An experimental investigation of barite formation in seawater

We report results from time-series decay and sequential leaching experiments of laboratory cultured and coastal plankton to elucidate the mechanisms controlling barite formation in seawater. Batch-cultured diatoms (Stephanopyxis palmerina) and coccolithophorids (Emiliania huxleyi) were let to decay in the dark for 8-10 weeks, suspended in aerated seawater. The development of barite crystals was monitored by Scanning Electron Microscopy (SEM). A similar experiment was conducted with plankton collected during the spring-bloom in Vineyard Sound (MA). In addition to SEM, suspended particles were sequentially leached for Ba (distilled water rinse; 10% (v/v) HNO₃ rinse at room temperature; 30% (v/v) HCl at 80°C overnight; 50% (v/v) HNO₃ at 80°C overnight) immediately after collection, and after 10-week decay in seawater, in seawater poisoned with HgCl₂, and in seawater spiked with ¹³⁵Ba.Both experiments showed an increase in the number of barite crystals during decay. The spring-bloom plankton had initially a large pool of labile Ba, soluble in distilled water and cold dilute HNO₃ that was lost from the plankton after 10-week decay in both axenic and nonaxenic conditions. In contrast, Ba in the decayed plankton samples was predominantly in forms extracted by hot HCl and hot HNO₃ acids, which were attributed to presence of barite Ba and refractory organic Ba respectively. The increase in barite crystal counts under a Scanning Electron Microscope (SEM), the increase in HCl extractable Ba relative to organic carbon, and the loss of a large fraction of Ba during plankton decay suggest that living plankton consists of a relatively large pool of labile Ba, which is rapidly released during plankton decomposition and acts as the main source of Ba for barite formation in supersaturated microenvironments. Since mass balance indicates that only a small proportion (2 to 4%) of the labile-Ba pool is converted to barite, the availability of microenvironments that could locally concentrate Ba released by plankton decay seems to be the main limiting factor in barite precipitation.     

The Big Questions in Geography

In noting his fondness for geography, John Noble Wilford, science correspondent for The New York Times, nevertheless challenged the discipline to articulate those big questions in our field, ones that would generate public interest, media attention, and the respect of policymakers. This article presents our collective judgments on those significant issues that warrant disciplinary research. We phrase these as a series of ten questions in the hopes of stimulating a dialogue and collective research agenda for the future and the next generation of geographic professionals.     

Chinese Industrial and Science Parks: Bridging the Gap

This article proposes the addition of a “bridge high technology” stage to Park's (1996) Asian development model, based upon field research and analysis of four “science and technology parks” in different regions of China: Shenzhen, Shanghai, Suzhou, and Xi’an. Initially established as learning districts to foster technology transfer from foreign to domestic enterprises, these specially configured spaces exhibit a variety of interactions indicating an increasing shift toward domestically generated technology for native companies. The mix and type of companies in parks at different locations within China reflect the locational comparative advantages of each place, whether as an outgrowth of local research or by government design.     

Resilience and justice: planning for New York City

New York City has developed recent policy initiatives under the rubric of resilience. I consider the implications of extending the concept of resilience beyond the physical environment, analyze the effect of planning for adaptation rather than prevention, and finally examine the positive role played by community groups organized for environmental justice in responding to resiliency planning. My argument is that use of the term resilience tends to obscure distributional impacts and, even under a progressive mayor, supports neoliberal policy initiatives.     

Multiproxy surface wetness records from replicate cores on an ombrotrophic mire: implications for Holocene palaeoclimate records

Ombrotrophic mires can provide records of palaeoclimate over the mid- to late- Holocene in several areas of the world. Their potential is currently partly limited by difficulties with scaling indices based on plant macrofossils and humification, and the need to account for the internal variability of the mire system. This paper explores the use of testate amoebae analysis as a third technique and assesses the minimum within-site variability by comparing results from two closely spaced cores. Reconstruction of surface wetness changes was carried out on cores from the centre of an intermediate raised-blanket mire, Coom Rigg Moss, Northumberland, by analysis of testate amoebae, plant macrofossils and humification. Surface wetness changes were expressed as mean annual water table changes inferred from testate amoebae assemblages, two separate indices based on plant macrofossils and percentage transmission of humification extracts. Comparisons between the proxies suggest good agreement of general trends in Sphagnum peats but some differences in monocot and ericaceous peats. The magnitude of surface wetness changes also differs within Sphagnum peats. The records from the separate cores converge over time and replicability between cores is best in the last 1000 yr. Changes over this period are similar to those shown by estimates based on documentary sources. Good agreement is obtained between a normalised plant macrofossil index and normalised reconstructed water-table values and it is suggested that this approach could form the basis for improved composite, multiproxy records from peatlands. Copyright © 1999 John Wiley & Sons, Ltd.     

