安徽大别山北部红刚玉岩石的成因

大别山北部红刚玉矿产在太古代大别山群黑云角门外长片麻岩以及超基性岩中。赋存红刚玉的刚玉黑云二长片麻岩的原始岩石为富铝泥质岩,在角门岩相变质条件下,通过两种脱硅方式,即变质分异作用和超基性岩侵位,形成刚玉黑云二长片麻岩。它们形成的温压条件：Ｔ＝５００℃～７００℃,Ｐ＝０．４～０．７ＧＰａ。刚玉形成的可能的化学机制是白云母在缺硅条件下的分解。     

浙江省东部土壤元素地球化学特征及意义

为了研究土壤和稻米元素地球化学分布特征及影响稻米中重金属质量分数的主要因素,对浙江省东部农田根系土-稻谷样品进行了采集和分析。结果表明：各研究区均有重金属元素质量分数高于区域地球化学背景值,尤其是温州南郊地区的Hg、台州泽国地区Cd、绍兴北郊地区的Hg,其质量分数分别是背景值的6倍、5倍及9倍;7个研究区中,只有嘉兴新胜地区的As质量分数超过背景值。其原因是这些地区工业化进程迅速,人为活动频繁,污染较严重。绍兴北郊、嘉兴新丰、嘉兴新胜和桐乡崇福地区稻米中As、Cd、Cr、Hg、Se和Pb质量分数均未超过标准限值。稻米对重金属元素的吸收富集主要受土壤有机质、pH、土壤阳离子交换量和黏粒组成等土壤理化性质的影响：土壤有机碳越丰富越有利于稻米对As、Cd、Cr和Ni的吸收;稻米对As、Cd、Mn和Ni的富集系数随着pH上升而下降;土壤阳离子交换量和黏粒组成与水稻As、Cu、Hg、Mn、Pb、Se和Zn的富集系数呈显著负相关。     

汶川地震映秀-北川地表破裂带虹口乡段精细填图、位移特征和地震构造分析

同震地表破裂带是地震破裂最直观的表现。地表破裂带的精细填图对理解地震破裂过程及发震机理有着重要意义。我们对5.12汶川地震映秀-北川同震破裂带南部的虹口乡区段开展了较为精细的填图工作,该区段地表破裂带的平面几何和同震位移特征沿走向均显示出公里尺度的横向变化和复杂性。根据同震破裂不连续性特征可把地表破裂分为4段,自南向北依次为深溪沟段、庙坝段、高原新村段和八角庙段。其中,深溪沟段和八角庙段同震垂直位错较大,达.5～6m;庙坝段同震垂直位移量普遍较低,1～2m或更低;  在高原新村附近,地表破裂带分为近平行的南北两支,北支以右旋走滑为主,南支以南东盘逆冲抬升为主,这与与映秀-北川同震破裂总体北西盘抬升的性质相反。本文对高原新村附近的反向陡坎进行了深入的探讨,并综合前人的研究结果,认为是破裂在从深部往上扩展的过程中,在浅表部位顺着发育在虹口东南部的大鱼洞-龙溪飞来峰后缘的具南东倾向的断面继承而成。与北川沙坝附近的反向陡坎一样,说明老断裂带构造几何特征对单次地震破裂的扩展有牵引作用。最后,讨论了八角庙有切割关系的两组断层擦痕的地震学和地质学意义,指出可能指示了映秀-北川断裂面上局部区段震前的初始应力水平较低。     

Correction of common lead in U-Pb analyses that do not report 204 Pb

During the Early-Middle Proterozoic era, three major lithostratigraphic unit associations, namely Hekou-Dahongshan, Dongchuan, and Kunyang-Huili Groups, were established for the metamorphosed volcanic-sedimentary rocks exposed in the southwestern Yangtze Block (SWYB). The integration of petrology, geochemistry and geochronology constrains tectonic framework and evolution of the SWYB, in which four sets of SHRIMP U-Pb zircon ages were obtained from the volcanic rocks interbedded within the Middle Proterozoic successions: 1800–1600 Ma, 1600–1300 Ma, 1300–1100 Ma, and 1100–1000 Ma. Major and trace elemental analysis indicate that four key tectonic evolutionary stages, each coinciding with the above radiometric age set, of the SWYB during the Early-Middle Mesoproterozoic. The SWYB was characterized by an east-westerly trending rift in the Hekou, Dongshan, and Dongchuan areas, and separate basin-forming events during 1800–1600 Ma and 1600–1300 Ma, respectively. In the SWYB, an intracontinental rift basin and a rift basin occurred in the Caiziyuan-Matang and Laowushan areas, respectively in 1300–1100 Ma ago. During 1100–1000 Ma, the SWYB was characterized by the closure of the Caiziyuan-Matang rift-ocean basin, collision between the Huili Blocks and Kunyang Blocks, and presence of volcanic arcs in the Tianbaoshan and Fulingpen areas. Accordingly, the SWYB represents a new basin that records the relatively complete assembly process of the Rodina during the Early-Middle Mesoproterozoic era.     

