The kinetic interactions of metal ions with humic acids

Complexation of europium (III) and UO₂²⁺ by humic acid was found to be very fast (< 1 m). However, passage through ion exchange resin removed a fraction which decreased as the contact time increased over a 2–3 day period. The dissociation kinetics for UO₂²⁺-humate were described by an equation with five first order terms with rate constants ranging from 40.6 m⁻¹ to 5.64×10⁻³ m⁻¹. The percentage of UO₂²⁺ dissociating by the slower paths, comparable to that eluting with the humic acid through the ion exchange resin is assigned to internal site-bound cations (strong binding). The faster dissociating fraction corresponded roughly to the UO₂²⁺ removed by the cation exchange resin (weak binding). The time dependence of the weak to strong binding ratio was associated with change in the conformation of the macromolecular humic acid as the cations neutralized the charge repulsions of the anionic humate.     

Geology of the platanares geothermal area, Departamento de Copán, Honduras

The Platanares geothermal area, Departamento de Copán, Honduras, is located within a graben that is complexly faulted. The graben is bounded on the north by a highland composed of Paleozoic (?) metamorphic rocks in contact with Cretaceous - Tertiary redbeds of unknown thickness. These are unconformably overlain by Tertiary andesitic lavas, rhyolitic ignimbrites, and associated sedimentary rocks. The volcanic rocks are mostly older than 14 Ma, and thus are too old to represent the surface expression of an active crustal magma body. Thermal fluids that discharge in the area are heated during deep circulation of meteoric water along faults in a region of somewhat elevated heat flow. Geothermometry based upon the chemical composition of thermal fluids from hot springs and from geothermal gradient coreholes suggests that the reservoir equilibrated at temperatures as high as 225 to 240°C, within the Cretaceous redbed sequence. Three continuously cored geothermal gradient holes have been drilled; fluids of about 165°C have been produced from two drilled along a NW-trending fault zone, from depths of 250 to 680 m. A conductive thermal gradient of 139°C/km, at a depth of 400 m, was determined from the third well, drilled 0.6 km west of that fault zone. These data indicate that the Platanares geothermal area holds considerable promise for electrical generation by moderate- to hightemperature geothermal fluids.     

Enhancing the human benefits of flood warnings

This article evaluates some of the factors which limit the human benefits of hazard warnings, with specific reference to flood warnings, and we conclude by suggesting ways of enhancing these benefits. We focus mainly upon the economic benefits generated by flood damage savings by households that warnings facilitate; health effects of flooding and flood warnings; and the effects of warnings on loss of life and physical injury. Our results, based partly upon surveys of flooded households, reveal that economic benefits are currently more limited than we previously thought, but that for several reasons these benefits are likely to be under-estimated. We argue that the intangible benefits to public health, safety and security must also be taken into account in decisions about investment in flood warnings. In England and Wales, the public’s response to flood warnings is currently low and is a key benefit-limiting factor which could begin to undermine a recent major shift in national flood risk management policy towards a more people-centred, portfolio approach in which changing human behaviour is viewed as important. Using a trans-disciplinary approach, we discuss the evidence and literature surrounding this poor response, and suggest a number of ways in which the issue may be addressed in future.     

Local tomography and focal mechanisms in the south-western Alps: Comparison of methods and tectonic implications

