利用催化动力学原理测定化探样中微量碘的含量

在HAc-NaAc形成的中性缓冲溶液体系中,利用碘的催化动力学原理,使N-N-四甲基-4-4-二氨基二苯甲烷与氯胺T的氧化反应,生成蓝色络合物来测定地探样中微量碘的含量。通过实验,最佳试剂加入量为8%的HAc溶液5mL,8%的Na2CO3溶液3mL,0.1%的N-N-四甲基-4-4-二氨基二苯甲烷溶液5mL所组成的溶液体系中,在加入0.1%的氯胺T1mL显色后,其测定结果准确度、精密度高,检出限低,测定化探样中微量碘时该方法可以推广应用。     

采用DBM方法的时间序列LAI建模与估算

运用DBM(Data Based Mechanistic)方法,使用MODIS数据,建立了遥感观测反射率数据与叶面积指数(LAI)在时间序列上的统计关系模型(LAI_DBM模型),并结合部分Bigfoot站点实测LAI数据进行了模型检验。结果显示,LAI_DBM模型能够较好表达时间序列反射率与LAI的动态变化关系。LAI_DBM模型使用遥感观测数据实时估算得到的LAI,在数据质量和时间连续性上比MODISLAI有改进。     

“7.15”宜昌大暴雨的地形影响特征

湖北地形复杂,受地形影响产生的局地强降水造成的灾害很多。2010年7月15日宜昌地区的强降水是在满足大尺度降水条件下受地形作用加强的局地暴雨。本文利用实况高空、地面、加密自动站、雷达以及LAPS再分析资料对背景场、低层流场、雷达回波等几个方面进行了分析。得出：冷空气南下和副热带高压的加强促进低层风场的调整,在大尺度降水条件下,地形对低层风场的辐合作用触发了局地强降水的发生。此次过程中地形对降水的触发主要有两方面的作用：一方面为地形迎风坡抬升触发作用,另一方面为地形对近地层流场的影响造成的辐合触发。     

近百年来湖泊有机碳与无机碳埋藏响应流域开发的协同变化——以石林喀斯特地区为例

有机碳和无机碳的流域输出是湖泊碳埋藏的重要驱动因子,而喀斯特地区无机碳循环具有反应迅速且对人类活动影响敏感的特点.在流域开发持续增强的背景下,喀斯特地区湖泊有机碳和无机碳的来源、含量与埋藏通量可能会出现同步变化的协同模式.本文以云南省石林喀斯特地区流域土地利用类型不同的两个中型湖泊(长湖、月湖)开展对比分析,通过对沉积物钻孔的土壤侵蚀强度(磁化率)、流域外源输入(C:N比值)、水动力(粒度)、营养盐(总氮、总磷)、藻类生产力(叶绿素色素)等代用指标的分析,结合监测数据和历史资料重建了两个湖泊环境变化的近百年历史,并定量识别了有机碳和无机碳埋藏响应流域开发的变化特征与协同模式.沉积物磁化率和C:N比值结果揭示了流域地表侵蚀和外源输入的阶段性特征,同时总氮和总磷含量记录了长湖和月湖营养水平上升的长期模式.在流域森林覆被较高(33.43%)的长湖中,全岩和有机质C:N比值分别与磁化率信号呈显著正相关(r=0.95和0.89,P<0.001),且与无机碳和有机碳含量呈显著负相关(r=-0.94,P<0.001和r=-0.52,P=0.01),反映了森林植被退化时流域碳输出的减少对沉...     

砂岩中的凝灰质填隙物分异特征及其对油气储集空间影响--以鄂尔多斯盆地西北部二叠系为例

运用铸体薄片、扫描电镜、能谱分析及溶蚀实验等多种测试手段对鄂尔多斯盆地西北部二叠系砂岩填隙物进行了成份和成岩演化分析,认为砂岩中的填隙物主要为凝灰质填隙物,而不是普通意义上的粘土矿物。在有残余粒间孔隙或裂缝沟通的较开放性水环境里,凝灰质填隙物蚀变程度强,Si、Al、K、Na及Ca等离子因活性不同而发生分异,蚀变为“脏”高岭石及硅质团块等产物;封闭环境下,凝灰质填隙物保存完好,偏光显微镜下显示出似非晶态波状消光,活性强的K、Na元素含量仍然很高。凝灰质填隙物分异过程中,可以产生一定数量的溶蚀孔隙及晶间孔隙,砂岩储集性能得到了明显改善。对声波时差异常带砂岩进行大量的铸体薄片观察,证实了本区砂岩粒间溶蚀孔隙发育,凝灰质填隙物发生了强烈溶蚀。综合分析26口井的资料,发现垂向上凝灰质填隙物溶蚀强度呈箱型展布,箱内“脏”高岭石及溶蚀孔隙发育,箱顶部凝灰质填隙物含量高,保存好,并缺少“脏”高岭石团块出现。     

辉钼矿Re-Os同位素定年方法的改进与应用

公认的Re-Os同位素定年代表物辉钼矿,目前已在金属硫化物矿床年代学研究领域获得了广泛的应用。本研究采用浓HNO₃分解辉钼矿样品,大大地简化了Re和Os的化学制备过程,并根据辉钼矿中正常Os含量水平相对放射成因¹⁸⁷Os可以忽略的特点,以正常Os标准为稀释剂,实现了仪器测量过程中Os同位素质量分馏的在线校正,改善了分析数据的质量。该方法经辉钼矿国家标准物质进行验证,获得了满意的Re、Os含量及Re-Os年龄数据,并且在南岭地区与连阳复式岩体相关的姓坪夕卡岩型钼矿床成矿年龄研究中获得了成功应用。在实际应用中,为了获得有意义的能反映真实地质事件的年龄数据,辉钼矿样品不仅要有足够的取样量,而且还要保证粒度细、混合均匀。     