Using Resin‐Based 3D Printing to Build Geometrically Accurate Proxies of Porous Sedimentary Rocks

Three‐dimensional (3D) printing is capable of transforming intricate digital models into tangible objects, allowing geoscientists to replicate the geometry of 3D pore networks of sedimentary rocks. We provide a refined method for building scalable pore‐network models (“proxies”) using stereolithography 3D printing that can be used in repeated flow experiments (e.g., core flooding, permeametry, porosimetry). Typically, this workflow involves two steps, model design and 3D printing. In this study, we explore how the addition of post‐processing and validation can reduce uncertainty in the 3D‐printed proxy accuracy (difference of proxy geometry from the digital model). Post‐processing is a multi‐step cleaning of porous proxies involving pressurized ethanol flushing and oven drying. Proxies are validated by: (1) helium porosimetry and (2) digital measurements of porosity from thin‐section images of 3D‐printed proxies. 3D printer resolution was determined by measuring the smallest open channel in 3D‐printed “gap test” wafers. This resolution (400 µm) was insufficient to build porosity of Fontainebleau sandstone (～13%) from computed tomography data at the sample's natural scale, so proxies were printed at 15‐, 23‐, and 30‐fold magnifications to validate the workflow. Helium porosities of the 3D‐printed proxies differed from digital calculations by up to 7% points. Results improved after pressurized flushing with ethanol (e.g., porosity difference reduced to ～1% point), though uncertainties remain regarding the nature of sub‐micron “artifact” pores imparted by the 3D printing process. This study shows the benefits of including post‐processing and validation in any workflow to produce porous rock proxies.     

Understanding fracture distribution and its relation to knickpoint evolution in the Rio Icacos watershed (Luquillo Critical Zone Observatory,Puerto Rico) using landscape-scale hydrogeophysics

The Rio Icacos watershed in the Luquillo Mountains (Puerto Rico) is unique due to its extremely rapid weathering rates. The watershed is incised into a quartz diorite that has developed a large knickzone defining the river profile. Regolith thickness within the watershed generally decreases from 20 to 30 m at the ridges to several meters in the quartz diorite-dominated valley to tens of centimeters near the major river knickpoint, as determined from previous studies. Above the knickzone, we observe spheroidal corestones, but below this weathering is much less apparent. Measured erosion rates from previous studies are also high in the knickzone compared with upper elevations within the river profile. A suite of near-surface geophysical methods (i.e. ground penetrating radar and terrain conductivity) capable of fast data acquisition in rugged landscapes, was deployed at kilometer scales to characterize critical zone structure. Concentrations of chaotic ground penetrating radar (GPR) reflections and diffraction hyperbolas with low electrical conductivity were observed in vertical zones that outcrop at the land surface as areas of intense fracturing and spheroidally weathered corestones. The width of these fractured and weathered zones showed an increase with proximity to the knickpoint, and was attributed to dilation of these sub-vertical fractures near the knickpoint, as postulated theoretically by a stress model calculated for the topographic variability across the knickzone in the Rio Icacos, and that shows a release of compressive stress near the knickpoint. We hypothesize that erosion rates increase in the knickzone because of this inferred dilation of fractures. Specifically, opened fractures could enhance access of water and in turn promote spalling, erosion, and spheroidal weathering. This study shows that ground-based hydrogeophysical methods used at the landscape-scale (traditionally applied at smaller scales) can be used to explore critical zone architecture at the scales needed to explain the extreme variability in erosion rates across river profiles. © 2018 John Wiley & Sons, Ltd.