. The aragonite concentrations are remarkably sensitive to climate, and exhibit millennial‐scale oscillations. Extending observations from modern lakes, the Iznik record shows that the aerobic decomposition of organic matter and sulphate reduction are also substantial factors in carbonate preservation over long time periods. Lower lake levels favour aragonite precipitation from supersaturated waters. Prolonged periods of stratification and, consequently, enhanced sulphate reduction favour aragonite preservation. In contrast, prolonged or repeated exposure of the sediment–water interface to oxygen results in in situ aerobic organic matter decomposition, eventually leading to carbonate dissolution. Notably, the Iznik sediment profile raises the hypothesis that different states of lacustrine mixing lead to selective preservation of different carbonate polymorphs. Thus, a change in the entire lake water chemistry is not strictly necessary to favour the preservation of one polymorph over another. Therefore, this investigation is a novel contribution to the carbon cycle in lacustrine systems.     

High resolution regional climate model simulations for Germany: Part II—projected climate changes

The projected climate change signals of a five-member high resolution ensemble, based on two global climate models (GCMs: ECHAM5 and CCCma3) and two regional climate models (RCMs: CLM and WRF) are analysed in this paper (Part II of a two part paper). In Part I the performance of the models for the control period are presented. The RCMs use a two nest procedure over Europe and Germany with a final spatial resolution of 7 km to downscale the GCM simulations for the present (1971–2000) and future A1B scenario (2021–2050) time periods. The ensemble was extended by earlier simulations with the RCM REMO (driven by ECHAM5, two realisations) at a slightly coarser resolution. The climate change signals are evaluated and tested for significance for mean values and the seasonal cycles of temperature and precipitation, as well as for the intensity distribution of precipitation and the numbers of dry days and dry periods. All GCMs project a significant warming over Europe on seasonal and annual scales and the projected warming of the GCMs is retained in both nests of the RCMs, however, with added small variations. The mean warming over Germany of all ensemble members for the fine nest is in the range of 0.8 and 1.3 K with an average of 1.1 K. For mean annual precipitation the climate change signal varies in the range of ?2 to 9 % over Germany within the ensemble. Changes in the number of wet days are projected in the range of ±4 % on the annual scale for the future time period. For the probability distribution of precipitation intensity, a decrease of lower intensities and an increase of moderate and higher intensities is projected by most ensemble members. For the mean values, the results indicate that the projected temperature change signal is caused mainly by the GCM and its initial condition (realisation), with little impact from the RCM. For precipitation, in addition, the RCM affects the climate change signal significantly.     

Combination of multi-mission altimetry data along the Mekong River with spatio-temporal kriging

River water-level time series at fixed geographical locations, so-called virtual stations, have been computed from single altimeter crossings for many years. Their temporal resolution is limited by the repeat cycle of the individual altimetry missions. The combination of all altimetry measurements along a river enables computing a water-level time series with improved temporal and spatial resolutions. This study uses the geostatistical method of spatio-temporal ordinary kriging to link multi-mission altimetry data along the Mekong River. The required covariance models reflecting the water flow are estimated based on empirical covariance values between altimetry observations at various locations. In this study, two covariance models are developed and tested in the case of the Mekong River: a stationary and a non-stationary covariance model. The proposed approach predicts water-level time series at different locations along the Mekong River with a temporal resolution of 5 days. Validation is performed against in situ data from four gauging stations, yielding RMS differences between 0.82 and 1.29 m and squared correlation coefficients between 0.89 and 0.94. Both models produce comparable results when used for combining data from Envisat, Jason-1, and SARAL for the time period between 2002 and 2015. The quality of the predicted time series turns out to be robust against a possibly decreasing availability of altimetry mission data. This demonstrates that our method is able to close the data gap between the end of the Envisat and the launch of the SARAL mission with interpolated time series.     

Regional vulnerability assessment for debris flows in China—a CWS approach

Based on former conceptual models of vulnerability, this paper aims to improve the quantitative model for regional vulnerability assessment by analyzing in-depth the relation between vulnerability, exposure, coping capacity, and resilience. Taking the mountain settlements in the upper reaches of Min River, China, as a case study, the method of Contributing Weight Superposition (CWS) is applied in establishing both a model and a system for the vulnerability assessment of elements at risk. The CWS approach consists of 13 index factors including population, economic and road densities, building and farmland coverage, hazard-affected areas, urbanization rate, and GDP per capita. Accordingly, a debris flow hazard vulnerability zoning map was obtained and the assessment results show that the distribution of high and comparatively high vulnerability zones, where economic activities are considerably high, has a close correlation to the topography of the catchment and population characteristics. The results thus may serve as a pertinent guidance for settlement relocation, population distribution readjustment, and management to prevent and reduce hazards in the upper reaches of Min River and beyond.     

