The effect of line averaging on concentration fluctuations

The reduction in variance of concentration fluctuations due to line averaging is estimated assuming that the process is influenced by the integral distance scale, y _I , of ambient turbulence and the scaling width, W, of the time-averaged plume. An analytical formula is derived for the line-averaged variance for situations where the autocorrelogram is exponential and the point variance decreases exponentially with distance from plume centerline. Predictions of concentration fluctuation variance are compared with water tank and field data, with the result that the decrease of variance with averaging distance is well-simulated if the model parameters y _I and W are carefully chosen.     

An empirical formula for the height of the coastal internal boundary layer

Observations of the height of the daytime coastal internal boundary layer at several sites are used to justify an empirical formula in the Offshore and Coastal Dispersion (OCD) model, which states that the boundary-layer slope is 0.1 in the first 2km from the shoreline, and 0.03 therafter.     

Acid catalysis of alkyl hydrogen exchange and configurational isomerisation reactions: acyclic isoprenoid acids

Acid-catalysed alkyl hydrogen exchange and configurational isomerisation has been studied in a series of acyclic isoprenoid acids when they were heated at 160°C in the presence of a montmorillonite. Hydrogen exchange occurred between the adsorbed water of the clay surface and the a position of the isoprenoid acids. In cases where this position was chiral, exchange was accompanied by configurational isomerisation. Configurational isomerisation occurred more slowly in experiments conducted without a clay matrix in the presence of water. These results have been rationalized in terms of a reaction mechanism involving protonation of the carbonyl oxygen causing enolization and consequent hydrogen exchange at the a position of the acids. This mechanism was used to account for the relatively fast rate of isomerisation of C-2 chiral centres in sedimentary acyclic isoprenoid acids during maturation.     

Quasi-static propagator matrices: Creep on strike-slip faults

This paper presents a method for computing viscoelastic flow in a layered Earth by means of quasi-static propagator matrices. The method has advantages over approximate or purely numerical attacks in that exact, semi-analytical solutions are obtained. The procedure enables a more rapid calculation than is possible with finite elements, yet it does not sacrifice exactness as do analytical approximations. To illustrate the technique, I constructed a plausible model of the San Andreas fault and investigated the time and space behavior of displacement, displacement rate, shear-stress and shear-strain rate at depth as well as at the surface. Viscoelastic relaxation speeds the restressing of the fault. For events of magnitude 6.2 and 6.9, viscoelasticity reduces recharge time relative to the base strain rate by 15% and 50% respectively. For events of magnitude 6.2 and less, viscoelasticity has only a small influence and a linear extrapolation of stress accumulation will predict the time of recharge reasonably well. Relative plate velocities measured within 400 km of the fault are highly variable in space and time. Direct plate velocity measurements made as far as 100 km from a major fault could differ by a factor of two from the average rate. Features of the fault model at depth include: stresses and strain rates which exceed surface values by a factor of three; sign reversals in strain rates; and positive coseismic stress drops induced for limited periods in narrow thin zones. The latter feature could initiate and terminate aftershock sequences. Stress recharge does not occur simultaneously at all depths on the fault for all magnitude events. Recurrence times of earthquakes estimated from surface observations may thus be biased.     

Hyperfiltration-induced precipitation of calcite

Hyperfiltration is sometimes cited as a mechanism to explain high degrees of calcite cementation at shale/sandstone contacts. To test this cementation mechanism, a series of experiments were performed in which solutions undersaturated with respect to calcite were hydraulically forced through a Ca-bentonite at different flow rates. Calcite precipitate was observed on the bentonite membrane from hyperfiltrated stock solutions having initial calcite saturation indices of 0.91 and 0.59. Supersaturation conditions at the clay's high-pressure interface are likely provided by establishment of a concentration polarization layer.In the subsurface, the driving force for hyperfiltration is a differential hydraulic pressure gradient acting across a shale membrane. This hydraulically-induced flux of solution causes a build-up of solute at the shale's high-pressure interface to levels that may exceed saturation indices of common cementing minerals like calcite. Although the source of the hydraulic pressure is likely due to compaction within the sedimentary pile, directional flow constraints suggest that hyperfiltration-induced precipitation of calcite occurs at sand/shale boundaries away from areas of active compaction.     

The exponential probability density function and concentration fluctuations in smoke plumes

Observations of 1-s average concentration fluctuations during two trials of a U.S. Army diffusion experiment are presented and compared with model predictions based on an exponential probability density function (pdf). The source is near the surface and concentration monitors are on lines about 30 to 100 m downwind of the source. The observed ratio of the standard deviation to the mean of the concentration fluctuations is about 1.3 on the mean plume axis and 4 to 5 on the mean plume edges. Plume intermittency (fraction of non-zero readings) is about 50%; on the mean plume axis and 10%; on the mean plume edges. A meandering plume model is combined with an exponential pdf assumption to produce predictions of the intermittency and the standard deviation of the concentration fluctuations that are within 20%; of the observations.     

