沉积物孔隙毛细管压力与甲烷水合物饱和度关系研究

To better understand the relationship between the pore capillary pressure and hydrate saturation in sediments, a new method was proposed. First, the phase equilibria of methane hydrate in fine-grained silica sands were measured. As to the equilibrium data, the pore capillary pressure and saturation of methane hydrate were calculated. The results showed that the phase equilibria of methane hydrates in fine-grained silica sands changed due to the depressed activity of pore water caused by the surface group and negatively charged characteristic of silica particles as well as the capillary pressure in small pores together. The capillary pressure increased with the increase of methane hydrate saturation due to the decrease of the available pore space. However, the capillary-saturation relationship could not yet be described quantitatively because of the stochastic habit of hydrate growth.     

Incorporating uncertainty into the estimation of biological reference points for a spiny lobster (Panulirus penicillatus) fishery

The status of a fishery is often defined as the probability of fishing mortality rate exceeding a perilous level for long‐term sustainability. Lobster stock assessments are often subject to large uncertainty in input data and high levels of natural variability in lobster life history processes, which calls for incorporating uncertainty associated with both indicator and management reference points in an evaluation of biological risk of overfishing. Using a Monte Carlo simulation approach, we evaluated the impacts of uncertainty in modelling on the determination of the status of the Taitung spiny lobster (Panulirus penicillatus) fishery (Taiwan), which has not been quantitatively determined despite its commercial importance. The commonly used biological reference points derived from the per recruit model (F _0.1 the fishing mortality rate where the slope of the curve of yield‐per‐recruit model is 10% of the maximum slope and F _4Q%, the fishing mortality rate that reduces the expected egg production for a cohort of female lobsters to 40% of that produced in the absence of a fishery of the egg‐per‐recruit model) were influenced by uncertainties associated with lobster life history and fishery parameters. A large uncertainty in the current fishing mortality rate (F _cnr) and estimates of biological reference points (F _BRPs) increased the uncertainty in determining the risk of overexploitation throughout the confidence levels of the stochastic decision‐making framework. This simulation study suggests that the target reference point of F _40% is less sensitive to the input parameters’ uncertainty than F _0.1 We suggest a further evaluation of other F‐based references points and development of biomass‐based reference points before final selection and implementation for the management of the Taitung lobster fishery.     

Northern Adriatic phytoplankton response to short Po River discharge pulses during summer stratified conditions

A 275‐km‐long transversel Northern Adriatic profile from the mouth of the Po River (Italian Adriatic coast) to the Kvarner region (Croatian coastal island area) was investigated in three successive case studies in August 2008, 2009 and 2010. The short Po River pulses in August result in the surface advection of riverine water, nutrients and phytoplankton from the western to the eastern side of the Adriatic. This surface spreading exhibits inter‐annual variability depending on the riverine discharge in the preceding period. The Po River discharge pulse in August 2010 in particular resulted in an extraordinary tongue‐like advection of riverine water, nutrients, and phytoplankton towards the Eastern Adriatic coast. The phenomenon was detected using both satellite imagery and classical oceanographic measurements. In the advective water, toxic dinoflagellates were most abundant in August 2010, when the influence of the Po was greatest.     

威海近岸人工鱼礁布设对生物资源恢复效果

为了解人工鱼礁投放对区域内海洋生物资源恢复效果,于2013年3月至2014年1月在北黄海近岸人工鱼礁投放区进行调查。结果显示,该海区发现浮游动物53种,其中优势种为浮游桡足类。夏秋季底栖生物幼体成为季节性优势种。游泳动物共发现14种,主要为常见的礁区鱼类。底栖动物共12种,其中棘皮动物海燕为绝对优势种,为近岸养殖生物的主要敌害生物,主要的底栖资源优势种为虾蟹类与软体动物。投礁区的浮游动物与游泳动物物种数明显多于未投礁区,表明人工投礁有助于生物群落的恢复,提高生物多样性,改善区域生态系统。但该海域大型底栖藻类较少,还应进一步对大型底栖藻类增殖以提高海域初级生产。     

Developing an intermediate-complexity projection model for China's fisheries: A case study of small yellow croaker(Larimichthys polyactis) in the Haizhou Bay,China

Projection models are commonly used to evaluate the impacts of fishing. However, previously developed projection tools were not suitable for China's fisheries as they are either overly complex and data-demanding or too simple to reflect the realistic management measures. Herein, an intermediate-complexity projection model was developed that could adequately describe fish population dynamics and account for management measures including mesh size limits, summer closure, and spatial closure. A two-patch operating model was outlined for the projection model and applied to the heavily depleted but commercially important small yellow croaker(Larimichthys polyactis) fishery in the Haizhou Bay, China, as a case study. The model was calibrated to realistically capture the fisheries dynamics with hindcasting. Three simulation scenarios featuring different fishing intensities based on status quo and maximum sustainable yield(MSY) were proposed and evaluated with projections. Stochastic projections were additionally performed to investigate the influence of uncertainty associated with recruitment strengths and the implementation of control targets. It was found that fishing at FMSY level could effectively rebuild the depleted stock biomass, while the stock collapsed rapidly in the status quo scenario. Uncertainty in recruitment and implementation could result in variabilities in management effects; but they did not much alter the management effects of the FMSY scenario. These results indicate that the lack of science-based control targets in fishing mortality or catch limits has hindered the achievement of sustainable fisheries in China. Overall, the presented work highlights that the developed projection model can promote the understanding of the possible consequences of fishing under uncertainty and is applicable to other fisheries in China.     

