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61.
Residence of trace elements in metasomatized spinel lherzolite xenoliths: a proton-microprobe study 总被引:19,自引:0,他引:19
Suzanne Y. O'Reilly W. L. Griffin C. G. Ryan 《Contributions to Mineralogy and Petrology》1991,109(1):98-113
Minerals occurring in dry and modally metasomatized spinel lherzolites from western Victoria have been analysed by proton microprobe for Ni, Cu, Zn, Ga, Rb, Sr, Y, Zr, Nb, Ba, Pb, Br, rare-earth elements (REE), Th and U. Mass-balance calculations demonstrate that these trace elements are contained in specific acceptor minerals and do not occur in significant concentrations at clean grain boundaries. The level of particular trace elements in the rock depends on the presence of specific phases: for example high levels of REE, Sr (and U, Th, Br) require apatite, while Ba, Nb and Ta are strongly concentrated in amphibole±mica. Mantle metasomatism in these spinel lherzolites is inferred to result from an open-system process involving infiltration of fluids released by crystallizing silicate melts. This process produces metasomatic zones with different modal mineralogy and hence greatly different trace-element signatures. The data demonstrate that large-ion-lithophile (LIL) and high-field strength (HFS) elements in metasomatized spinel lherzolites are strongly concentrated in non-refractory phases, which will break down easily in heated volumes such as the walls of magma conduits. The heterogeneity observed in trace-element patterns of intraplate alkali basaltic rocks may not reflect source heterogeneity, but may result largely from contamination by metasomatized mantle wall rock. The KDs for most trace elements show little temperature dependence except for KDSr between orthopyroxene and clinopyroxene where KD decreases with increasing temperature. The generally uniform KDs can be used to test for disequilibrium in such assemblages. 相似文献
62.
Brenda Moraska Lafrancois Suzanne Magdalene D. Kent Johnson 《Journal of Paleolimnology》2009,41(4):603-622
Long-term water quality monitoring data from two riverine lakes in the Upper Mississippi River basin, Lakes St. Croix and
Pepin, were analyzed to compare the long-term average water quality conditions and land use distributions, water quality trends
and loads at lake inlets and outlets, trends from long-term versus short-term monitoring records, and the ability of paleolimnological
cores to accurately infer lake water quality conditions. During the 1976–2004 period, the long-term average concentrations
of nutrients, suspended solids, and chlorophyll-a were consistently lower at the Lake St. Croix inlet versus the Lake Pepin inlet, which drains a greater proportion of urban
and agricultural runoff. Despite these differences, nutrient trends were similar at the inlets to both lakes; reductions in
total phosphorus and ammonium concentrations were attributed to improvements in point source technologies, whereas increasing
nitrate concentrations were attributed to both point source changes and nonpoint source increases. Despite improvements in
several water quality variables, nitrate concentrations are increasing in both lakes, sediment trends indicate persistent
nonpoint source inputs to Lake Pepin, and current total phosphorus concentrations remain well above pre-1950s levels in both
lakes. Since urban development and agriculture are increasing in the Lake St. Croix and Lake Pepin Watersheds, continued point
source regulation and additional nonpoint source control efforts will be needed to further improve water quality in these
lakes. The 1976–2004 trends for most water quality variables were similar at inlet versus outlet sites on Lake St. Croix.
Trends at Lake Pepin inlet versus outlet sites were less similar, but data availability limited the comparison to the 1993–2003
period. While the truncated data record highlighted short-term trends in both lakes, the full data record was most useful
for exploring general patterns in water quality. Length of monitoring record affected our ability to detect trends at the
inlets to both lakes, and altered the magnitude of detected trends. During the two decades of the 1980s and 1990s, paleolimnological
estimates of retained phosphorus loads were similar to those estimated from recent water quality monitoring. These similarities
support the use of paleolimnological approaches to infer past water quality conditions in Lakes St. Croix and Pepin.
This is one of eight papers dedicated to the “Recent Environmental History of the Upper Mississippi River” published in this
special issue of the Journal of Paleolimnology. D. R. Engstrom served as guest editor of the special issue. 相似文献
63.
