A combined experimental study of vivianite and As (V) reactivity in the pH range 2–11

Four different sets of experiments were completed in order to constrain vivianite [Fe₃(PO₄)₂ · 8H₂O] reactivity under conditions pertinent to As(V)-bearing groundwater systems. Firstly, titration experiments were undertaken in the pH range 4-9 to determine the zero point of charge (ZPC) of vivianite; showing that the ZPC lies at a pH of approximately 5.3. Secondly, the steady state dissolution rates of vivianite far from equilibrium were measured in aqueous solutions in the pH range 2–10 at 18.5 ^°C (±3 °C) using a fluidized bed reactor. The rate of vivianite dissolution, R, is given by     

Evaluation of climate reanalysis and space-borne precipitation products over Bangladesh

ABSTRACT

This study aims to quantify the spatial distribution of errors in two climate reanalysis (ERA5 and CFSR) and two satellite (TMPA-RT and TMPA-V7) precipitation products over Bangladesh. The datasets are assessed against ground-based rain gauge observations to capture the extreme rainfall accumulations at daily temporal scale over a 5-year period (January 2010–December 2014). The bias ratio scores indicate that CFSR and TMPA-RT seriously overestimate the rainfall values over much of the study area. Whilst TMPA-V7 performs better than the other precipitation products, all datasets lose their detection skills substantially for higher quantile thresholds (i.e. above 50th and 75th percentiles). With respect to rainfall detection metrics – probability of detection (POD) and volumetric hit index (VHI) – both ERA5 and CFSR show superior performance (in the range 0.9–1.0 for all the analysis grid boxes). All rainfall datasets are equally good in terms of false alarm ratio (FAR) and volumetric FAR (VFAR), even though the lowest values are associated with ERA5 for higher quantiles. All products demonstrate a decrease in skill to capture the amount of rainfall but show satisfactory results to detect the rainfall events when using higher quantile thresholds (i.e. rainfall above the 50th and 75th percentiles) to sample the data before computing product skill.     

The tectonic stress field and deformation pattern of northeast India,the Bengal basin and the Indo-Burma Ranges: A numerical approach

We performed numerical simulations to determine the contemporary maximum horizontal compressive stress (σ_Hmax) in the northeast India region, the Bengal basin (Bangladesh), and the adjoining Indo-Burma Ranges, with different boundary conditions. The regional tectonic stress was simulated using the finite element method (FEM) under the plane stress condition. Most of the study areas show NE–SW regional stress orientation, which is consistent with other stress indicators, such as earthquake focal mechanism solutions. The E–W trending Dauki fault, which separates the Shillong plateau to the north from the Bengal basin to the south, plays a major role in the stress distribution and regional deformation. This fault alone accommodates ～25% of the regional surface displacement rate of the study area. The fault pattern of the study area was also simulated using rheological parameters and the Mohr–Coulomb failure criterion. The simulated results reproduce the observed tectonic state of the area, including a strike-slip regime along the Dauki fault, in the southwestern part of the Bengal basin, and in the Tripura fold belt areas. The modeling indicates that the Brahmaputra valley to the north of the Shillong plateau and to the south of the Himalayan frontal thrust exhibits thrust/reverse faulting with a strike-slip component, and in the Indo-Burma Ranges, strike-slip faulting is predominant with a reverse fault component.     

Paleozoic glaciation in NE Africa: field and remote sensing-based evidence from the South Eastern Desert of Egypt

ABSTRACT

Exhumed Paleozoic glacial deposits and landforms of the North Gondwana are reported here for the first time from the South Eastern Desert (SED) of Egypt. Using field observations and remote sensing datasets (Advanced Land Observing Satellite [ALOS], Phased Array L-band Synthetic Aperture Radar [PALSAR] radar, multispectral Landsat TM datasets, and digital elevation models [DEMs]), we mapped the distribution of Paleozoic glacial features (i.e. deposits and landforms) in the SED. Two main glaciogenic facies were identified in three locations in the SED: (1) massive, poorly sorted, matrix supported, boulder-rich diamictites in Wadi El-Naam and Korbiai, and (2) moderately-sorted, occasionally bedded outwash deposits in Betan area. Inspection of radar, DEMs, and Landsat Operational Land Imager (OLI) images revealed previously unrecognized ENE-WSW trending glacial megalineations (MLs) over the peneplained Neoproterozoic basement rocks in the central sections of the SED, whose trends align along their projected extension with those of glacial features (tunnel valleys and striation trends) reported from Saudi Arabia. The glaciogenic features in the SED are believed to be largely eroded during the uplift associated with the Red Sea opening, except for those preserved as basal units beneath the Nubia Sandstone Formation or as remnant isolated deposits within paleo-depressions within the basement complex. The apparent spatial correlation of the SED glacial features with well-defined Late Ordovician deposits in North Africa and in Saudi Arabia, and the reported thermochronometric analyses and fossil records are consistent with a Late Ordovician age for the SED glaciogenic features and support models that call on the continuation of the Late Ordovician (Hirnantian) ice sheet from the Sahara into Arabia through the SED of Egypt.