Pore-water geochemistry in methane-seep sediments of the Makran accretionary wedge off Pakistan: Possible link to subsurface methane hydrate

Cold seeps are pervasive along the continental margin worldwide,and are recognized as hotspots for elemental cycling pathway on Earth.In this study,analyses of pore water geochemical compositions of one-400 cm piston core(S3) and the application of a mass balance model are conducted to assess methane-associated biogeochemical reactions and uncover the relationship of methane in shallow sediment with gas hydrate reservoir at the Makran accretionary wedge off Pakistan.The results revealed that approximately 77% of sulfate is consumed by the predominant biogeochemical process of anaerobic oxidation of methane.However,the estimated sulfate-methane interface depth is-400 cm below sea floor with the methane diffusive flux of 0.039 mol/(m~2·a),suggesting the activity of methane seepage.Based on the δ~(13)C_(DIC) mass balance model combined with the contribution proportion of different dissolved inorganic carbon sources,this study calculated the δ~(13)C of the exogenous methane to be-57.9‰,indicating that the exogenous methane may be a mixture source,including thermogenic and biogenic methane.The study of pore water geochemistry at Makran accretionary wedge off Pakistan may have considerable implications for understanding the specific details on the dynamics of methane in cold seeps and provide important evidence for the potential occurrence of subsurface gas hydrate in this area.     

基于稳定同位素方法的吕泗渔场近岸海域主要生物潜在碳源及营养级分析

基于稳定同位素方法,对2018年吕泗渔场近岸海域夏季主要生物种类的潜在碳源及其营养级进行分析,利用IsoSource模型计算该海域消费者的3大碳源（浮游植物、悬浮颗粒有机物、底质有机物）贡献值,并比较叠加潜在碳源影响前后主要生物种类的营养级变化。结果表明,浮游植物和底质有机物对37种主要生物种类的贡献比例分别为58.7%和28.2%,而悬浮颗粒有机物的贡献较小。因此判定吕泗渔场近岸海域夏季主要生物种类的潜在碳源主要是浮游植物和底质有机物。通过分别叠加3大潜在碳源和单一物种作为基准值构建两个营养级谱,右营养级谱的生物种类营养级范围为1.74～3.92,比左营养级谱平均下降0.19个营养级,尽管两个营养级谱的整体趋势走向不变,但部分鱼类和多数虾类的营养位置发生改变。右营养级谱的基准值随着潜在碳源叠加比例的不同而变化,能有效反映生物营养级,更适用于低营养级的虾蟹类。但对于处于中高级消费者位置的鱼类来说,这种叠加的效果影响不大。     

HD-1注汽井新型防砂材料的研究与应用

孤岛油田属稠油疏松砂岩油藏,生产过程中油井出砂严重,现有的涂敷砂人工井壁防砂注蒸汽后强度较低,造成防砂成功率低,注汽后高强度采液生产周期较短。为此,通过室内试验,优选出耐高温树脂、高强度骨架颗粒、偶联剂、固化剂,进行室内配方优化试验,评价固结体耐高温性能,测定其渗透率,研制出一种适用于疏松砂岩油藏注蒸汽热采井的HD-1注汽井新型防砂材料。在孤岛油田稠油注蒸汽热采区共试验72口井,成功率为91.0%,截止目前,累计产油为121 572 t,单井平均有效期为233 d。现场应用表明：HD-1注汽井新型防砂材料耐高温、强度高,防砂成功率高,有效期长,能够有效改善注蒸汽热采井的防砂效果。     

极性分子型电流变液导电机理研究

极性分子型电流变液是一种新型的电流变材料.其介电颗粒上吸附极性分子,极性分子在颗粒间强局域电场作用下发生取向是产生巨电流变效应的关键.通过对Ca—Ti—O(CTO)体系极性分子型电流变液电流密度的测量发现,其导电行为遵从Poole-Frenkel效应的规律,这是极性分子型电流变液的重要特征之一.而500 ℃处理过的CTO粉体不含极性分子,所配制的电流变液无巨电流变效应,其电流密度随外电场强度近似地呈线性关系,显示出传统电流变液特性.     

Ga和Sb纳米线声子结构和电子-声子相互作用的第一性原理研究

基于密度泛函理论的第一性原理方法,系统研究了Ga和Sb纳米线的电子能带结构和声子结构以及电子-声子耦合(EPC)作用.通过对声子的完整Brillouin区分析来研究纳米线的结构稳定性.结果表明,所考察的纳米线显示出不稳定性,不稳定声子波矢远离Brillouin区中心.与通常的Peierls变形机理相比,不稳定的横向声子模会导致一种无开口带隙的相变.Sb比Ga纳米线的EPC要强很多,并且横向变形导致的锯齿形结构使纳米线中的电子-声子相互作用增加了几个数量级.