On the occurrence,trace element geochemistry,and crystallization history of zircon from in situ ocean lithosphere

We characterize the textural and geochemical features of ocean crustal zircon recovered from plagiogranite, evolved gabbro, and metamorphosed ultramafic host-rocks collected along present-day slow and ultraslow spreading mid-ocean ridges (MORs). The geochemistry of 267 zircon grains was measured by sensitive high-resolution ion microprobe-reverse geometry at the USGS-Stanford Ion Microprobe facility. Three types of zircon are recognized based on texture and geochemistry. Most ocean crustal zircons resemble young magmatic zircon from other crustal settings, occurring as pristine, colorless euhedral (Type 1) or subhedral to anhedral (Type 2) grains. In these grains, Hf and most trace elements vary systematically with Ti, typically becoming enriched with falling Ti-in-zircon temperature. Ti-in-zircon temperatures range from 1,040 to 660°C (corrected for a _TiO2 ≈ 0.7, a _SiO2 ≈ 1.0, pressure ≈ 2 kbar); intra-sample variation is typically ~60–150°C. Decreasing Ti correlates with enrichment in Hf to ~2 wt%, while additional Hf-enrichment occurs at relatively constant temperature. Trends between Ti and U, Y, REE, and Eu/Eu* exhibit a similar inflection, which may denote the onset of eutectic crystallization; the inflection is well-defined by zircons from plagiogranite and implies solidus temperatures of ~680–740°C. A third type of zircon is defined as being porous and colored with chaotic CL zoning, and occurs in ~25% of rock samples studied. These features, along with high measured La, Cl, S, Ca, and Fe, and low (Sm/La)_N ratios are suggestive of interaction with aqueous fluids. Non-porous, luminescent CL overgrowth rims on porous grains record uniform temperatures averaging 615 ± 26°C (2SD, n = 7), implying zircon formation below the wet-granite solidus and under water-saturated conditions. Zircon geochemistry reflects, in part, source region; elevated HREE coupled with low U concentrations allow effective discrimination of ~80% of zircon formed at modern MORs from zircon in continental crust. The geochemistry and textural observations reported here serve as an important database for comparison with detrital, xenocrystic, and metamorphosed mafic rock-hosted zircon populations to evaluate provenance.     

Nutrient availability in support of Karenia brevis blooms on the central West Florida Shelf: What keeps Karenia blooming?

Identifying nutrient sources, primarily nitrogen (N) and phosphorus (P), sufficient to support high biomass blooms of the red tide dinoflagellate, Karenia brevis, has remained problematic. The West Florida Shelf is oligotrophic, yet populations >10⁶ cells L⁻¹ frequently occur and blooms can persist for months. Here we examine the magnitude and variety of sources for N and P that are available to support blooms. Annual average in situ or background concentrations of inorganic N in the region where blooms occur range 0.02–0.2 μM while inorganic P ranges 0.025–0.24 μM. Such concentrations would be sufficient to support the growth of populations up to ∼3×10⁴ cells L⁻¹ with at least a 1 d turnover rate. Organic N concentrations average 1–2 orders of magnitude greater than inorganic N, 8–14 μM while organic P concentrations average 0.2–0.5 μM. Concentrations of organic N are sufficient to support blooms >10⁵ cells L⁻¹ but the extent to which this complex mixture of N species is utilizable is unknown. Other sources of nutrients included in our analysis are aerial deposition, estuarine flux, benthic flux, zooplankton excretion, N₂-fixation, and subsequent release of organic and inorganic N by Trichodesmium spp., and release of N and P from dead and decaying fish killed by the blooms. Inputs based on atmospheric deposition, benthic flux, and N₂-fixation, were minor contributors to the flux required to support growth of populations >2.6×10⁴ cells L⁻¹. N and P from decaying fish could theoretically maintain populations at moderate concentrations but insufficient data on the flux and subsequent mixing rates does not allow us to calculate average values. Zooplankton excretion rates, based on measured zooplankton population estimates and excretion rates could also supply all of the N and P required to support populations of 10⁵ and 10⁶ cells L⁻¹, respectively, but excretion is considered as “regenerated” nutrient input and can only maintain biomass rather than contribute to “new” biomass. The combined estuarine flux from Tampa Bay, Charlotte Harbor, and the Caloosahatchee River can supply a varying, but at times significant level of N and P to meet growth and photosynthesis requirements for populations of approximately 10⁵ cells L⁻¹ or below. Estimates of remineralization of dead fish could supply a significant proportion of bloom maintenance requirements but the rate of supply must still be determined. Overall, a combination of sources is required to maintain populations >10⁶ cells L⁻¹.     

