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51.
This paper reports that vibrational spectroscopic analysis on hydrogen-bonding between acetone and water comprises both experimental Raman spectra and ab initio calculations on structures of various acetone/water complexes with changing water concentrations. The optimised geometries and wavenumbers of the neat acetone molecule and its complexes are calculated by using ab initio method at the MP2 level with 6-311+G(d,p) basis set. Changes in wavenumber position and linewidth (fullwidth at half maximum) have been explained for neat as well as binary mixtures with different mole fractions of the reference system, acetone, in terms of intermolecular hydrogen bonding. The combination of experimental Raman data with ab initio calculation leads to a better knowledge of the concentration dependent changes in the spectral features in terms of hydrogen bonding. 相似文献
52.
利用河南省区域地震台网的近震波形资料,采用近震时间域方法,反演2010年10月24日16点58分太康 MS 4.6地震的地震矩张量,结果显示,该地震为走滑型地震。结合震后灾害考察,认为太康地震发生在周口-太康断裂上。 相似文献
53.
54.
利用混合法构建三维数字岩心(英文) 总被引:9,自引:0,他引:9
在弹性波有三维数字岩心描述了岩石的微观孔隙结构。X射线CT扫描是获取三维数字岩心最准确和直接的方法,但实验成本高。本文结合沉积过程模拟和模拟退火算法,提出了重建三维数字岩心的混合法,基于岩石二维图像重建三维数字岩心。利用岩石颗粒沉积算法构建初始数字岩心,作为模拟退火算法的初始状态。运用模拟退火算法调整岩石颗粒和孔隙的相对位置,使三维数字岩心与岩心二维图像具有相似的自相关函数,从而建立三维数字岩心。与传统模拟退火算法相比,该方法计算时间明显减小。运用局部孔隙度理论定量比较了重建数字岩心和岩心X射线微CT图像,两种数字岩心具有相似的均质性和孔隙连通性。利用有限元方法和格子玻尔兹曼方法分别模拟了重建三维数字岩心的地层因素和渗透率,数值模拟结果与实验结果相符。相比传统模拟退火算法,混合法重建数字岩心的传导特性更接近真实岩心的传导特性。 相似文献
55.
Eun-Hee Koh Seung Hyun Lee Dugin Kaown Hee Sun Moon Eunhee Lee Kang-Kun Lee Bong-Rae Kang 《Environmental Earth Sciences》2017,76(4):176
Impacts of land use changes and groundwater management actions on groundwater quality were evaluated at the island scale with spatiotemporal trends of NO3-N and Cl concentrations in groundwater of Jeju Island, Korea. The temporal trends from 1993 to 2012 in the concentrations of NO3-N and Cl from more than 3900 wells were estimated using the Mann–Kendall trend test and Sen’s slope analysis and compared with the land use change trend for the period 1995–2009. The results indicate that the upward trends in NO3-N were associated with the expansion of agricultural lands, whereas Cl trends were considered to be affected by other factors in addition to the land use changes. In the mid-mountainous region, the deterioration in the groundwater quality by the both NO3-N and Cl was expected due to the continuous expansion of agricultural lands. In the lowland area, the NO3-N and Cl components showed different trends depending on the regions. In the eastern area, increasing trends in NO3-N were observed due to the development of new agricultural areas, while the Cl concentration was observed to decrease as a result of the regulation on groundwater extraction to reduce seawater intrusion. Our study highlights that a comprehensive interpretation of trends in NO3-N and Cl and land use changes for long-term periods can provide useful insights to prepare for suitable groundwater management plans in the whole island perspective. 相似文献
56.