AbstractSmall dams fragment river landscapes, disrupting channel connectivity and impacting water quality and quantity. Although they impound volumetrically less total water than large dams, the ubiquity of small dams suggests their cumulative impacts could be significant. Documenting the distribution and characteristics of small dams is necessary to understanding and mitigating their impacts. In this study, we compare datasets of small dams in Oregon, compile a new comprehensive dataset, and document geographic variations in small dam distributions between different ecoregions. We used Oregon Water Resources Department dam and Oregon Department of Fish and Wildlife fish passage barrier datasets to compare dam heights and contributing drainage areas between different ecoregions. Over 61% of Oregon’s land area is above one or more small dam. We highlight the location of Oregon’s small dams at valley margins, transition zones between flat plains and mountains, and areas of high population density. Given the hidden nature of small dams, evaluation of small dam impacts using public imagery is not effective. However, knowledge of small dam distributions given their association with landforms can aid in finding unrecorded dams, assessing approaches for evaluating their geomorphic impacts, and informing their management. 相似文献
64.
The analysis of Venus’ gravity field and topography suggests the presence of a small number of deep mantle plumes (~9). This study predicts the number of plumes formed at the core–mantle boundary, their characteristics, and the production of partial melt from adiabatic decompression. Numerical simulations are performed using a 3D spherical code that includes large viscosity variations and internal heating. This study investigates the effect of several parameters including the core–mantle boundary temperature, the amount of internal heating, and the mantle viscosity. The smallest number of plumes is achieved when no internal heating is present. However, scaling Earth’s radiogenic heating to Venus suggests a value of ~16 TW. Cases with internal heating produce more realistic lid thickness and partial melting, but produce either too many plumes or no plumes if a high mantle temperature precludes the formation of a hot thermal boundary layer. Mantle viscosity must be reduced to at least 1020 Pa s in order to include significant internal heating and still produce hot plumes. In all cases that predict melting, melting occurs throughout the upper mantle. Only cases with high core temperature (>1700 K) produce dry melting. Over time the upper mantle may have lost significant volatiles. Depending on the water content of the lower mantle, deep plumes may contribute to present-day atmospheric water via volcanic outgassing. Assuming 50 ppm water in mantle, 10 plumes with a buoyancy flux of 500 kg/s continuously erupting for 4 myr will outgas an amount of water on the order of that in the lower atmosphere. A higher level of internal heating than achieved to date, as well as relatively low mantle viscosity, may be required to achieve simulations with ~10 plumes and a thinner lid. Alternatively, if the mantle is heating up due to the stagnant lid, the effect is equivalent to having lower rates of internal heating. A temperature increase of 110 K/byr is equivalent to ?13 TW. This value along with the internal heating of 3 TW used in this study may represent the approximate heat budget of Venus’ mantle. 相似文献
65.
Tsvetomila Mateeva George A. Wolff Gianreto Manatschal Suzanne Picazo Nick J. Kusznir John Wheeler 《Swiss Journal of Geoscience》2017,110(2):457-478
Evidence from ultraslow spreading mid-ocean ridges and both fossil and present-day Ocean–Continent Transitions (OCT) demonstrates that mantle serpentinization resulting from the interaction of mantle rock and water during tectonic exhumation is widespread. Observations at white smokers in modern ocean settings suggest that methane produced by serpentinization can support methanotrophic bio-systems, which use methane as the only source of carbon. An important question is whether such bio-systems are more generally pervasive in their association with serpentinized mantle in the subsurface. In this study, we examined whether there is evidence for such a methanotrophic system in exhumed serpentinized mantle at a magma-poor rifted continental margin, by probing for characteristic biological markers in these and associated sedimentary rocks in the Totalp unit of SE Switzerland. This unit represents a remnant of the former OCT of the southern Alpine Tethyan margin and was chosen because of its mild Alpine tectonic and low-grade metamorphic overprint during Alpine orogeny, hence giving potential for the preservation of indigenous organic matter (OM). Totalp samples are characterized by low organic carbon contents of 11–647 ppm. The majority of the samples contain hydrocarbons in the form of n-alkanes in the range C17–C36. Some sediments contain isoprenoids, for example pristane and phytane and a suite of steranes that are consistent with a marine origin for the OM preserved in the rocks. Traces of marine planktonic and bacterial OM are preserved in the serpentinized mantle and overlying sediments of this ancient Tethyan OCT, but there is no evidence that the OM has been generated from methanotrophic bio-systems. 相似文献
66.