Zooplankton and Karenia brevis in the Gulf of Mexico

Blooms of the toxic dinoflagellate Karenia brevis are common in the Gulf of Mexico, yet no in situ studies of zooplankton and K. brevis have been conducted there. Zooplankton abundance and taxonomic composition at non-bloom and K. brevis bloom stations within the Ecology of Harmful Algal Blooms (ECOHAB) study area were compared. At non-bloom stations, the most abundant species of zooplankton were Parvocalanus crassirostris, Oithona colcarva, and Paracalanus quasimodo at the 5-m isobath and P. quasimodo, O. colcarva, and Oikopleura dioica at the 25-m isobath. There was considerable overlap in dominance of zooplankton species between the 5 and 25-m isobaths, with nine species contributing to 90% of abundance at both isobaths. At stations within K. brevis blooms however, Acartia tonsa, Centropages velificatus, Temora turbinata, Evadne tergestina, O. colcarva, O. dioica, and P. crassirostris were dominant. Variations in abundance between non-bloom and bloom assemblages were evident, including the reduction in abundance of three key species within K. brevis blooms.     

Community Development Approaches to Heart Health Promotion: A Geographical Perspective

This paper reports results of a qualitative study of community development approaches to heart health promotion in Ontario. Cardiovascular disease (CVD) represents a substantial proportion of the burden of illness experienced by western industrialized countries. Biomedical research has implicated lifestyle choices and socioeconomic conditions as primary determinants of CVD. There has been a resultant shift from curative to preventive/health promoting strategies to reduce this burden of illness. The Canadian Heart Health Initiative-Ontario Project (CHHIOP), a two-stage (quantitative and qualitative) longitudinal study, was designed to address issues of heart health promotion through the investigation and strengthening of community-based heart health activities in both the formal and informal public health systems. The study reported on in this paper forms one part of the qualitative stage and focuses on how community relationships and community development approaches play out in local contexts to shape the reality of (heart) health promotion practice. Analysis of key informant interviews using Ethnograph illustrates the centrality of community context, the lack of a common understanding of key concepts (e.g., community development), and the emergence of a shift in health agencies' ways of doing business characterized by increased partnering and collaboration in the delivery of (heart) health promotion programs. Local perspectives and the dynamics of intra-community relations were allowed to emerge through the use of qualitative approaches implying a need for place-sensitive (heart) health promotion strategies.     

Nature of sedimentary deposits in the western Makgadikgadi basin, Botswana

Quaternary sedimentation in the western Makgadikgadi basin of north central Botswana is evaluated on the basis of new evidence from satellite imagery and sedimentological analyses. Thematic Mapper imagery interpretation, combined with field evidence, has led to the identification of geomorphological features which are mainly composed of light grey calcareous sandstones (formerly calcretes) overlain by dark grey sands. The literature suggests that palaeolake Makgadikgadi I formed and developed intermittently after initial downwarping in the early–mid Pleistocene. The calcareous sandstones were formed when calcium carbonate precipitation took place in pre-existing Kalahari sands along the western shoreline of Makgadikgadi I. Field evidence, supported by X-ray diffraction and SEM analyses, indicates that CaCO₃precipitated mainly in marshy conditions around plant roots and stems and in association with bacteria in embayments along the lakeshore. The sandstones thickened and became partially indurated as a result of increasing palaeolake levels. Deposition was terminated by renewed tectonism which uplifted the shoreline zone relative to the lake basin, leading to falling palaeolake levels. Post-uplift reworking led to case hardening and pedogenic calcrete formation in the upper sections of the calcareous sandstones. Sedimentary conditions altered during the late Pleistocene. Extensive distributaries from the proto-Okavango system incised the shoreline ridge contributing to the filling of Makgadikgadi II. Satellite data suggest that the proto-Okavango rivers formed a series of fan deltas at this time along the western Makgadikgadi basin. Widespread dispersal of fluvial grey sands took place as a result of basin tilting which led to anastomosing channels flowing southward possibly around 18,000 B.P. These results, although preliminary in nature, augment previous geomorphological analyses by adding some detail in terms of depositional environments and by providing a tentative age and origin for the ubiquitous grey sands.     

