Structural elements in southeastern Quebec,northwestern Appalachians,Canada

An attempt is made to correlate and separate in terms of style and time two contrasting sets of structural elements in the northwestern part of the Appalachian Uplands in the Province of Quebec, Canada. There is sufficient evidence to indicate that a fold system with north-south trending axes is superimposed on a fold system with east-west axes. It is suggested that the two sets of structures represent pulses of one long-continued deformation accompanied by corresponding early and late phases of metamorphism.

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Zusammenfassung Es wurde versucht, in den Appalachen des südöstlichen Teiles der Provinz Quebec, Kanada, zwei ungleichzeitige tektonische Systeme verschiedenen Baustils zu trennen. Die komplexen Kleinstrukturen zeigen, da\ Ost-West streichende Faltenachsen von einer jüngeren Nord-Süd-Faltung überprägt worden sind. Der Autor ist der Meinung, da\ die zwei tektonischen Systeme, die von einer frühen und späten Phase der Metamorphose begleitet werden, den zeitlich getrennten Verformungsstadien einer Orogenese entsprechen.

     

Horizontal and vertical zones of influence for root systems of four Mojave Desert shrubs

Horizontal and vertical zones of influence for root systems of four Mojave Desert shrubs were characterized using ³²P as a nutrient tracer. Larrea tridentata's horizontal zone of influence was sparse near the plant's stem base, with a maximum probability of accessing ³²P (P_max) of 41%. However, its horizontal zone of influence extended beyond 5 m, and the distance from the stem base at which the probability of accessing ³²P was half P_max (L₅₀3 m) was significantly greater than the other three shrubs. Ambrosia dumosa's zone of influence was dense near the plant's stem base (P_max78%), but was rare at distances >2 m (L₅₀1 m). Zones of influence for Lycium andersonii and Lycium pallidum were intermediate between those of L. tridentata and A. dumosa. For vertical zones of influence, L. tridentata was more likely to obtain ³²P from 5 m soil depths than A. dumosa, but L. pallidum was not significantly different from either A. dumosa or L. tridentata. Horizontal zones of influence did not change with treatments that altered soil water and nitrogen availability, but vertical zones of influence increased with a flood irrigation treatment that increased water availability to 5 m soil depth. These differences among species likely reflect compromises between their shoot growth strategies and their need to acquire spatially and temporally limited soil resources, especially through competitive interactions.     

Schorlomite: a discussion of the crystal chemistry, formula, and inter-species boundaries

Examination of schorlomite from ijolite at Magnet Cove (USA) and silicocarbonatite at Afrikanda (Russia), using electron-microprobe and hydrogen analyses, X-ray diffraction and Mössbauer spectroscopy, shows the complexity of substitution mechanisms operating in Ti-rich garnets. These substitutions involve incorporation of Na in the eightfold-coordinated X site, Fe²⁺ and Mg in the octahedrally coordinated Y site, and Fe³⁺, Al and Fe²⁺ in the tetrahedrally coordinated Z site. Substitutions Ti⁴⁺Fe³⁺Fe³⁺_–1Si_–1 and Ti⁴⁺Al³⁺Fe³⁺_–1Si_–1 are of major significance to the crystal chemistry of schorlomite, whereas Fe²⁺ enters the Z site in relatively minor quantities (<3% Fe). There is no evidence (either structural or indirect, such as discrepancies between the measured and calculated Fe²⁺ contents) for the presence of ^[6]Ti³⁺ or ^[4]Ti⁴⁺ in schorlomite. The simplified general formula of schorlomite can be written as Ca₃Ti⁴⁺₂[Si_3-x(Fe³⁺,Al,Fe²⁺)_xO₁₂], keeping in mind that the notion of end-member composition is inapplicable to this mineral. In the published analyses of schorlomite with low to moderate Zr contents, x ranges from 0.6 to 1.0, i.e. Ti⁴⁺ in the Y site is <2 and accompanied by appreciable amounts of lower-charged cations (in particular, Fe³⁺, Fe²⁺ and Mg). For classification purposes, the mole percentage of schorlomite can be determined as the amount of ^[6]Ti⁴⁺, balanced by substitutions in the Z site, relative to the total occupancy in the Y site: (^[6]Ti⁴⁺–^[6]Fe²⁺–^[6]Mg²⁺– ^[8]Na⁺)/2. In addition to the predominant schorlomite component, the crystals examined in this work contain significant (>15 mol.%) proportions of andradite (Ca₃Fe³⁺₂Si₃O₁₂), morimotoite (Ca₃Fe²⁺TiSi₃O₁₂), and Ca₃MgTiSi₃O₁₂. The importance of accurate quantitative determination and assignment of Fe, Ti and other cations to the crystallographic sites for petrogenetic studies is discussed.

A STUDY OF THE SEISMIC SIGNATURES OF SEDIMENTATION MODELS USING SYNTHETIC SEISMOGRAMS*

In modern exploration for hydrocarbons there is a great emphasis on the location of stratigraphic traps and estimation of lithologic information like sand-shale ratios from seismic data. In order to investigate the possibilities of success in this endeavour we have studied the synthetic seismograms for wave form and spectral characteristic for four basic sedimentation models: (I) interbedded sand-shale model representing the sediments of generally fluviatile origin, (2) interbedded coal-shale model representing deltaic deposits, (3) sedimentary models representing transgression and regression of shore lines, and (4) a basal sand model. The results have shown that for the first two models a change in the sand-shale or coal-shale ratio results in a characteristically different seismogram. The nature of the seismogram, however, is also strongly dependent on how the sand-shale or coal shale layers are arranged to ultimately give the same number of total layers, thus implying the same coal-shale or sand-shale ratios. The transgression, regression, and basal sand models also produce characteristically different seismic signatures. The spectra of these seismograms show attendant characteristic changes. However, it seems that in the case of real data which are disturbed by noise and the effects of overlying layers these characteristic features may not always be distinguishable.     

