Raman microspectrometry, FT-IR and inclusion characteristics of gem garnets from Tanzania and Madagascar

Chemical composition, Raman microspectrometry, and Fourier transform infrared (FT-IR) and SEM-CL (Cathodluminescence) analyses are carried out for Tanzania and Madagascar garnets for locality identification. Inclusion study was sustained after electron probe microanalysis (EPMA). Needle-like illmenites, apatites and zircons were the most common solid inclusions in Tanzania garnets. Madagascar garnets revealed rutile needles and apatites were also observed, but differences in size, shape and distribution patterns were noticed compared to Tanzania garnets. Tanzania garnets exhibited all types of observable fluid inclusions such as "fingerprint" pattern, called Type Ⅰ-A, liquid-only (L) single phase fluid inclusion, called Type Ⅰ-B and Type Ⅱ-A (L + S), Type Ⅱ-B (L + V) and Type Ⅲ-A (L + Sylvite +S), Type Ⅲ-B (L+S+V), while no more than two phase fluid inclusions found in both Madagascar and Korea garnets even if all examined garnets from three localities retained "fingerprint" features, so called, partially healed fractures, in common. Chemical composition, Raman microspectrometry and Fourier transform infrared (FT-IR) analysis taken turned out to be useful methods for the purpose of this study. Using consequences of SEM-CL and inclusion study, accordingly,the locality identification of gem-quality garnets is capable of being available in further application for other kinds of gemstones.     

Inversion of two-phase extensional basin systems during subduction of the Paleo-Pacific Plate in the SW Korean Peninsula:Implication for the Mesozoic “Laramide-style” orogeny along East Asian continental margin

During subduction, continental margins experience shortening along with inversion of extensional sedimentary basins. Here we explore a tectonic scenario for the inversion of two-phase extensional basin systems, where the Early-Middle Jurassic intra-arc volcano-sedimentary Oseosan Volcanic Complex was developed on top of the Late Triassic-Early Jurassic post-collisional sequences, namely the Chungnam Basin. The basin shortening was accommodated mostly by contractional faults and related folds. In the basement, regional high-angle reverse faults as well as low-angle thrusts accommodate the overall shortening, and are compatible with those preserved in the cover. This suggests that their spatial and temporal development is strongly dependent on the initial basin geometry and inherited structures.Changes in transport direction observed along the basement-sedimentary cover interface is a characteristic structural feature, reflecting sequential kinematic evolution during basin inversion. Propagation of basement faults also enhanced shortening of the overlying sedimentary cover sequences. We constrain timing of the Late Jurassic-Early Cretaceous(ca. 158-110 Ma) inversion from altered K-feldspar 40 Ar/39 Ar ages in stacked thrust sheets and K-Ar illite ages of fault gouges, along with previously reported geochronological data from the area. This "non-magmatic phase" of the Daebo Orogeny is contemporaneous with the timing of magmatic quiescence across the Korean Peninsula. We propose the role of flat/low-angle subduction of the Paleo-Pacific Plate for the development of the "Laramide-style" basement-involved orogenic event along East Asian continental margin.     

Adaptive second-order Volterra filtering and its application tosecond-order drift phenomena

This paper presents an adaptive second-order Volterra filter and its application to model-test data of a prototype tension leg platform (TLP). The least-squares approach of a second-order Volterra model and its adaptive filtering algorithm based on recursive least-squares are introduced. The second-order Volterra filter is applied to identify the linear and quadratically nonlinear relationship between irregular sea wave excitation and the surge response of a tension leg platform. Next, a deconvolution technique, based on the impulse invariance standard Z-transform, is utilized to recover the linear and quadratic forces exerted on the TLP     

Urbanization and the groundwater budget, metropolitan Seoul area, Korea

The city of Seoul is home to more than 10 million people in an area of 605 km². Groundwater is abstracted for public water supply and industrial use, and to drain underground facilities and construction sites. Though most tap water is supplied from the Han River, the quantity and quality of groundwater is of great concern to Seoul's citizens, because the use of groundwater for drinking water is continuously increasing. This study identifies the major factors affecting the urban water budget and quality of groundwater in the Seoul area and estimates the urban water budget. These factors include leakage from the municipal water-supply system and sewer systems, precipitation infiltration, water-level fluctuations of the Han River, the subway pumping system, and domestic pumping. The balance between groundwater recharge and discharge is near equilibrium. However, the quality of groundwater and ability to control contaminant fluxes are impeded by sewage infiltration, abandoned landfills, waste dumps, and abandoned wells. Electronic Publication     