Moraine Exposure Dates Imply Synchronous Younger Dryas Glacier Advances in the European Alps and in the Southern Alps of New Zealand

Samples taken from the top surfaces of boulders on the Lake Misery moraines at Arthur's Pass, in the Southern Alps of New Zealand, were analysed for ¹⁰Be by accelerator mass spectrometry. Exposure ages calculated with the currently accepted production rate, along with scaling corrections for sample latitude and elevation (42°50'S, 960 m), are: 9300 ± 990, 11,000 ± 1360, 11,410 ± 1030, 12,050 ± 960, and 12,410 ± 1180 years. We consider the date of 9300 years to be an outlier, not included in our mean exposure age of 11,720 ± 320 years for the Lake Misery moraines. Based on exposure ages and geomorphologic similarities, we compare the Lake Misery moraines with an Egesen moraine complex at Julier Pass in the Swiss Alps (46°30'N, 2200 m). Based on the ¹⁰Be, ²⁶Al, and ³⁶Cl exposure ages of three boulders, we calculate a mean exposure age of 11,750 ± 140 years for the outer Egesen moraine at Julier Pass. Based solely on ¹⁰Be measurements, we obtain a mean exposure age of 11,860 ± 210 years for this outer moraine. Egesen moraines in the Swiss Alps represent glacier readvance during the Younger Dryas cold reversal, based on regional correlations and on basal radiocarbon dates from bogs located up-valley of Egesen moraines. The exposure dates from Arthur's Pass and Julier Pass show synchronous glacier advances both in the Southern Alps and in the European Alps during the European Younger Dryas chronozone of Mangerud et al .     

The nature of publishing and assessment in Geography and Environmental Studies: evidence from the Research Assessment Exercise 2008

We present a summary of the kinds of outputs submitted to the Geography and Environmental Studies sub-panel (H-32) for the 2008 Research Assessment Exercise (RAE), and examine the relationships between the peer assessment of research quality that the RAE process has typified, and alternative modes of assessment based on bibliometrics. This comparison is effected using (in aggregate form) some of the results from the RAE, together with citation data gathered after completion of the RAE assessment, specifically for the purpose of this paper. We conclude that, if it continues to be necessary and desirable to assess, in some measure and however imprecisely, research quality, then peer assessment cannot be replaced by bibliometrics. Bibliometrics permit measurement of something that may be linked to quality but is essentially a different phenomenon – a measure of 'impact', for example.     

Spatial and compositional variations within finely laminated mineral crusts at Carpenter's Gap,an archaeological site in tropical Australia

Mineralogical and geochemical variations in ten rock surface crusts are described from a large rock shelter known as Carpenter's Gap 1 in the southern Kimberley, formed at the junction between a sandstone floor and an overlying limestone roof. The finely laminated crusts, containing quartz, clays, oxalate and phosphate minerals, and sulfate salts (bassanite, gypsum, epsomite), formed over quartz‐rich sandstones. Mineralogical analyses of crusts, determined by X‐ray diffraction, and major element geochemical trends, in the form of element maps of cross sections, show a complex distribution of hemi‐, mono‐, and dihydrated sulfate and oxalate minerals vertically and laterally within the shelter. These mineralogical changes have occurred under fluctuating moisture and temperature regimes, which follow a general drying trend spatially with distance from the back wall and temporally over a period of about 20,000 years. Documenting these mineralogical changes is a first step in understanding the nature of microclimatic controls on the formation of rock surface coatings in shelters and their implications for palaeoenvironmental reconstructions and for dating engravings covered by these crusts. © 2001 John Wiley & Sons, Inc.     

