Elucidation of the Alum Shale kerogen structure using a multi-disciplinary approach

The significance and validity of integrating data obtained from a variety of analytical techniques to understand, elucidate and model kerogen's complex chemical structure is reported here using degradative (open and closed system pyrolysis, chemical oxidation), non-degradative (¹³C CP/MAS NMR) and optical (incident white light and blue light) methods. Seven Cambrian Alum Shale samples, ranging in maturity from immature to post-mature with respect to petroleum generation, were studied and were chosen for their simple geological history, uniform organic matter type and high organic carbon content. The Alum Shale kerogens, which primarily consist of algal organic matter, liberate low molecular weight gaseous and aromatic compounds on pyrolysis and give mostly branched dicarboxylic acids on chemical oxidation. ¹³C NMR spectroscopy shows that the Alum Shale kerogens are anomalously rich in oxygen-bearing functional groups (such as C = O, ArCO, CHO, CH_xO), most of which apparently remain intact within the kerogen macro-molecule (KMM) through the diagenetic and catagenetic stages. Fragments released by different degradative techniques are quantified and the aromaticity (f_a), O/C and relative proportions of various carbon types estimated by ¹³C NMR. A synthesis of these data has allowed us to better understand the chemistry of the Alum Shale kerogen.     

Hydraulic and compaction characteristics of leachate-contaminated lateritic soil

Large quantities of leachate-contaminated lateritic soil results from dump yards in the southwest coast of India. These dump yards receive large quantities of municipal solid waste which includes chemical, industrial and biomedical wastes. Large areas of land are currently being used for this purpose. An extensive laboratory testing program was carried out to determine the compaction characteristics and hydraulic conductivity of clean and contaminated lateritic soil. Batch tests were used to study the immediate effect of leachate contamination on the properties of lateritic soil. Contaminated specimens were prepared by mixing the lateritic soil with leachate in the amount of 5%, 10% and 20% by weight to vary the degree of contamination. The results indicated a small reduction in maximum dry density and an increase in hydraulic conductivity due to leachate-contamination. The change induced by chemical reaction in the microstructure of the soil was studied by scanning electron microscope before and after contamination of soil with leachate. The structure of the leachate contaminated soil sample appeared to be aggregated in scanning electron microscope analysis. The aggregated structure increases the effective pore space and thus increases the hydraulic conductivity. Fifty percent increase in hydraulic conductivity was observed for specimens prepared at standard Proctor density and mixed with 20% leachate. Compaction characteristics did not change much with the presence of leachate up to 10%. With 20% leachate the maximum dry density decreased slightly indicating excess leachate in the soil. However the changes are not significant.     

Sustainable Management of Electronic Waste (e-Waste)

Electronic waste or e-waste is one of the fastest growing areas of the international waste stream and is increasing at a much higher rate than all other waste streams. Fast growing electronics industries arising from the demands of information and communication technologies around the world coupled with the rapid product obsolescence and lack of end-of-life management options, have all led to the unsustainable management of the waste stream. Computers are manufactured from over 1,000 materials, many of which are toxic, and they contribute significantly to the e-waste stream, which is estimated to be ca. 20 to 50 million tonnes annually. Design for environment cleaner production, extended producer responsibility, standards and labeling, product stewardship, recycling and remanufacturing are some of the practices adopted by various countries around the world to deal with the e-waste stream. An overview of these practices is presented and the manner in which they contribute to the sustainable management of e-waste is discussed.     