The distribution of sodium ions in aluminosilicate glasses: a high-field Na-23 MAS and 3Q MAS NMR study

The local configurations around sodium ions in silicate glasses and melts and their distributions have strong implications for the dynamic and static properties of melts and thus may play important roles in magmatic processes. The quantification of distributions among charge-balancing cations, including Na⁺ in aluminosilicate glasses and melts, however, remains a difficult problem that is relevant to high-temperature geochemistry as well as glass science.Here, we explore the local environment around Na⁺ in charge-balanced aluminosilicate glasses (the NaAlO₂-SiO₂ join) and its distribution using ²³Na magic-angle spinning (MAS) nuclear magnetic resonance (NMR) spectroscopy at varying magnetic fields of 9.4, 14.1, and 18.8 T, as well as triple-quantum (3Q)MAS NMR spectroscopy at 9.4 T, to achieve better understanding of the extent of disorder around this cation. We quantify the extent of this disorder in terms of changes in Na-O distance (d[Na-O]) distributions with composition and present a structural model favoring a somewhat ordered Na distribution, called a “perturbed” Na distribution model. The peak position in ²³Na MAS spectra of aluminosilicate glasses moves toward lower frequencies with increasing Si/Al ratios, implying that the average d(Na-O) increases with increasing R. The peak width is significantly reduced at higher fields (14.1 and 18.8 T) because of the reduced effect of second-order quadrupolar interaction, and ²³Na MAS NMR spectra thus provide relatively directly the Na chemical shift distribution and changes in atomic environment with composition. Chemical shift distributions obtained from ²³Na 3Q MAS spectra are consistent with MAS NMR data, in which deshielding decreases with R. The average distances between Na and the three types of bridging oxygens (BOs) (Na-{Al-O-Al}, Na-{Si-O-Al}, and Na-{Si-O-Si}) were obtained from the correlation between d(Na-O) and isotropic chemical shift. The calculated d(Na-{Al-O-Al}) of 2.52 Å is shorter than the d(Na-{Si-O-Si}) of 2.81 Å, and d(Na-{Al-O-Al}) shows a much narrower distribution than the other types of BOs. ²³Na chemical shifts in binary (Al-free) sodium silicate glasses are more deshielded and have ranges distinct from those of aluminosilicate glasses, implying that d(Na-NBO) (nonbridging oxygen) is shorter than d(Na-BO) and that d(Na-{Si-O-Si}) in binary silicates can be shorter than that in aluminosilicate glasses. The results given here demonstrate that high-field ²³Na NMR is an effective probe of the Na⁺ environment, providing not only average structural information but also chemically and topologically distinct chemical shift ranges (distributions) and their variation with composition and their effects on static and dynamic properties.     

Effect of masonry infills on seismic performance of a 3‐storey R/C frame with non‐seismic detailing

The objective of this study is to investigate the effect of masonry infills on the seismic performance of low‐rise reinforced concrete (RC) frames with non‐seismic detailing. For this purpose, a 2‐bay 3‐storey masonry‐infilled RC frame was selected and a 1 : 5 scale model was constructed according to the Korean practice of non‐seismic detailing and the similitude law. Then, a series of earthquake simulation tests and a pushover test were performed on this model. When the results of these tests are compared with those in the case of the bare frame, it can be recognized that the masonry infills contribute to the large increase in the stiffness and strength of the global structure whereas they also accompany the increase of earthquake inertia forces. The failure mode of the masonry‐infilled frame was that of shear failure due to the bed‐joint sliding of the masonry infills while that of the bare frame appeared to be the soft‐storey plastic mechanism at the first storey. However, it is judged that the masonry infills can be beneficial to the seismic performance of the structure since the amount of the increase in strength appears to be greater than that in the induced earthquake inertia forces while the deformation capacity of the global structure remains almost the same regardless of the presence of the masonry infills. Copyright © 2001 John Wiley & Sons, Ltd.     

