New abundance determinations in z < 1.5 QSO absorbers: seven sub-DLAs and one DLA

We present chemical abundance measurements from high-resolution observations of seven subdamped Lyα (sub-DLA) absorbers and one DLA system at   z < 1.5  . Three of these objects have high metallicity, with near or supersolar Zn abundance. Grids of cloudy models for each system were constructed to look for possible ionization effects in these systems. For the systems in which we could constrain the ionization parameter, we find that the ionization corrections as predicted by the cloudy models are generally small and within the typical error bars (∼0.15 dex), in general agreement with previous studies. The Al  iii to Al  ii ratio for these and other absorbers from the literature are compared, and we find that while the sub-DLAs have a larger scatter in the Al  iii to Al  ii ratios than the DLAs, there appears to be little correlation between the ratio and   N _{H  i}   . The relationship between the metallicity and the velocity width of the profile for these systems is investigated. We show that the sub-DLAs that have been observed to date follow a similar trend as DLA absorbers, with the more metal rich systems exhibiting large velocity widths. We also find that the systems at the upper edge of this relationship with high metallicities and large velocity widths are more likely to be sub-DLAs than DLA absorbers, perhaps implying that the sub-DLA absorbers are more representative of massive galaxies.     

Postseismic relaxation due to Bhuj earthquake on January 26, 2001: possible mechanisms and processes

Earthquakes cause static stress perturbations in the nearby crust and mantle. Obeying rheological laws, this stress relaxes in a time frame of months to years with the spatial extent of few km to hundreds of km. While postseismic relaxation associated with major inter-plate earthquakes is well established, there have been few opportunities to explore its occurrence following intraplate earthquakes. The M _w 7.6 Bhuj earthquake on January 26, 2001 in western India is considered to be an intraplate event and provided a unique opportunity to examine post-earthquake relaxation processes sufficiently away from plate boundaries. To study the characteristics of transient postseismic deformation, six Global Positioning System campaigns were made at 14 sites. The postseismic transients were delineated after removing plate motions from the position time series. Postseismic deformation has been observed at all the sites in the study area. During 2001?C2007, the site closest to the epicenter exhibited postseismic deformation of about 30 and 25?mm in the north and east components, respectively. Time series of the NS and EW components of the postseismic transients can be fitted to both logarithmic and exponential functions. Close to the epicenter, the logarithmic function fits well to the initial transient, and an exponential function fits well to the later phases. The remaining sites (located east and west of the epicentral region) exhibited significantly diminished north?Csouth relaxation. Rapidly decaying afterslip and poroelastic mechanisms seem to be responsible for postseismic relaxation in the vicinity of epicenter during the initial period subsequent to the Bhuj earthquake. Postseismic relaxation by viscoelastic flow below the seismogenic zone seems to affect displacements across the entire Bhuj region. This paper presents the characteristics of postseismic transients and deformation processes in the scenario of the highly heterogeneous crust in the Bhuj region.     

Red clouds in reducing atmospheres

A dark reddish-brown high-molecular-weight polymer is produced by long wavelength ultraviolet irradiation of abundant gases in reducing planetary atmospheres. The polymer i examined by paper chromatography, mass spectrometry, and infrared, visible, and ultraviolet spectroscopy. High carbon-number straight-chain alkanes with NH₂ and, probably, OH and CO groups are identified, along with the previously reported amino acids. There are chemical similarities between this polymer and organic compounds recovered from carbonaceous chondrites and precambrian sediments. The visible and near-ultraviolet transmission spectrum of the polymer shows its absorption optical depth to be redder than λ^?2 and perhaps similar in coloration to the clouds of Jupiter, Saturn, and Titan. The near-ultraviolet absorption coefficient is ～10³ cm^?1, and typical grain sizes ～30 μm. The nitrile content is small, and the polymer should be semitransparent in the 5 μm atmospheric window. Such polymers may be a common constituent of clouds in the outer solar system and on the early Earth.     