We investigate how focal solutions and hypocenter locations may depend on the ray tracing algorithm and the strategy of velocity inversion. Using arrival times from a temporary seismological network in the south-western Alps, a local earthquake tomography has been performed by Paul et al. [Paul, A., Cattaneo, M., Thouvenot, F., Spallarossa, D., Béthoux, N., and Fréchet, J., 2001. A three-dimensional crustal velocity model of the south-western Alps from local earthquake tomography. J. Geophys. Res. 106, 19367–19390.] with the method developed by Thurber [Thurber, C.H., 1993. Local earthquake tomography: velocity and Vp/Vs-Theory, in Seismic Tomography: Theory and practice, Iyer, H.M., and Irahara eds., Chapman and Hall, New York, 563–583.]. Another inversion of the same data set is performed here using a different tomography code relying on a shooting paraxial method and cubic interpolation of velocities. The resulting images display the same main features, although Thurber's code appears to be more robust in regions with scarce ray coverage and strong velocity contrasts. Concerning hypocenter location in Piemont units, one major result is the concentration of hypocenters at the boundary between the mantle wedge of the Ivrea body and the European crust. Forty-six focal mechanisms are shown that were computed using both the take-off angles in the minimum 1-D model and in the 3-D velocity structures resulting from the two inversions. The sets of focal solutions are very similar, proving the reliability and the coherency of the focal solutions. The widespread extension in the core of the western Alps is confirmed whereas a few compressive solutions are found east of the Piemont units. These results constrain the sharp change of stress tensor and evidence a decoupling of strain beneath the east of Dora Maira massif up to beneath the north of Argentera massif. On a geodynamical point of view seismicity and focal mechanism distribution are compatible with the present day models published for the western Alps, where the major feature is the lithospheric thickening [Schmid, S.M., and Kissling, E., 2000. The arc of the western Alps in the light of geophysical data on deep crustal structure. Tectonics, 19, 62–85.], implying widespread extension in the core of the western Alps [Sue, C., Thouvenot, F., Fréchet, J., and Tricart, P., 1999. Widespread extension in the core of the western Alps revealed by earthquake analysis. J. Geophys. Res., 104, 25611–25622.]. However the existence of compressive events dealing at depth with the boundary of Ivrea body allows to postulate that this geological structure is still tectonically active. Even if field work has not shown this so far, the Insubric line appears to extend toward the south at depth, as a blind fault, and to play a key role in the dynamics of the south-western Alps.     

Controls on accumulation of a volcaniclastic fan,Ruapehu composite volcano,New Zealand

The Whangaehu fan is the youngest sedimentary component on the eastern ring plain surrounding Ruapehu volcano. Fan history comprises constructional (830–200 years bp) and dissectional (<200 years bp) phases. The constructional phase includes four aggradational periods associated with both syneruptive and inter-eruptive behavior. All four aggradational periods began when deposition by large lahars changed flow conditions on the fan from channelized to unchannelized. Subsequent behavior was a function of the rate of sediment influx to the fan. The rate of sediment influx, in turn, was controlled by frequency and magnitude of volcanic eruptions, short-term climate change, and the amount of sediment stored on the volcano flanks. Fanwide aggradation occurred when rates of sediment influx and deposition on the fan were high enough to maintaìn unchannelized flow conditions on the fan surface. Maintenance of an undissected surface required sedimentation from frequent and large lahars that prevented major dissection between events. These conditions were best met during major eruptive episodes when high frequency and magnitude eruptions blanketed the volcano flanks with tephra and rates of lahar initiation were high. During major eruptive episodes, volcanism is the primary control on sedimentation. Climatic variations do not influence sediment accumulation. Local aggradation occurred when lahars were too small to maintain unchannelized flow across the entire fan. In this case, only the major channel system received much sediment following the deposition from the initial lahar. This localized aggradation occurred if (1) the sediment reservoir on the flank was large enough for floods to bulk into debris flows and (2) sedimentation events were frequent enough to maintain sediment supply to only some parts of the fan. These conditions were met during both minor eruptive and inter-eruptive episodes. In both cases, a large sediment reservoir remained on the volcano flanks from previous major eruptive intervals. Periods of increased storm activity produced floods that bulked to relatively small debris flows. When the sediment reservoir was depleted, the fan entered the present dissectional phase. Syneruptive and noneruptive lahars are mostly channelized and sediment bypasses the fan. Fan deposits are rapidly reworked. This is the present case at Ruapehu, even though the volcano is in a minor eruptive episode and the climate favors generation of intense storm floods.     