青藏高原北羌塘新生代高钾钙碱岩系火山岩角闪石类型有痕量元素地球化学 总被引:12,自引:2,他引:12
利用电子探针和激光探针剥蚀系统(LA-ICP-MS)对北羌塘新第三纪高钾钙碱岩系英安岩中角闪石的主元素和微量、角闪石强烈富集Sc、Ti、V、Cr、Co、Ni等不相容亲铁元素,而相对亏损Th、U、Pb、Rb等强不相容的大离子亲石元素。稀土元素丰度高,且无Eu异常,批示北羌塘这套高钾钙碱岩系火山岩可能是青藏高原加厚的相当于榴辉岩相物质组成的下部陆壳脱水熔融的产物。 相似文献
67.
Morphodynamic assessment of side channel systems using a simple one‐dimensional bifurcation model and a comparison with aerial images 下载免费PDF全文
R. Pepijn van Denderen Ralph M. J. Schielen Astrid Blom Suzanne J. M. H. Hulscher Maarten G. Kleinhans 《地球表面变化过程与地形》2018,43(6):1169-1182
Side channel construction is a common intervention applied to increase a river's conveyance capacity and to increase its ecological value. Past modelling efforts suggest two mechanisms affecting the morphodynamic change of a side channel: (1) a difference in channel slope between the side channel and the main channel and (2) bend flow just upstream of the bifurcation. The objective of this paper was to assess the conditions under which side channels generally aggrade or degrade and to assess the characteristic timescales of the associated morphological change. We use a one‐dimensional bifurcation model to predict the development of side channel systems and the characteristic timescale for a wide range of conditions. We then compare these results to multitemporal aerial images of four side channel systems. We consider the following mechanisms at the bifurcation to be important for side channel development: sediment diversion due to the bifurcation angle, sediment diversion due to the transverse bed slope, partitioning of suspended load, mixed sediment processes such as sorting at the bifurcation, bank erosion, deposition due to vegetation, and floodplain sedimentation. There are limitations to using a one‐dimensional numerical model as it can only account for these mechanisms in a parametrized manner, but the model reproduces general behaviour of the natural side channels until floodplain‐forming processes become important. The main result is a set of stability diagrams with key model parameters that can be used to assess the development of a side channel system and the associated timescale, which will aid in the future design and maintenance of side channel systems. © 2017 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd. 相似文献
68.
69.
Vegetation cycles in a disturbed sequence around the Cobb-Mountain subchron in Catalonia (Spain) 总被引:1,自引:0,他引:1
Suzanne A. G. Leroy 《Journal of Paleolimnology》2008,40(3):851-868
70.
Pyrite paragenesis and multiple sulfur isotope distribution in late Archean and early Paleoproterozoic Hamersley Basin sediments 总被引:1,自引:0,他引:1
Michaela A. Partridge Suzanne D. Golding Kim A. Baublys Elisa Young 《Earth and Planetary Science Letters》2008,272(1-2):41-49
The sulfur isotope record in late Archean and early Paleoproterozoic rocks is of considerable importance because it provides evidence for changes in early Earth atmospheric oxygen levels and potentially constrains the origin and relative impact of various microbial metabolisms during the transition from an anoxic to oxic atmosphere. Mass independently fractionated (MIF) sulfur isotopes reveal late Archean and early Paleoproterozoic sulfur sources in different pyrite morphologies in Western Australia's Hamersley Basin. Multiple sulfur isotope values in late Archean pyrite vary according to morphology. Fine grained pyrite has positive sulfur MIF, indicating a reduced elemental sulfur source, whereas pyrite nodules have negative sulfur MIF, potentially derived from soluble sulfate via microbial sulfate reduction. The Hamersley Basin δ34S–Δ33S record suggests that the extent of oxygenation of the surface ocean fluctuated through the Late Archean from at least 2.6 Ga, more than 150 million yr before the Great Oxidation Event. In the early Paleoproterozoic, there is less distinction between pyrite morphologies with respect to sulfur isotope fractionation, and pyrite from the Brockman Iron Formation trends toward modern sulfur isotope values. An important exception to this is the strong negative MIF recorded in layer parallel pyrite in Paleoproterozoic carbonate facies iron formation. This may suggest that deeper water hydrothermal environments remained anoxic while shallower water environments became more oxidised by the early Paleoproterozoic. The results of the current study indicate that sulfide paragenesis is highly significant when investigating Archean and early Paleoproterozoic multiple sulfur isotope compositions and sulfur sources. 相似文献