Silicate and carbonate weathering in the drainage basins of the Ganga-Ghaghara-Indus head waters: Contributions to major ion and Sr isotope geochemistry

The role of silicate and carbonate weathering in contributing to the major cation and Sr isotope geochemistry of the headwaters of the Ganga-Ghaghara-Indus system is investigated from the available data. The contributions from silicate weathering are determined from the composition of granites/ gneisses, soil profiles developed from them and from the chemistry of rivers flowing predominantly through silicate terrains. The chemistry of Precambrian carbonate outcrops of the Lesser Himalaya provided the data base to assess the supply from carbonate weathering. Mass balance calculations indicate that on an average ∼ 77% (Na + K) and ∼ 17% (Ca + Mg) in these rivers is of silicate origin. The silicate Sr component in these waters average ∼40% and in most cases it exceeds the carbonate Sr. The observations that (i) the⁸⁷Sr/⁸⁶Sr and Sr/Ca in the granites/gneisses bracket the values measured in the head waters; (ii) there is a strong positive correlation between⁸⁷Sr/⁸⁶Sr of the rivers and the silicate derived cations in them, suggest that silicate weathering is a major source for the highly radiogenic Sr isotope composition of these source waters. The generally low⁸⁷Sr/⁸⁶Sr (< 0.720) and Sr/Ca (∼ 0.2 nM/ μM) in the Precambrian carbonate outcrops rules them out as a major source of Sr and⁸⁷Sr/⁸⁶Sr in the headwaters on a basin-wide scale, however, the high⁸⁷Sr/⁸⁶Sr (∼ 0.85) in a few of these carbonates suggests that they can be important for particular streams. The analysis of⁸⁷Sr/⁸⁶Sr and Ca/Sr data of the source waters show that they diverge from a low⁸⁷Sr/⁸⁶Sr and low Ca/Sr end member. The high Ca/Sr of the Precambrian carbonates precludes them from being this end member, other possible candidates being Tethyan carbonates and Sr rich evaporite phases such as gypsum and celestite. The results of this study should find application in estimating the present-day silicate and carbonate weathering rates in the Himalaya and associated CO₂ consumption rates and their global significance.     

Anisotropic universe with cosmic strings and bulk viscosity

Spatially homogeneous and anisotropic LRS Bianchi type-I string cosmological models are studied in the frame work of general relativity when the source for the energy momentum tensor is a bulk viscous fluid containing one dimensional strings. A barotropic equation of state for the pressure and density is assumed to get determinate solutions of the field equations. The bulk viscous pressure is assumed to be proportional to the energy density. The physical and kinematical properties of the models are discussed. The role of bulk viscosity in getting an inflationary phase in the universe is studied.     

Chemistry of snow and lake water in Antarctic region

Surface snow and lake water samples were collected at different locations around Indian station at Antarctica, Maitri, during December 2004–March 2005 and December 2006–March 2007. Samples were analyzed for major chemical ions. It is found that average pH value of snow is 6.1. Average pH value of lake water with low chemical content is 6.2 and of lake water with high chemical content is 6.5. The Na⁺ and Cl^? are the most abundantly occurring ions at Antarctica. Considerable amount of SO ₄ ^2? is also found in the surface snow and the lake water which is attributed to the oxidation of DMS produced by marine phytoplankton. Neutralization of acidic components of snow is mainly done by NH ₄ ⁺ and Mg²⁺. The Mg²⁺, Ca²⁺ and K⁺ are nearly equally effective in neutralizing the acidic components in lake water. The NH ₄ ⁺ and SO ₄ ^2? occur over the Antarctica region mostly in the form of (NH₄)₂SO₄.     

Dissolved Boron in the Tapi,Narmada and the Mandovi Estuaries,the Western Coast of India: Evidence for Conservative Behavior

The concentrations of dissolved boron have been measured during different seasons in three estuaries, the Tapi, Narmada and the Mandovi situated on the western coast of India, to investigate its geochemical behavior and inputs from the localized anthropogenic pressures of industrial effluents and sewage discharge. The measured boron concentrations in these estuaries (except the Tapi during non-monsoon) at salinity ≤0.1 fall in a narrow range?～?2–4 μmol/kg (average B?～?2.4?±?0.8 μmol/kg) within the reported wide range?～?0.1–18.6 μmol/kg for global rivers. The much higher estimate of boron concentration in the Tapi River during non-monsoon is attributed to its possible additional supply from the sewage and/or industrial effluents discharged along the river course. During monsoon, the rains seem to be a significant source of dissolved boron to all the three rivers. The distribution of dissolved boron in each estuary exhibits a conservative behavior during the seasons sampled suggestive of no measurable addition or removal of boron in the estuarine region. The orders of magnitude differences in boron concentration between the river waters and seawater, and the conservative behavior of dissolved boron indicate that its major contributor to the estuaries sampled is seawater.     