Late Weichselian relative sea-level changes and ice sheet history in southeast Greenland

Relative sea-level (RSL) observations from the margins of the Greenland Ice Sheet (GIS) provide information regarding the timing and rate of deglaciation and constraints on geophysical models of ice sheet evolution. In this paper we present the first RSL record for the southeast sector of the GIS based on field observations completed close to Ammassalik. The local marine limit is c. 69 m above sea-level (asl) and is dated to c. 11 k cal. yrs BP (thousand calibrated years before present) and is a minimum date for ice free conditions at the study site. RSL fell to c. 24 m asl by 9.5 k cal. yrs BP and continued to fall at a decreasing rate to reach close to present by 6.5 k cal. yrs BP. Our chronology agrees with radiocarbon dates from offshore cores that indicate ice free conditions on the adjacent mid-shelf by 15 k cal. yrs BP. We compare the new RSL data with predictions generated using two recently published glaciological models of the GIS that differ in the amount and timing of ice loading and unloading over our study area. These two GIS models are coupled to the same Earth viscosity model and background (global) ice model to aid in the data-model comparison. Neither model provides a close fit to the RSL observations. Based on a preliminary sensitivity study using a suite of Earth viscosity models, we conclude that the poor data-model fit is most likely due to an underestimate of the local ice unloading. An improved fit could be achieved by delaying the retreat of a thicker ice sheet across the continental shelf. A thick ice sheet extending well onto the continental shelf is in agreement with other recent observations elsewhere in east and south Greenland.     

The 1996 Biescas campsite disaster in the Central Spanish Pyrenees,and its temporal and spatial context

On the evening of the 7 August 1996 an intense storm occurred over the Arás catchment near Biescas in the central Pyrenees. Eighty-seven people were killed as a result of the subsequent flood, which hit a campsite located on the alluvial fan at the outlet of the 18·8 km² catchment. This paper presents the main results of a hydromorphological study of the event. The Betés subcatchment received the most intense rainfall, estimated at somewhat in excess of 250 mm, which resulted in a peak flow from this tributary of 300 m³ s⁻¹. Just downstream from the Betés river junction, flow in the main channel reached 400 m³ s⁻¹, increasing to around 500 m³ s⁻¹ further downstream. Rainfall in the larger Aso tributary was less intense, and in the head reaches flow remained within-bank, representing a one in two-year return period event. Flow from this tributary did not exceed 100 m³ s⁻¹, indicating that the Betés subcatchment supplied some 75% of the flow from just 28·7% of the catchment area. The extreme flows caused the collapse of a series of sediment trap dams in the Arás channel downstream of the Betés junction. This resulted in the addition of 68 000 m³ of sediment to an already disastrous event. Data from other rain gauges in the area showed both the extremely local nature of the event, and the problems of return period analysis for such storms, whose peaks are rarely observed at gauges. Together with the high geomorphological risks of the zone, this leads to the conclusion that a new method of spatial and temporal risk analysis is required for infrastructure planning. © 1997 John Wiley & Sons, Ltd.     

Dissolved and total organic and inorganic carbon in some British rivers

Rivers transport both organic and inorganic carbon from their sources to the sea. Results of ~800 organic and inorganic analyses from various British rivers of contrasting size and land use are presented here: (1) the headwater River Tern, a rural river of 852 km² catchment; (2) the Ouseburn, a small urban 55 km² catchment; (3) the River Tyne, a larger river system of ~3000 km² catchment; (4) a spatial survey from 205 sample sites on ~60 rivers from SW England. We found that, with the exception of peat-rich headwaters, DIC concentration is always greater than DOC. DIC is primarily in the form HCO₃ ⁻ , with DIC concentrations highest in highly urbanised catchments, typically greater than those observed in catchments with carbonate bedrock, demonstrating a significant and previously unrecognised anthropogenic inorganic carbon input to urban rivers.