Tectono-metamorphic evolution of the Okcheon Metamorphic Belt, South Korea: Tectonic implications in East Asia

Abstract The tectonic history of the Okcheon Metamorphic Belt (OMB) is a key to understanding the tectonic relationship between South Korea, China and Japan. The petrochemistry of 150 psammitic rocks in the OMB indicates that the depositional environment progressively deepened towards the northwest. These data, combined with the distribution pattern of oxide minerals and the abundance of carbonaceous material, support a half‐graben basin model for the OMB. Biotite and muscovite K–Ar dates from metasediments in the central OMB range from 102 to 277 Ma. K–Ar ages of 142–194 Ma are widespread throughout the area, whereas the older ages of 216–277 Ma are restricted to the metasediments of the middle part of the central OMB. The younger (Cretaceous) ages are only found in metasediments that are situated near the Cretaceous granite intrusions. The 216–277 Ma dates from weakly deformed areas represent cooling ages of M1 intermediate pressure/temperature (P/T) metamorphism. The relationship between age distribution and deformation pattern indicates that the Jurassic muscovite and biotite dates can be interpreted as complete resetting ages, caused by thermal and deformational activities associated with Jurassic granite plutonism. Well‐defined ⁴⁰Ar/³⁹Ar plateau ages of 155–169 Ma for micas from both metasediments and granitic rocks can be correlated with the main Jurassic K–Ar mica ages (149–194 Ma). U–Pb zircon dates for biotite granite from the southwest OMB are 167–169 Ma. On the basis of the predominantly Jurassic igneous and metamorphic ages and the uniformity of d₀₀₂ values for carbonaceous materials in the study area, it is suggested that the OMB has undergone amphibolite facies M2 metamorphism after M1 metamorphism. This low P/T M2 regional thermal metamorphism may have been caused by the regional intrusion of Jurassic granites. The OMB may have undergone tectono‐metamorphic evolution as follows: (i) the OMB was initiated as an intraplate rift in the Neoproterozoic during break‐up of Rodinia, and may represent the extension of Huanan aulacogen within the South China block; (ii) sedimentation continued from the Neoproterozoic to the Ordovician, perhaps with several unconformities; (iii) M1 intermediate P/T metamorphism occurred during the Late Paleozoic due to compression caused by collision between the North and South China blocks in an area peripheral to the collision zone; and (iv) during the Early to Middle Jurassic, north‐westward subduction of the Farallon‐Izanagi Plate under the Asian Plate resulted in widespread intrusion of granites, which triggered M2 low P/T regional thermal metamorphism in the OMB. This event also formed the dextral Honam shear zone at the boundary between the OMB and Precambrian Yeongnam massif.     

Accounting seasonal nonstationarity in time series models for short-term ozone level forecast

Due to the nonlinear feature of a ozone process, regression based models such as the autoregressive models with an exogenous vector process (ARX) suffer from persistent diurnal behaviors in residuals that cause systematic over-predictions and under-predictions and fail to make accurate multi-step forecasts. In this article we present a simple class of the functional coefficient ARX (FARX) model which allows the regression coefficients to vary as a function of another variable. As a special case of the FARX model, we investigate the threshold ARX (TARX) model of Tong [Lecture notes in Statistics, Springer-Verlag, Berlin, 1983; Nonlinear time series: a dynamics system approach, Oxford University Press, Oxford, 1990] which separates the ARX model in terms of a variable called the threshold variable. In this study we use time of day as the threshold variable. The TARX model can be used directly for ozone forecasts; however, investigation of the estimated coefficients over the threshold regimes suggests polynomial coefficient functions in the FARX model. This provides a parsimonious model without deteriorating the forecast performance and successfully captures the diurnal nonstationarity in ozone data. A general linear F-test is used to test varying coefficients and the portmanteau tests, based on the autocorrelation and partial autocorrelation of fitted residuals, are used to test error autocorrelations. The proposed models were applied to a 2 year dataset of hourly ozone concentrations obtained in downtown Cincinnati, OH, USA. For the exogenous processes, outdoor temperature, wind speed, and wind direction were used. The results showed that both TARX and FARX models substantially improve one-day-ahead forecasts and remove the diurnal pattern in residuals for the cases considered.