Lower bound solutions for uplift capacity of strip anchors adjacent to sloping ground in clay

Numerical solutions have been obtained for the vertical uplift capacity of strip plate anchors embedded adjacent to sloping ground in fully cohesive soil under undrained condition. The analysis was performed using finite element lower bound limit analysis with second-order conic optimization technique. The effect of anchor edge distance from the crest of slope, angle and height of slope, normalized overburden pressure due to soil self-weight, and embedded depth of anchor on the uplift capacity has been examined. A nondimensional uplift factor defined as F_cγ owing to the combined contribution of soil cohesion (c_u), and soil unit weight (γ) is used for expressing the uplift capacity. For an anchor buried near to a sloping ground, the ultimate uplift capacity is dependent on either pullout failure of anchor or overall slope failure. The magnitude of F_cγ has been found to increase with an increase in the normalized overburden pressure up to a certain maximum value, beyond which either the behavior of anchor transfers from shallow to deep anchor or overall slope failure occurs.     

Modelling soil water dynamics considering measurement uncertainty

In shallow water table‐controlled environments, surface water management impacts groundwater table levels and soil water dynamics. The study goal was to simulate soil water dynamics in response to canal stage raises considering uncertainty in measured soil water content. Water and Agrochemicals in the soil, crop and Vadose Environment (WAVE) was applied to simulate unsaturated flow above a shallow aquifer. Global sensitivity analysis was performed to identify model input factors with the greatest influence on predicted soil water content. Nash–Sutcliffe increased and Root Mean Square Error reduced when uncertainties in measured data were considered in goodness‐of‐fit calculations using measurement probability distributions and probable asymmetric error boundaries, implying that appropriate model performance evaluation should be carried out using uncertainty ranges instead of single values. Although uncertainty in the experimental measured data limited evaluation of the absolute predictions by the model, WAVE was found a useful exploratory tool for estimating temporal variation in soil water content. Visual analysis of soil water content time series under proposed changes in canal stage management indicated that sites with land surface elevation of less than 2.0‐m NGVD29 were predicted to periodically experience saturated conditions in the root zone and shortening of the growing season if canal stage is raised more than 9 cm and maintained at this level. The models developed could be combined with high‐resolution digital elevation models in future studies to identify areas with the greatest risk of experiencing saturated root zone. The study also highlighted the need to incorporate measurement uncertainty when evaluating performance of unsaturated flow models. Copyright © 2014 John Wiley & Sons, Ltd.     

Green Electronics through Legislation and Lead Free Soldering

Management of used electrical and electronic equipment (EEE) is becoming a major issue as each year around 20 to 50 million tonnes of electronic waste (e‐waste) is generated worldwide. EEE contains over 1000 materials of which lead (Pb) has been one of the targets of the regulators forcing manufacturers to adopt lead free products. Industry has come up with several lead free solders with preference given to alloys containing tin, silver, and copper but there is no ,drop‐in' substitute to leaded solder. Issues with lead free solders such as temperature, intermetallics, tin whisker, tin pest, and reliability are yet to be resolved. The paper investigated the contribution of lead free soldering to green electronics in a holistic way. Global lead free movement has reached a point of no return. However, it is necessary to make sure that life span of EEE is not shortened thereby resulting in an unforeseen increase in e‐waste or problem shifting does not occur by shifting a problem from one life cycle to another or from one category/media to another.     

