地基微波辐射计探测在黄河上游人工增雨中的应用

利用2003、2004年夏秋季在青海省河南县的地基双频段微波辐射计连续观测资料,在实施系统探测实验以进行辐射亮温值(TB(23.87),TB(31.65))与大气汽态总水汽含量(Q)和云中积分液态水含量(L)值反演处理的基础上,分析了黄河上游河曲地区的云水特征,并进行了降水预测及人工增雨作业指标的探讨。结果表明:在黄河上游河曲地区,7—9月纯晴天无云天气条件下,L值基本为0,表明了统计回归反演的显著性。多云条件下Q值和L值分别在3.76~4.75g·cm-2、227.34~859.42g·m-2的范围内。可降水云天气,Q值在5.23~8.65g·cm-2间,L值在421.18~1016.37g·m-2的范围内;积雨云个例分析表明,在降雨开始前近5小时的降雨酝酿期内,Q及L的增加有明显的波动,但在对流云出现并发展时,Q和L总是急剧上升,在降雨前达到一峰值;由河南站和西安站的Q、L值比较差异可以看出,Q、L值受水汽输送、地形等因素的影响,黄河上游河曲地区的人工增雨潜力有显著的优势;所计算出的降水预测阈值,可作为该地区人工增雨作业指标的参考。     

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金矿床的热液流体特征研究

通过对中国东部金成矿区域地质特征的分析,根据氢氧同位素及流体包裹体数据特征,表明中国东部金矿床成矿流体主要来自大气降水,其次为变质作用过程释放的水和岩浆分异水;成矿金属组分主要来自太古宙变质岩系。     

The apparent copper complexing capacity of seawater and the interaction of copper with humic matter

The anodic stripping voltammetry with physically-coating mercury film electrode was used to investigate the complexing action of trace heavy metals in seawater with organic ligands. The apparent copper complexing capacity of seawater was determined by titrating the organic ligands in natural seawater with standard ionic copper solution. The complexing actions of copper in seawater with humic acid (HA) or fulvic acid (FA) were investigated by titrating copper in seawater with HA or FA solution. The equilibrium time, electrodeposition potential, and effect of pH etc. were investigated respectively. The results show that the interaction of copper in seawater with organic matter is a fast process. At natural pH, HA or FA tend to act with copper in seawater to form nonlabile complexes. During experimental electrode process, these complexes did not significantly dissociate. The experimental results were calculated according to 1∶1 complex formation.     

Application of stable isotope techniques in studies of carbon and nitrogen biogeochemical cycles of ecosystem

Stable isotope techniques have been proved useful as tools for studying the carbon (C) and nitrogen (N) biogeochemical cycles of ecosystem. This paper firstly introduced the basic principles and the distribution characteristics of stable isotope, then reviewed the recent advances and applications of stable isotope in the C and N biogeochemical cycles of ecosystem. By applying the 13 C natural abundance technique, ecologists are able to understand the photosynthetic path and CO 2 fixation of plants, the CO 2 exchange and C balance status of ecosystem, the composition, distribution and turnover of soil organic C and the sources of organic matter in food webs, while by using the 13 C labeled technique, the effects of elevated CO 2 on the C processes of ecosystem and the sources and fate of organic matter in ecosystem can be revealed in detail. Differently, by applying the 15 N natural abundance technique, ecologists are able to analyze the biological N 2 -fixation, the N sources of ecosystem, the N transformation processes of ecosystem and the N trophic status in food webs, while by using the 15 N labeled technique, the sources, transformation and fate of N in ecosystem and the effects of N input on the ecosystem can be investigated in depth. The applications of both C and N isotope natural abundance and labeled techniques, combined with the elemental, other isotope ( 34 S) and molecular biomarker information, will be more propitious to the investigation of C and N cycle mechanisms. Finally, this paper concluded the problems existed in current researches, and put forward the perspective of stable isotope techniques in the studies on C and N biogeochemical cycles of ecosystem in the future.     

Corrosion behavior of anodic oxidized TiO<Subscript>2</Subscript> film in seawater

TiO₂ films were formed on metallic titanium substrates by the anodic oxidation method in H₂SO₄ solution under the 80V D.C.. Phase component and microstructure were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). Water contact angles on titanium oxide film surface were measured under both dark and sunlight illumination conditions. Corrosion tests were carried out in seawater under different illumination conditions by electrochemistry impedance spectrum (EIS) and polarization curves. The result showed that the TiO₂ film prepared by the anodic oxidation method was anatase with a uniform structure and without obvious pores or cracks on its surface. The average water contact angle of the film was 116.4° in dark, in contrast to an angle of 42.7° under the UV illumination for 2 hours, which demonstrates good hydrophobic property. The anti-corrosion behavior of the TiO₂ film was declining with the extended immersion time. Under dark conditions, however, the hydrophobic TiO₂ film retarded the water infiltrating into the substrate. The impedance changed slowly and the corrosion current density was 2 orders of magnitude lower than that with the film illuminated by sunlight. All of those mentioned above indicate that the TiO₂ film possesses much better performance under dark condition, and it can be applied as an engineering material under dark seawater environment.     

GPS揭示的现今地壳运动与地震前兆特征

利用“中国地壳运动观测网络”产出的GPS观测资料,采用球坐标系下非连续变形算法对资源进行计算,以此为基础,对我国大陆地块及其边界带运动与形变进行了分析。对GPS基准站的连续观测序列采用小波变换进行分解变换,分析了部分震例,探讨了从GPS连续观测序列提取地震前兆的方法。初步取得两点认识：（1）7级以上的大地震主要发生在走滑运动量大的活动边界,且与高应变率地块有关,这可以作为地震中长期预测判据;（2）GPS基准站连续观测序列中的低频段,地震前6个月或稍长时段有一定的前兆异常出现,这可以作为地震中短期预测判据。     

利用自回归模型检测地球极移重力效应

同时采用4个台站的国际超导重力仪长期连续重力观测资料和国际地球自转服务中心提供的同步地球自转参数，研究了极移引起的地球重力场变化特征。利用自回归模型估计了各序列的功率谱密度和积谱密度，结果表明极移导致的重力效应的主要能量集中在Chandler摆动和周年项附近，叠积后实际重力观测与极移重力信号理论值之间的差异分别为0．4％和3．9％，说明超导重力仪可有效监测极移导致的重力变化。     

From sequential to parallel growth of cities: Theory and evidence from Canada

This paper examines city growth patterns and the corresponding city size distribution evolution over long periods of time using a simple New Economic Geography(NEG) model and urban population data from Canada. The main findings are twofold. First, there is a transition from sequential to parallel growth of cities over long periods of time: city growth shows a sequential mode in the stage of rapid urbanization, i.e., the cities with the best development conditions will take the lead in growth, after which the cities with higher ranks will become the fastest-growing cities; in the late stage of urbanization, city growth converges according to Gibrat′s law, and exhibits a parallel growth pattern. Second, city size distribution is found to have persistent structural characteristics: the city system is self-organized into multiple discrete size groups; city growth shows club convergence characteristics, and the cities with similar development conditions eventually converge to a similar size. The results will not only enhance our understanding of urbanization process, but will also provide a timely and clear policy reference for promoting the healthy urbanization of developing countries.