Thermal expansion and decomposition of jarosite: a high-temperature neutron diffraction study

The structure of deuterated jarosite, KFe₃(SO₄)₂(OD)₆, was investigated using time-of-flight neutron diffraction up to its dehydroxylation temperature. Rietveld analysis reveals that with increasing temperature, its c dimension expands at a rate ~10 times greater than that for a. This anisotropy of thermal expansion is due to rapid increase in the thickness of the (001) sheet of [Fe(O,OH)₆] octahedra and [SO₄] tetrahedra with increasing temperature. Fitting of the measured cell volumes yields a coefficient of thermal expansion, α = α₀ + α₁ T, where α₀ = 1.01 × 10⁻⁴ K⁻¹ and α₁ = −1.15 × 10⁻⁷ K⁻². On heating, the hydrogen bonds, O1···D–O3, through which the (001) octahedral–tetrahedral sheets are held together, become weakened, as reflected by an increase in the D···O1 distance and a concomitant decrease in the O3–D distance with increasing temperature. On further heating to 575 K, jarosite starts to decompose into nanocrystalline yavapaiite and hematite (as well as water vapor), a direct result of the breaking of the hydrogen bonds that hold the jarosite structure together.     

Dynamics of Saturn's magnetodisk near Titan's orbit: Comparison of Cassini magnetometer observations from real and virtual Titan flybys

We analyze the variability of the ambient magnetospheric field along Titan's orbit at 20.3 Saturn radii. However, while our preceding study (Simon et al., 2010) focused on Cassini magnetometer observations from the 62 Titan flybys (TA-T62) between October 2004 and October 2009, the present work discusses magnetic field data that were collected near Titan's orbit when the moon was far away. In analogy to the observations during TA-T62, the magnetospheric fields detected during these 79 “virtual” Titan flybys are strongly affected by the presence of Saturn's bowl-shaped and highly dynamic magnetodisk current sheet. We therefore provide a systematic classification of the magnetic field observations as magnetodisk current sheet or lobe-type scenarios. Among the 141 (62 real+79 virtual) crossings of Titan's orbit between July 2004 and December 2009, only 17 encounters (9 real+8 virtual) took place within quiet, magnetodisk lobe-type fields. During another 50 encounters (21 real+29 virtual), rapid transitions between current sheet and lobe fields were observed around the moon's orbital plane. Most of the encounters (54=22 real+32 virtual) occurred when Titan's orbit was embedded in highly distorted current sheet fields, thereby invalidating the frequently applied idealized picture of Titan interacting with a homogeneous and stationary magnetospheric background field. The locations of real and virtual Titan flybys are correlated to each other. Each of the 62 real Titan flybys possesses at least one virtual counterpart that occurred shortly before or after the real encounter and at nearly the same orbital position. A systematic comparison between Cassini magnetometer observations from the real Titan flybys and their virtual companions suggests that there is no clear evidence of Titan exerting a significant level of control on the vertical oscillatory motion of the magnetodisk near its orbit.     

Meso- and bathy-pelagic fish parasites at the Mid-Atlantic Ridge (MAR): Low host specificity and restricted parasite diversity

Seven meso- and bathy-pelagic fish species from the Mid-Atlantic Ridge (MAR) were firstly studied for fish parasites and feeding ecology. With a total of seven parasite species, the 247 meso- and bathy-pelagic deep-sea fish specimens belonging to the families Melamphaidae (3 spp.), Myctophidae (3 spp.) and Stomiidae (1 sp.) revealed low parasite diversity. The genetically identified nematodes Anisakis simplex (s.s.) and Anisakis pegreffii from the body cavity, liver and muscles of Myctophum punctatum were the most abundant parasites, reaching a prevalence of 91.4% and mean intensity of 3.1 (1–14). Anisakis sp. (unidentified) infected Chauliodus sloani and Poromitra crassiceps. Bothriocephalidean and tetraphyllidean cestode larvae infected Benthosema glaciale, the latter also occurring in C. sloani and Scopelogadus beanii, at low prevalences. Adult parasites at low infection rates included the digenean Lethadena sp. (2.9%), and the two copepod species Sarcotretes scopeli (5.7%) and Tautochondria dolichoura (5.3–11.4%). The myctophid Lampanyctus macdonaldi and the melamphaid Scopelogadus mizolepis mizolepis were free of parasites. Analyses of the stomach contents revealed crustaceans, especially copepods and euphausiids for the myctophids and also amphipods for the melamphaids as predominant prey items. While all stomachs showing distinct content comprising often unidentified ‘tissue’ (possibly gelatinous zooplankton), only C. sloani preyed upon fish. Though this feeding habit would enable transfer of a variety of crustacean-transmitted parasites into the fish, the parasite fauna in the meso- and bathy-pelagic fish was species poor. All observed parasites showed low host specificity, demonstrating no distinct pattern of host–parasite co-evolution. The MAR is no barrier for the parasite distribution in the North Atlantic meso- and bathy-pelagial.