Fu-yuan Wu Simon A. Wilde Guang-liang Zhang De-you Sun 《Journal of Asian Earth Sciences》2004,23(5):781
Northeastern (NE) China is a well-documented example of a collisional zone characterized by widespread post-orogenic granites and mafic–ultramafic complexes. Based on a study of the Hongqiling and Piaohechuan Cu–Ni sulfide-bearing mafic–ultramafic complexes in central Jilin province, we present geological, petrological, geochemical and geochronological data which indicates their post-orogenic origin.The Hongqiling complex comprises pyroxenite, olivine websterite, lherzolite, gabbro and leucogabbro. Zircon U–Pb SHRIMP analyses on a leucogabbro of the Hongqiling complex yield a weighted mean 206Pb–238U age of 216±5 Ma. The Piaohechuan complex is composed of gabbro, pyroxenite and dolerite, exposed as dikes. A plagioclase-bearing pyroxenite has a U–Pb zircon weighted mean 206Pb–238U age of 217±3 Ma, identical to that of the Hongqiling complex. These ages are coeval with the emplacement of A-type granites in the area, but slightly younger than the regional metamorphism (240 Ma) and syn-orogenic granitic magmatism (246±4 Ma). This suggests that these mafic–ultramafic complexes are post-orogenic in origin. The age data also indicated a short period of lithospheric stabilization of about 30 Ma after cessation of orogenic activity.Geochemical investigation indicates that the primary mafic magma was a lithospheric mantle-derived basalt resulting from the upwelling of asthenosphere due to lithospheric delamination during post-orogenic processes. The magmatic source was contaminated by a small amount of crustal material, and subsequent crystal fractionation resulted in the Cu–Ni mineralization.The widespread occurrence of mafic–ultramafic complexes in the Xing'an–Mongolian Orogenic Belt of NE China and in the Altay–Tianshan–Junggar Orogenic Belt of Northern Xinjiang indicates that mafic intrusions are an important magmatic suite that evolved during post-orogenic processes. Portions of this mafic magma could have underplated the lower crust, and served as the heat source for associated late-stage granitic magmas. 相似文献
57.
The surface accuracy of a large parabolic antenna is an important indicator to evaluate the quality of the antenna.It not only directly affects the antenna’s aperture efficiency,thereby determining the shortest wavelength that the antenna can work,but also affects the main lobe width and side lobe structure of the antenna pattern.Microwave holography is an important method for parabolic antenna profile detection.In this article we adopt a new algorithm to adjust the panels for the large radio telescope with an active main reflector through the TM65 m antenna’s aperture phase profile.The panels of the TM65 m radio telescope is in a radial pattern with 14 rings.Each corner of the panel is fixed on the screw of the actuator to move up and down,and the adjacent corners of the four panels share an actuator.We use the method of plane fitting to calculate the adjustment value of every panel’s corner.But one actuator,which simultaneously controls the common corner of the adjacent panels,will have different adjustment values according to the different plane fitting equation based on adjacent panels.In this paper,the adjustment value of the adjacent panels’crosspoints are constrained to be equal to the constraint condition to calculate each actuator’s adjustment value of the TM65 m radio telescope.Through multiple adjustments and application of the new algorithms,the accuracy of the TM65 m antenna reflector profile has been improved from the original 0.28 mm to the current 0.19 mm. 相似文献
58.
对取自桑沟湾北西南三根柱样近200 a碳来源及埋藏通量的解析,分析了湾内不同站位各形态碳的差异性,进而对全湾碳埋藏进行了估算。湾内环流、贝藻养殖等造成湾内不同区域碳埋藏的差异;桑沟湾总碳(TC)平均量1.79%,有机碳(TOC)平均量0.54%,无机碳(TIC)平均量1.25%,TOC含量相对较小,为海陆混合来源,以陆源有机碳(Ct)为主,大规模人工养殖后,海源有机碳(Ca)有明显增加的趋势。桑沟湾碳埋藏通量平均为228.9 g/(m2·a),以无机碳为主要埋藏形式(约占70%),高的沉积速率及生物残骸沉降使桑沟湾养殖区碳的来源及埋藏区别于其他陆架海域。 相似文献
59.
辽宁省“十五”数字化地磁数据分析系统 总被引:1,自引:0,他引:1
依据台站“十五”数字化地磁工作需求,结合地磁学科组运行管理的相关技术要求,研发辽宁省“十五”数字化地磁数据分析系统.该软件采用IDL作为开发语言,Oracle 10g数据库管理数据,主要包含用户管理模块、日志管理模块和数据管理模块3部分,具备数据实时处理、快速成像、操作简便、安全稳定等特点,可以有效解决目前台站地磁数据... 相似文献
60.
WANGHai-xia WANZhong-juan YUShao-peng LUOXin-zheng SUNGuang-you 《中国地理科学(英文版)》2004,14(2):179-185
Although the Songnen Plain in the northeastern China was developed relatively late in the temperate zone of the world, its eco-environment has changed greatly. This paper analyzes the changes of land cover and the rates and trends ofdesertification during the past 100 years in the Songnen Plain. According to the macroscopic analysis, we find that the eco-environment in the plain has reached to the threshold of catastrophic change since the 1950s. The Thorn Needle Catastrophic Model was used to determine and validate this conclusion. Human activities, including large-scale construction projects, such as huge dams and dikes, and excessive grazing were the primary factors contributing to regional eco-environmental catastrophe. And irrational reclamation of the wilderness also affected the eco-environmental change. The results reveal the complex human-land interactions. 相似文献