南极企鹅粪土沉积柱样、蛋卵中OCPs、PCBs含量分布及其环境意义

对南极阿德雷岛企鹅栖息地粪土层进行210Pb测年,同时采用气相色谱-电子捕获检测器(GC-ECD)内标定量法测定了企鹅栖息地粪土混合地层和企鹅蛋卵中有机氯污染物含量,粪土混合地层中有机氯污染物最高浓度:表层PCBs为0.92ng/g,HCHs为0.42ng/g,DDTs在0.70ng/g,与非栖息地相比较,研究结果显示,通过鸟类活动的粪土混合地层(营巢和粪便)输入PCBs和OCPs含量比无鸟类生命途径的土壤相对要高。企鹅蛋卵样∑PCB在0.4-10.2ng/g,∑DDT2.4-10.3ng/g,HCB0.1-9.4ng/g,∑HCH0.1-0.5ng/g,总积蓄水平依次为:∑PCB>∑DDT>HCB>∑HCH。     

东河砂岩钙结成岩作用的主要特征

石炭系底部的东河砂岩是一套优质储集层和富油层,也是塔里木盆地的主要产油层.本文从砂岩的成岩作用入手,通过对哈得4油田钙质胶结物作用的细致研究,识别出3期同生钙结成岩作用和4期表生钙结成岩作用,并总结了淡水方解石的矿物特征.结合东河砂岩的时空展布特征,确认了东河砂岩在沉积-成岩过程中遭受过抬升剥蚀,目前哈得4油田不足30 m的东河砂岩应为残余厚度.     

黔南桂中二叠系Cisuralian统和Guadalupian统层序地层及其与牙形石演化的关系

通过对黔南罗甸纳水剖面和桂中来宾铁桥剖面２个斜坡相剖面详细的层序地层研究,将华南二叠系Ｃｉｓｕｒａｌｉａｎ统和Ｇｕａｄａｌｕｐｉａｎ统划分为１个二级层序,即阳新层序,及其９个三级层序,并建立了相应的海平面变化曲线．结合原有和最新的生物地层资料,将这２个剖面的层序地层实现了精确划分对比,从而将原有地层对比精度提高了一倍．阐明了层序与海侵海退旋回的区别与联系．将二叠纪牙形石演化划分为５个阶段、４个演替事件,并阐明了它们与层序地层及海平面变化事件之间的相互关系．同时,提出了二叠纪牙形石分带及其全球对比表．发现栖霞亚统的氧碳同位素在下部偏轻、上部偏重,具全球对比意义     

Chronology and Geochemistry of Volcanic Rocks in the Cretaceous Suifenhe Formation in Eastern Heilongjiang, China

Zircon U-Pb ages and geochemical data of volcanic rocks in the Suifenhe Formation in eastern Heilongjiang Province are reported, and their petrogenesis is discussed in this paper. The Suifenhe Formation mainly consists of basalt, andesite, and dacite. Zircon from andesite and dacite are euhedral in shape and show typical oscillatory zoning with high Th/U ratios (0.18-0.57), implying its magmatic origin. Zircon U-Pb dating results by laser ablation inductively coupled plasma mass spectrometer (LA-ICP-MS) indicate that the 206Pb/238U ages of zircons from andesite range within 105-106 Ma, yielding a weighted mean age of 105.5±0.8 Ma (n=14), and that 206Pb/238U ages of zircons from dacite are between 90-96 Ma, yielding a weighted mean age of 93.2±1.3 Ma (n =13). The volcanic rocks from the Suifenhe Formation are subalkaline series and show a calc-alkaline evolutionary trend with SiO2 content of 47.69%-65.47%, MgO contents of 1.42%-6.80% (Mg#= 45-53), and Na2O/K2O ratios of 1.83-3.63. They are characterized by enrichment in large ion lithophile elements (LILE) and light-rare-earth elements (LREE), depletion in heavy rare earth elements (HREE) and high field strength elements (HFSE) (e.g., Nb, Ta, Ti), and low initial 87Sr/86Sr ratios (0.7041-0.7057) and positiveεNd(t) values (039-4.08), implying that they could be derived from a depleted magma source. Taken together, these results suggest that the primary magma of the volcanic rocks might originate from partial melting of the mantle wedge metasomatized by fluids derived from subducted slab under a tectonic setting of active continental margin.     

Guadalupian （Middle Permian） Conodont Faunas at Shangsi Section, Northeast Sichuan Province

This study recovered the Guadalupian conodont faunas from Shangsi (上寺) Section in Northeast Sichuan (四川). Four genera and nine species were identified, and three conodont zones were recognized and established; they include Jinogondolella nankingensis Zone, J. aserrata Zone, and J. postserrata Zone. The Roadian and Wordian boundary is set in the interval 5 m from the top of Bed 86 by the first appearance of the conodont J. aserrata. The Wordian and Capitanian boundary is set in the interval 2.3 m from the top of the Bed 95 by the first appearance of J. postserrata. Most of the specimens demonstrated low color alteration index (CAI) as 1.5-3, indicating that most part of the Maokou (茅口) Formation may have the suitable thermal conditions for the formation of oil source rocks.     