中国区域地壳稳定性定量化评价与分区

中国地处环太平洋构造带与地中海构造带交接部位,地质构造复杂,活动性较为强烈,各种内动力地质灾害比较严重,总体看来中国区域地壳稳定性相对较差。为了使区域地壳稳定性评价与分区获得定量化认识,更好地服务于经济建设和减灾防灾,本文在分析中国现今活动的主要构造体系与内动力地质灾害的分布规律的基础上,首先进行区域地壳稳定性定量化评价待评区的划分;其次进行定量化评价指标的选定、取值、权重分配及评价标准的确定;最后运用模糊数学进行中国区域地壳稳定性定量化评价与分区。      

柴达木盆地西部地区咸化湖盆天然气地球化学特征及成因类型判识指标——以古近系—新近系为例

根据天然气地球化学基本理论,对柴达木盆地西部（柴西）地区天然气的地球化学特征进行分析。测试和收集该地区18个油气田及含油气构造的83个天然气样品,分析其组分和C同位素数据,结果显示,该区天然气以烃类气体为主,烃类含量介于79.24%~99.81%之间,天然气比重介于0.72~1.36之间,天然气干燥系数（C1/C2+）介于1.04~617.8之间,甲烷C同位素值介于-51.4‰~-24.2‰之间,乙烷C同位素值介于-34.2‰~-17.4‰之间。在此基础上,对该区不同构造带的天然气成因类型进行研究。研究结果表明,柴达木盆地西部地区天然气类型可划分为腐泥型气、腐殖型气、混合气3类,柴西北部天然气主要为腐泥型气和混合气,少量腐殖型气;柴西南部主要为腐泥型气,少量混合气。同时,建立了天然气成因类型的判识指标,对该区的天然气地球化学特征有了较为深入的认识,对今后的天然气勘探具有指导意义。     

Longitudinal Displacement of the Subtropical High in the Western Pacific in Summer and its Influence

Using the relative vorticity averaged over a certain area, a new index for measuring the longitudinal position of the subtropical high (SH) in the western Pacific is proposed to avoid the increasing trend of heights in the previous indices based on geopotential height. The years of extreme westward and eastward extension of SH using the new index are in good agreement with those defined by height index. There exists a distinct difference in large-scale circulation between the eastward and westward extension of SH under the new definition, which includes not only the circulation in the middle latitudes but also the flow in the lower latitudes. It seems that when the SH extends far to the east (west), the summer monsoon in the South China Sea is stronger (weaker) and established earlier (later). In addition, there exists a good relationship between the longitudinal position of SH and the summer rainfall in China. A remarkable negative correlation area appears in the Changjiang River valley, indicating that when the SH extends westward (eastward), the precipitation in that region increases (decreases). A positive correlation region is found in South China, showing the decrease of rainfall when the SH extends westward. On the other hand, the rainfall is heavier when the SH retreats eastward. However, the anomalous longitudinal position of SH is not significantly related to the precipitation in North China. The calculation of correlation coefficients between the index of longitudinal position of SH and surface temperature in China shows that a large area of positive values, higher than 0.6 in the center, covers the whole of North China, even extending eastward to the Korean Peninsula and Japan Islands when using NCEP/NCAR reanalysis data to do the correlation calculation. This means that when the longitudinal position of the SH withdraws eastward in summer, the temperature over North China is higher. On the other hand, when it moves westward, the temperature there is lower. This could explain the phenomenon of the seriously high temperatures over North China during recent summers, because the longitudinal position of SH in recent summers was located far away from the Asian continent. Another region with large negative correlation coefficients is found in South China.     

Land surface temperature shaped by urban fractions in megacity region

The influence of spatial scales on surface fluxes is an interesting but not fully investigated question. This paper presents an analysis on the influence of spatial scales on surface fluxes in the north Tibetan Plateau based on eddy covariance (EC) and large aperture scintillometer (LAS) data at site Nagqu/BJ, combined with the land surface temperature (LST) and normalized difference vegetation index (NDVI) of moderate-resolution imaging spectroradiometer (MODIS). The analysis shows that sensible heat fluxes calculated with LAS data (H_LAS) agree reasonably well with sensible heat fluxes calculated with EC data (H_EC) in the rain and dry seasons. The difference in their footprints due to the wind direction is an important reason for the differences in H_EC and H_LAS. The H_LAS are statistically more consistent with H_EC when their footprints overlap than when their footprints do not. A detailed analysis on H_EC and H_LAS changes with net radiation and wind direction in rain and dry season indicates that the spatial heterogeneity in net radiation created by clouds contributes greatly to the differences in H_EC and H_LAS in short-term variations. A significant relationship between the difference in footprint-weighted averages of LST and difference in H_EC and H_LAS suggests that the spatial heterogeneity in LST at two spatial scales is a reason for the differences in H_EC and H_LAS and that LST has a positive correlation with the differences in H_EC and H_LAS. A significant relationship between the footprint-weighted averages of NDVI and the ratio of sensible heat fluxes at two spatial scales to net radiation (H/Rn) in the rain season supports the analysis that the spatial heterogeneity in canopy at two spatial scales is another reason for differences in H_EC and H_LAS and that canopy has a negative correlation with (H/Rn). An analysis on the influence of the difference in aerodynamic roughness lengths at two spatial scales on sensible heat fluxes shows that the influence is greater in the dry season and smaller in the rain season because the ratio of z_{0m_LAS} to z_{0m_EC} is big in the dry season and is close to 1.0 in the rain season. This study on spatial scales on surface fluxes in the Tibetan Plateau will be helpful in analyzing and understanding its influence on climate.