汶川地震(Ms8.0）地表建筑体变形特征及其构造意义

通过汶川地震震区大量的实地考察已证实沿着早先活动断裂主要发育了两条地表破裂带：一条是沿着映秀－北川断裂产生的逆冲伴随右旋走滑破裂带,长275km,最大垂直位移达11m,水平位移达12m; 另一条纯逆冲性质的破裂带,沿着灌县－安县断裂发育,最大垂直位移达4m。活动断裂之上的地表破裂带是野外工作中确定地震断裂性质的重要现象。另外,在活动断裂相邻区域和远离区域的路面以及建筑体还大量存在变形现象。通常沿活动断裂产生的地表破裂是典型的同震破裂,相邻区域的地表路面及建筑体发育的变形属于次生变形,远离区域发育的变形则属于震后变形。对次生变形和震后变形测量数据的应用容易影响活动断裂特征的确定和性质的判断,因为路面等建筑体上的挤压拱起、叠置以及水平错断等现象多是受到地震过程中通过断裂活动突然释放的巨大能量作用在局部地表建筑体产生的变形。但是,分布广泛的挤压现象暗示了区域上挤压应力场环境,有利于地表同震破裂位置的推测及地震断裂性质的判断。     

Kinetic mechanism of competitive adsorption of disperse dye and anionic dye on fly ash

The adsorption behavior of four anionic dyes and one disperse dye in single solution and binary solutions on fly ash was investigated in order to elucidate the effect of competitive adsorption on the kinetics. The experimental findings showed that adsorption equilibriums of four anionic dyes were reached within 50 min either in the single solution or in binary mixtures. Competitive adsorption increased the time of attaining equilibrium of disperse dye. Desorption of dyes suggested the predominant adsorption mechanisms, that is, chemisorption for anionic dyes and physisorption for disperse dye. For the binary mixtures, the anionic dyes could be adsorbed preferentially on fly ash at the first stage. Second-order kinetic models fitted better to the equilibrium data of all dyes in the single solution as well as in the binary mixtures. The maximum rate constant of intraparticle diffusion and the minimum external mass transfer coefficient was found for disperse dye both in single and in binary solutions. The intraparticle diffusion constants and external mass transfer coefficients of the four anionic dyes in binary solution are similar to those obtained in single solution. The Biot number confirmed that the intraparticle diffusion was the rate-limiting step in the dye sorption process.     

生态地球化学预测预警若干问题探讨

回顾了生态地球化学危害效应的作用机理,提出了区域地球化学调查-地球化学环境监测-机理研究相结合的生态地球化学预测预警基本思路。根据当前中国多目标区域地球化学调查和生态地球化学评价工作的现状,举例说明了土壤重金属元素累积、土壤环境变化、生态效应机理的若干研究方法,提出了预测预警成果体现的若干建议。     

Geochemical, Sr–Nd and zircon U–Pb–Hf isotopic studies of Late Carboniferous magmatism in the West Junggar, Xinjiang: Implications for ridge subduction?

Voluminous granitic intrusions are distributed in the West Junggar, NW China, and they can be classified as the dioritic rocks, charnockite and alkali-feldspar granite groups. The dioritic rocks (SiO₂ = 50.4–63.8 wt.%) are calc-alkaline and Mg enriched (average MgO = 4.54 wt.%, Mg^# = 0.39–0.64), with high Sr/Y ratios (average = 21.2), weak negative Eu (average Eu/Eu = 0.80) and pronounced negative Nb–Ta anomalies. Their Sr–Nd and zircon Hf isotopic compositions ((⁸⁷Sr/⁸⁶Sr)_i = 0.7035–0.7042, ε_Nd(t) = 4.5–7.9, ε_Hf(t) = 14.1–14.5) show a depleted mantle-like signature. These features are compatible with adakites derived from partial melting of subducted oceanic crust that interacted with mantle materials. The charnockites (SiO₂ = 60.0–65.3 wt.%) show transitional geochemical characteristics from calc-alkaline to alkaline, with weak negative Eu (average Eu/Eu = 0.75) but pronounced negative Nb–Ta anomalies. Sr–Nd and zircon Hf isotopic compositions ((⁸⁷Sr/⁸⁶Sr)_i = 0.7037–0.7039, ε_Nd(t) = 5.2–8.0, ε_Hf(t) = 13.9–14.7) also indicate a depleted source, suggesting melts from a hot, juvenile lower crust. Alkali-feldspar granites (SiO₂ = 70.0–78.4 wt.%) are alkali and Fe-enriched, and have distinct negative Eu and Nb–Ta anomalies (average Eu/Eu = 0.26), low Sr/Y ratios (average = 2.11), and depleted Sr–Nd and zircon Hf isotopic compositions ((⁸⁷Sr/⁸⁶Sr)_i = 0.7024–0.7045, ε_Nd(t) = 5.1–8.9, ε_Hf(t) = 13.7–14.2). These characteristics are also comparable with those of rocks derived from juvenile lower crust. Despite of the differences in petrology, geochemistry and possibly different origins, zircon ages indicate that these three groups of rocks were coevally emplaced at ~ 305 Ma.A ridge subduction model can account for the geochemical characteristics of these granitoids and coeval mafic rocks. As the “slab window” opened, upwelling asthenosphere provided enhanced heat flux and triggered voluminous magmatisms: partial melting of the subducting slab formed the dioritic rocks; partial melting of the hot juvenile lower crust produced charnockite and alkali-feldspar granite, and partial melting in the mantle wedge generated mafic rocks in the region. These results suggest that subduction was ongoing in the Late Carboniferous and, thus support that the accretion and collision in the Central Asian Orogenic Belt took place in North Xinjiang after 305 Ma, and possibly in the Permian.