Nine years of GPS measurements of crustal deformation at Imphal,Indo-Burmese wedge

We report results of 9 years of GPS measurements of crustal deformation at Imphal, Manipur, a site located in the Indo-Burmese wedge of northwest Sunda arc. The analysis of these measurements suggests that the site moves at a rate of about 36.3±0.5 mm/year towards N55° in the ITRF2008. With respect to the Indian plate it moves at a rate of 16.7 mm/year towards N222°, i.e., predominantly towards southwest. The site is located about 15 km east of the Churachandpur Mao fault (CMF), which is reported to accommodate part of the India-Sunda motion. The site motion is not significantly affected by the earthquakes that occurred in the nearby region. However, the 2004 Sumatra-Andaman earthquake caused a coseismic displacement of ～ 3–5 mm predominantly towards southwest. The site motion is almost linear, with some seasonal variation, and does not show any evidence of accelerated slip or slow earthquake on the CMF or along the plate boundary.     

GPR studies over the tsunami affected Karaikal beach,Tamil Nadu,south India

In this study, results of GPR profiling related to mapping of subsurface sedimentary layers at tsunami affected Karaikal beach are presented . A 400 MHz antenna was used for profiling along 262 m stretch of transect from beach to backshore areas with penetration of about 2.0 m depth (50 ns two-way travel time). The velocity analysis was carried out to estimate the depth information along the GPR profile. Based on the significant changes in the reflection amplitude, three different zones are marked and the upper zone is noticed with less moisture compared to other two (saturated) zones. The water table is noticed to vary from 0.5 to 0.75 m depth (12–15 ns) as moving away from the coastline. Buried erosional surface is observed at 1.5 m depth (40–42 ns), which represents the limit up to which the extreme event acted upon. In other words, it is the depth to which the tsunami sediments have been piled up to about 1.5 m thickness. Three field test pits were made along the transect and sedimentary sequences were recorded. The sand layers, especially, heavy mineral layers, recorded in the test pits indicate a positive correlation with the amplitude and velocity changes in the GPR profile. Such interpretation seems to be difficult in the middle zone due to its water saturation condition. But it is fairly clear in the lower zone located just below the erosional surface where the strata is comparatively more compact. The inferences from the GPR profile thus provide a lucid insight to the subsurface sediment sequences of the tsunami sediments in the Karaikal beach.     

The chemical composition of tertiary Indian coal ash and its combustion behaviour – a statistical approach: Part 2

In Part 1 of the present investigation, 37 representative Eocene coal samples of Meghalaya, India were analyzed and their physico-chemical characteristics and the major oxides and minerals present in ash samples were studied for assessing the genesis of these coals. Various statistical tools were also applied to study their genesis. The datasets from Part 1 used in this investigation (Part 2) show the contribution of major oxides towards ash fusion temperatures (AFTs). The regression analysis of high temperature ash (HTA) composition and initial deformation temperature (IDT) show a definite increasing or decreasing trend, which has been used to determine the predictive indices for slagging, fouling, and abrasion propensities during combustion practices. The increase or decrease of IDT is influenced by the increase of Fe₂O₃, Al₂O₃, SiO₂, and CaO, respectively. Detrital-authigenic index (DAI) calculated from the ash composition and its relation with AFT indicates Sialoferric nature of these coals. The correlation analysis, Principal Component Analysis (PCA), and Hierarchical Cluster Analysis (HCA) were used to study the possible fouling, slagging, and abrasion potentials in boilers during the coal combustion processes. A positive relationship between slagging and heating values of the coal has been found in this study.