Winter rainfall interception by two mature open‐grown trees in Davis,California

A rainfall interception measuring system was developed and tested for open‐grown trees. The system includes direct measurements of gross precipitation, throughfall and stemflow, as well as continuous collection of micrometeorological data. The data were sampled every second and collected at 30‐s time steps using pressure transducers monitoring water depth in collection containers coupled to Campbell CR10 dataloggers. The system was tested on a 9‐year‐old broadleaf deciduous tree (pear, Pyrus calleryana ‘Bradford’) and an 8‐year‐old broadleaf evergreen tree (cork oak, Quercus suber) representing trees having divergent canopy distributions of foliage and stems. Partitioning of gross precipitation into throughfall, stemflow and canopy interception is presented for these two mature open‐grown trees during the 1996–1998 rainy seasons. Interception losses accounted for about 15% of gross precipitation for the pear tree and 27% for the oak tree. The fraction of gross precipitation reaching the ground included 8% by stemflow and 77% by throughfall for the pear tree, as compared with 15% and 58%, respectively, for the oak tree. The analysis of temporal patterns in interception indicates that it was greatest at the beginning of each rainfall event. Rainfall frequency is more significant than rainfall rate and duration in determining interception losses. Both stemflow and throughfall varied with rainfall intensity and wind speed. Increasing precipitation rates and wind speed increased stemflow but reduced throughfall. Analysis of rainfall interception processes at different time‐scales indicates that canopy interception varied from 100% at the beginning of the rain event to about 3% at the maximum rain intensity for the oak tree. These values reflected the canopy surface water storage changes during the rain event. The winter domain precipitation at our study site in the Central Valley of California limited our opportunities to collect interception data during non‐winter seasons. This precipitation pattern makes the results more specific to the Mediterranean climate region. Copyright © 2000 John Wiley & Sons, Ltd.     

The assessment of vitellogenin as a biomarker of exposure to estrogenic compounds in two Australian perciformes

Vitellogenin (Vtg) is a yolk protein precursor that has been identified as a sensitive biomarker for exposure to estrogenic compounds. We evaluated specific monoclonal and polyclonal antibodies for reactivity with plasma Vtg from two Australian Perciformes, the tropical barramundi (Lates calcarifer) and the temperate black bream (Acanthopagrus butcheri). Blood plasma from 17beta-estradiol exposed (E2) male barramundi (20 mg kg(-1)) and male black bream (2.5-5.0 mg kg(-1)) were sent to Biosense Laboratories (Norway) for cross-reactivity testing using their extensive anti-Vtg antibody selection. Indirect ELISA results determined barramundi plasma displayed the highest binding affinities to ND-3G2 (monoclonal-Mab) and PO-1 (polyclonal-Pab). Black bream was most cross-reactive with ND-1C8 (Mab) and PO-2 (Pab). Next, plasma was assessed for Vtg induction in E2-dosed (5 mg kg(-1)), hatchery-reared barramundi and black bream versus a non-injected control group. Vtg production was assessed by Western blot and indirect ELISA using ND-3G2 and ND-1C8 Mabs, respectively. A prominent band was identified in the range of 100-200 kDa for all female black bream and for all E2-treated barramundi and black bream males, which was confirmed as Vtg by Western blot. Indirect ELISA results for barramundi demonstrated highly significant differences in E2-dosed fish as compared to control fish (Student t, P<0.001). E2 male black bream were significantly different than control males (Student t, P<0.001) and control and E2 females displayed highly significant differences (Student t, P<0.001). These results indicate that exposure to 17beta-estradiol induces significant Vtg production in males of the two Australian Perciformes, with potential use as a biomarker for exposure to estrogenic compounds.