Overwater dispersion in coastal regions

Air pollution sources such as oil platforms and ships are sometimes located near coastlines where the plumes can impact population centers. Models of overwater dispersion must account for the stability of the overwater boundary layer. An overwater dispersion model based on the standard Gaussian formula is described which uses measurements of the air-sea temperature difference, the wind speed, and the mixing depth to predict concentration patterns at the coastline. Internal boundary layers and complex terrain at the coastline are accounted for. This new model is evaluated using the results of three tracer experiments in United States coastal zones.     

The oxidation state of manganese in surface sediments of the deep sea

Iodometric titration of deep sea sediment from cores at MANOP sites M and H indicate a particulate Mn oxidation state between 3.3 and 3.9 in the top 5 cm. Results from site H show a minimum in the Mn oxidation state at 1.5 cm depth indicating Mn reduction is occurring above the zone of pore water Mn oxidation. Using a simple box model, the rate of reduction is calculated to be 19 mg/cm² kyr ? 77 mg/cm² kyr, at least 5 times the flux of Mn to nodules in this region. Although no Mn oxidation state minimum is observed in site M sediments, oxic reduction is inferred from a particulate mass balance, indicating that a large fraction of the Mn rain to this site is not preserved in the sediments and must be remobilized. We suggest that the process of reduction in oxic or suboxic environments near the sediment-water interface may be an important mechanism controlling the concentration of Mn in sediments and provides a mechanism for supplying diagenetic Mn to the nodules at site H.     

Population dynamics of spot,leiostomus xanthurus,in polyhaline tidal creeks of the York River estuary,Virginia

Most populations of estuarine-dependent, early life stages of marine fishes are open. As a result, it has been difficult to apply conventional population models to most systems. In this study, a marked population of young-of-year spot (Leiostomus xanthurus) was released into a polyhaline tidal creek within the Guinea Marshes of the York River estuary, Virginia. Over a 90-day study period, 221 marked fishes were recaptured. Plots of the ratio of marked to unmarked individuals (m_i/n_i) in subsequent samples indicated that the population was resident in the creek for up to 162 days with the average individual present for 81 days. When this population turnover rate was compared to the total population decay rate (marked plus unmarked fish), it was determined that exchange between habitats (immigration/emigration) accounted for about 36.4% of the total decay rate, with the remainder attributed to natural mortality. By correcting the overall disappearance rate for population turnover due to emigration and using this adjusted value as a measure of instantaneous mortality (z), the estimated production (over 90 days) in this population was 23,630 cal (98,870 J) per m². This figure agrees with a previously derived estimate for spot in the Guinea marshes and is nearly two orders of magnitude higher than other reported values for this species for all size classes over the entire growing season.     

Plinian and co-ignimbrite tephra fall from the

A study of pyroclastic deposits from the 1815 Tambora eruption reveals two distinct phases of activity, i.e., four initial tephra falls followed by generation of pyroclastic flows and the production of major co-ignimbrite ash fall. The first explosive event produced minor ash fall from phreatomagmatic explosions (F-1 layer). The second event was a Plinian eruption (F-2) correlated to the large explosion of 5 April 1815, which produced a column height of 33 km with an eruption rate of 1.1 × 10⁸ kg/s. The third event occurred during the lull in major activity from 5 to 10 April and produced minor ash fall (F-3). The fourth event produced a 43-km-high Plinian eruption column with an eruption rate of 2.8 × 10⁸ kg/s during the climax of activity on 10 April. Although very energetic, the Plinian events were of short duration (2.8 h each) and total erupted volume of the early (F-1 to F-4) fall deposits is only 1.8 km³ (DRE, dense rock equivalent). An abrupt change in style of activity occurred at end of the second Plinian event with onset of pyroclastic flow and surge generation. At least seven pyroclastic flows were generated, which spread over most of the volcano and Sanggar peninsula and entered the ocean. The volume of pyroclastic flow deposits on land is 2.6 km³ DRE. Coastal exposures show that pyroclastic flows entering the sea became highly fines depleted, resulting in mass loss of about 32%, in addition to 8% glass elutriation, as indicated by component fractionation. The subaqueous pyroclastic flows have thus lost about 40% of mass compared to the original erupted mixture. Pyroclastic flows and surges from this phase of the eruption are stratigraphically equivalent to a major ash fall deposit (F-5) present beyond the flow and surge zone at 40 km from the source and in distal areas. The F-5 fall deposit forms a larger proportion of the total tephra fall with increasing distance from source and represents about 80% of the total at a distance of 90 km and 92% of the total tephra fall from the 1815 eruption. The field relations indicate that the 20-km³ (DRE) F-5 deposit is a co-ignimbrite ash fall, generated largely during entrance of pyroclastic flows into the ocean. Based on the observed 40% fines depletion and component fractionation from the flows, the large volume of the F-5 co-ignimbrite ash requires eruption of 50 km³ (DRE, 1.4 × 10¹⁴ kg) pyroclastic flows.