Principles of tabling

The mechanism of concentration on the shaking table is discussed and a fresh attempt is made to obtain the theoretical model describing the velocity of a fluid in depth and time when in contact with a symmetrically reciprocating surface.The significance of the many design and operational variables and their interrelationships are examined. The various areas where the shaking table plays its role are then considered.The relevant features of micropanner, superpanner and the subsequent macropanner and pulsepanner are also treated since they all, like the shaking table, have the differential motion in common.     

Evaluation of Interactions Between Oilfield Chemicals and Reservoir Rocks

Natural Resources Research - Sand failure and production occurs when the formation stress exceeds the strength of the formation, which is derived majorly from the natural material that cements the...     

X-ray transient sources

The galactic distribution and physical nature of X-ray transient sources is investigated. Two types of transients are considered. The observational data on 41 X-ray transient sources are given, and the average parameters of hard and soft X-ray transients are estimated.     

Power spectrum of brightness temperature fluctuations derived from solar eclipse observations at 2.8 GHz

In this paper we report on the MEM power spectrum analysis of brightness temperature fluctuations observed at 2.8 GHz during the total solar eclipse of 16 February 1980. The observed periodicities range from 3.5 min to 64 min. These periodicities may arise due to spatial and/or temporal variations in the solar radio emission. The observed periodicities imply presence of scale sizes ranging from 70,000 to 600,000 km assuming that the brightness fluctuations arise because of spatial variation only. On the other hand, if these fluctuations are due to temporal variation, the observed periodicities correspond well to predicted modes of solar global oscillations.     

Evidence for focused hot fluid flow within the Britannia Field, offshore Scotland, UK

Fluid inclusion and scanning electron microscope‐cathodoluminescence evidence indicates focused hot, saline, diagenetic fluid flow within the Eastern Flank of the Britannia Field, offshore Scotland, UK. The fluid was sourced from the Andrew Salt Dome, 10 km to the east. The fluids, which promoted quartz cementation of the upper zones within the field, were up to ～30°C hotter and had salinities up to ～10 wt% NaCl equivalent higher than fluids from lower in the reservoir section. During diagenesis hot saline fluids migrated westwards as part of a radiating ‘diagenetic front’ from the Andrew Salt Dome. Structural dip associated with the Eastern Flank of the Fladen Ground Spur impeded the westward movement of the diagenetic fluid. The quartz cements from the upper and lower reservoir zones can be distinguished by morphology. In the upper zones the quartz cements have well‐developed macro‐crystalline zoning and heterogeneous luminescence across the grain. In the lower zones, the cements are much less developed, unzoned and very weakly luminescent. The diagenetic fluids were primarily focused into Zone 45 within the upper reservoir. Furthermore, within the Main Platform Area the most prolific producing zone is Zone 45, indicating the importance of this interval as a permeable flow unit during both diagenetic and production timescales. Within the Eastern Flank, the quartz overgrowths have a major impact on reservoir permeability and thus well productivity. The overgrowths are most extensive in the originally clean sandstones with low clay content. Clay in optimum volumes (5–10%) can inhibit nucleation of the damaging quartz overgrowths without having a detrimental effect on pore connectivity. These observations provide a predictive concept for use in the search for relative reservoir sweetspots within the degraded Eastern Flank.     

Electron paramagnetic resonance,optical absorption,and magnetic circular dichroism studies of the CO 3 − molecular-ion in irradiated natural beryl

Room temperature X-irradiation of some natural beryls produced several new absorption lines in the electron paramagnetic resonance (EPR) spectrum, a known series of optical absorption lines in the 500–700 nm range, and a shift of the absorption edge to lower energies. Several of the new EPR lines and part of the irradiation-induced shift of the absorption edge disappeared after a few days at room temperature, and were not examined in detail. However, three of the paramagnetic centres responsible for the new EPR lines were stable at room temperature and two of these have previously been identified as atomic hydrogen and the methyl radical, CH₃. These species were stable to ～150 and ～450°C respectively. The third stable species, hitherto unreported, showed a single-line EPR spectrum of axial symmetry, with g∥=2.0051 and g⊥=2.0152. This spectrum was found to be intensity-correlated with the series of optical bands in the 500–700 nm range, after thermal bleaching at 175°C. The EPR and optical spectra are therefore assigned to the same species. It is argued that this species is the CO ₃ ^? molecular ion, located in the widest part of the structural channel and aligned with the plane of the molecule perpendicular to the c axis. The EPR spectrum is consistent with a ² A′₂ ground state of a CO ₃ ^? molecule with trigonal symmetry, and this requires that the optical transition has a ² A′₂ → ² E′ character. Most of the features in the optical spectrum can be assigned to coupling of a totally symmetric mode of frequency ～1020 cm^?1 onto a zero-phonon line at 14,490 cm^?1 and a second weaker line at 16,020 cm^?1. However, both of these two fundamental lines are structured, and the two components show strong temperature-dependent derivative-shaped magnetic circular dichroism (MCD). Furthermore, the overall sign of the MCD for the line at 16,020 cm^?1 is opposite to that at 14,490 cm^?1. The separation (～120 cm^?1) of the two components of the 14,490 cm^?1 line is much larger than that expected from spin-orbit interaction, and the origin of this splitting is not yet understood.