滇西北金沙江带蛇绿岩,蛇绿混杂岩形成环境及时代

本文对滇西北金沙江带蛇绿岩及其混杂岩的产状、规模，岩石学及岩石化学特征等进行系统的综合研究，并根据大量的化石资料，将该区蛇绿岩的形成时代厘定为晚石炭世至二叠纪，蛇绿要岩的形成时代厘定为早、中三叠世，论证了本区蛇绿岩产于规模较小的洋盆环境之中，由于金沙江洋盆发育阶段较短暂，不具有隔离冈瓦纳及扬子两大古生物地理区系的作用，因此，金沙江缝合带不能构成古特提斯域的主缝合带。     

鄂尔多斯盆地中央古隆起的地质结构与成因机制

克拉通盆地内古隆起是了解板内变形机制的重要窗口,也是油气、煤、盐、铀等矿产勘查的主要对象,一直是盆地分析的热点领域。本文以鄂尔多斯盆地中央古隆起为例,利用新的高精度反射地震剖面与深探井资料,解剖古隆起的地质结构,刻画构造演化过程,探讨其形成机制。研究表明,鄂尔多斯盆地古生代隆起带发育在华北克拉通地块中西部,自伊盟—杭锦旗、乌审旗—定边,南延至镇原—正宁一带,呈“工”字形,面积达7.5×104 km2以上;伊盟凸起为基底隆起,镇原隆起为多阶段、间隙性发育的剥蚀与沉积型隆起,定边凸起为沉积型隆起。它是基底分异构造格局与周缘板块构造事件共同控制的产物,为在中元古代裂陷基础上早古生代被动大陆边缘背景下发育演化的古隆起;古生代早期,邻接周缘洋盆表现为台缘隆起;石炭纪晚期—二叠纪早期,因差异升降而具陆缘隆起性质;印支晚期—燕山期以来,隐伏于天环坳陷之下埋藏沉没。鄂尔多斯盆地中央隆起带为多机制复合成因,伊盟凸起为基底强烈伸展、长期剥露剥蚀型隆起;镇原凸起为西缘断阶迁移、南缘前缘隆起叠加的复合隆起;定边凸起为断阶迁移、挤压叠加的继承性隆起。鄂尔多斯盆地中央隆起带对盆地内部的构造—沉积分异施加了重要影响,其两翼斜坡带是油气聚集的有利区带。     

Synthesis and characterisation of a multifunctional oil-based drilling fluid additive

An oil-based drilling fluid additive H-DEA (or humic acid-cocamide diethanolamine) was synthesised using humic acid and cocamide diethanolamine as raw materials. The rheological behaviors of H-DEA showed that the synthesised product has the good properties in both decreasing the filtrate loss and improving rheology property of oil-based drilling fluids compared with other commercially available additives. Under the optimal additive amount of 3%, both API filtrate loss and yield point changed remarkably from 5.40 to 0.41 mL and 9.0 to 25.6 Pa, respectively. Furthermore, differential scanning calorimetry (DSC) showed that H-DEA has good thermal stability in a wide temperature range up to 170 °C. Infrared spectroscopy (IR) and rheological analysis revealed that the possible mechanism of the multifunctional effects may be attributed to the existing of high density of strong polar groups, hydrogen bonds, electrostatic forces, and intermolecular association on H-DEA molecular structure. The results of the study showed that the synthesised H-DEA can be potentially used as a multifunctional oil-based drilling fluid additive in oil-drilling excavation.     

考虑渗透率变化的煤层气储层数值模拟及参数敏感性研究

煤层气开采过程中储层渗透率的变化对产气量影响较大,通过引入S＆D渗透率变化模型,建立了考虑渗透率变化的煤储层三维气水两相渗流数学模型,完成模型检验后应用所编制软件研究了煤储层参数、吸附参数及渗透率模型特征参数对开发效果的影响。结果表明,煤层气产量随着初始含气量、煤层有效厚度、裂缝渗透率和Langmuir压力的增大而增大,随储层原始压力、裂缝孔隙度和Langmuir体积的增大而减小,而解吸时间对产气量影响不大;裂缝渗透率随着杨氏模量和基质收缩/膨胀系数的增大而增大,随泊松比和裂缝压缩系数的增大而减小。引入S＆D模型后计算的累积产气量要比常规模型低1.3%,因此不可忽视煤层气产出过程中渗透率的变化。     

胶州湾海域水质预测

在已建潮流模型的基础上,用ADI法建立了胶州湾扩大域变动边界的平流—扩散输运模型,以COD为指示因子,预测了胶州湾海域1995年、2000年的水质、青岛环海公路海上段、沧口区北半部污水截流、北水南调、集中排放以及胶州湾西部经济开发对海域水质的影响等。为青岛市环保部门制定环保规划提供决策依据。