Polycyclic aromatic hydrocarbons in the atmospheres of Titan and Jupiter

Polycyclic aromatic hydrocarbons (PAHs) are important components of the interstellar medium and carbonaceous chondrites, but have never been identified in the reducing atmospheres of the outer solar system. Incompletely characterized complex organic solids (tholins) produced by irradiating simulated Titan atmospheres reproduce well the observed UV/visible/IR optical constants of the Titan stratospheric haze. Titan tholin and a tholin generated in a crude simulation of the atmosphere of Jupiter are examined by two-step laser desorption/multiphoton ionization mass spectrometry. A range of two- to four-ring PAHs, some with one to four alkylation sites are identified, with net abundance approximately 10(-4) g g-1 (grams per gram) of tholins produced. Synchronous fluorescence techniques confirm this detection. Titan tholins have proportionately more one- and two-ring PAHs than do Jupiter tholins, which in turn have more four-ring and larger PAHs. The four-ringed PAH chrysene, prominent in some discussions of interstellar grains, is found in Jupiter tholins. Solid state 13C NMR spectroscopy suggests approximately equal to 25% of the total C in both tholins is tied up in aromatic and/or aliphatic alkenes. IR spectra indicate an upper limit in both tholins of approximately equal to 6% by mass in benzenes, heterocyclics, and PAHs with more than four rings. Condensed PAHs may contribute at most approximately 10% to the observed detached limb haze layers on Titan. As with interstellar PAHs, the synthesis route of planetary PAHs is likely to be via acetylene addition reactions.     

A GIS-based Spatial Pattern Analysis Model for eco-region mapping and characterization

Growing concerns about global climate change, biodiversity maintenance, natural resources conservation, and long-term ecosystem sustainability have been responsible for the transformation of traditional single resource management approaches into integrated ecosystem management models. Eco-regions are large ecosystems of regional extent that contain smaller ecosystems of similar response potential and resource production capabilities. They can be used as a geographical framework for organizing and reporting resource information, setting bioecological recovery criteria, extrapolating site-level management, and monitoring global change. The objective of this research is to develop a quantitative, multivariate regionalization model that is capable of delineating eco-regions at multiple levels from remotely sensed information and other environmental and natural resources spatial data. The Spatial Pattern Analysis Model developed in this study uses a region-growing algorithm to generate spatially contiguous regions from primitive polygonal land units. The algorithm merges the most similar pair of neighbouring units at each iteration, based on satisfying certain similarity criteria until all units are grouped into one. This model was utilized to develop an eco-region map of Nebraska with three hierarchical levels. In the mapping process, the STATSGO data set was used to build the primitive map units. Environmental parameters included in the model were multi-temporal AVHRR data, soil rooting depth, organic matter content, available water capacity, and long-term annual averages of water balance and growing degree day totals. Development of the model provides a new and useful approach to eco-region mapping for resource managers and researchers. The method is automated and efficient, reduces the judgement biases and uncertainty of manual analyses, and can be replicated for other regions or for the regionalization of other themes.     

Temporal variations in Sr and 87Sr/86Sr of the Ganga headwaters: estimates of dissolved Sr flux to the mainstream

The headwaters of the Ganga (the Alaknanda, Bhagirathi and the Ganga) were analysed for their dissolved major ions, Sr and ⁸⁷Sr/⁸⁶Sr on a biweekly to monthly basis over a period of one year to determine their temporal variations and the factors contributing to them. The concentrations of major ions and Sr show significant seasonal variation with lower values during monsoon period in all the three rivers. A similar trend is also observed for ⁸⁷Sr/⁸⁶Sr and Na*/Ca (Na* = Na_r? Cl_r) suggesting relatively lower contribution of Sr and Na from silicates (which are more radiogenic in Sr) during monsoon. Budget calculations show that silicate derived dissolved Sr (Sr_s) in the river Ganga, Alaknanda and the Bhagirathi varied from 10 ± 4 to 27 ± 11, 7 ± 3 to 30 ± 12, 16 ± 6 to 57 ± 23% of measured Sr respectively with lower values during monsoon. The relative decrease in silicate erosion compared to carbonate during monsoon can result from several factors, these include higher dissolution kinetics of the carbonates, lower water–rock interaction time and availability of larger area for weathering. The annual discharge weighted Sr flux derived from the time series data is higher by ～20% from that based on peak flow Sr, and lower by ～40% compared to that derived from lean flow Sr concentration. The area‐normalized annual flux of dissolved Sr from the Ganga at Rishikesh is about five times its flux at Rajshahi (Bangladesh) and a few other major global rivers, such as the Amazon, indicating higher erosion rate over the Himalaya. Copyright © 2010 John Wiley & Sons, Ltd.