Towards a volcanic–structural balance: relative importance of volcanism, folding, and remobilisation of nickel sulphides at the Perseverance Ni–Cu–(PGE) deposit, Western Australia

Perseverance is a world-class, komatiite-hosted nickel sulphide deposit situated in the well-endowed Leinster nickel camp of the Agnew–Wiluna greenstone belt, Western Australia. The mine stratigraphy at Perseverance trends north-northwest (NNW), dips steeply to the west, and is overturned. Stratigraphic footwall units lie along the western margin of the Perseverance Ultramafic Complex (PUC). The PUC comprises a basal nickel sulphide-bearing orthocumulate- to mesocumulate-textured komatiite that is overlain by a thicker, nickel sulphide-poor, dunite lens. Hanging wall rocks include rhyodacite that is texturally and compositionally similar to footwall volcanic rocks. These rocks separate the PUC from a second sequence of nickeliferous, E-facing, spinifex-textured komatiite units (i.e. the East Perseverance komatiite). Past workers argue for a conformable stratigraphic contact between the PUC and the East Perseverance komatiite and conclude that the PUC is extrusive. This study, however, clearly demonstrates that these komatiite sequences are discordant, implying that the PUC may have intruded rhyodacite country rock as a sill with subsequent structural juxtaposition against the East Perseverance komatiite. Early N–S shortening associated with the regional D_I deformation event (corresponding to the local D_P1 to D_P3 events at Perseverance) resulted in the heterogeneous partitioning of strain along the margins of the competent dunite. A mylonite developed in the more ductile footwall rocks along the footwall margin of the PUC, while isoclinal F₃ folds, such as the Hanging wall limb and Felsic Nose folds, formed in low-mean stress domains along the fringes of the elongated dunite lens. Strata-bound massive and disseminated nickel sulphides were passively fold thickened in hinge areas of isoclinal folds, whereas basal massive sulphides lubricated fold limbs and promoted thrust movement along shallowly dipping lithological contacts. Massive sulphides were physically remobilised up to 20 m from their primary footwall position into deposit-scale fold hinges to form the 1A and Felsic Nose orebodies. First-order controls on the geometry of the Perseverance deposit include the thermomechanical erosion of footwall rocks and the channelling of the mineralised komatiitic magma. Second- or third-order controls are several postvolcanic deformation events, which resulted in the progressive folding and shearing of the footwall contact, as well as the passive fold thickening of massive and disseminated sulphide orebodies. Massive sulphides were physically remobilised into multiple generations of fold hinges and shear zones. Important implications for near-mine exploration in the Leinster camp include identifying nickeliferous komatiite units, defining their three-dimensional geometry, and targeting fold hinge areas. Fold plunge directions and stretching lineations are indicators of potential plunge directions of massive sulphide orebodies.     

X-ray and ultraviolet observations of the dwarf nova VW Hyi in quiescence

We present an analysis of X-ray and ultraviolet (UV) data of the dwarf nova VW Hyi that were obtained with XMM–Newton during the quiescent state. The X-ray spectrum indicates the presence of an optically thin plasma in the boundary layer that cools as it settles on to the white dwarf. The plasma has a continuous temperature distribution that is well described by a power law or a cooling flow model with a maximum temperature of 6–8 keV. We estimate from the X-ray spectrum a boundary layer luminosity of  8 × 10³⁰ erg s^-1  , which is only 20 per cent of the disc luminosity. The rate of accretion on to the white dwarf is  5 × 10⁻¹² M_⊙ yr⁻¹  , about half of the rate in the disc. From the high-resolution X-ray spectra, we estimate that the X-ray emitting part of the boundary layer is rotating with a velocity of 540 km s⁻¹, which is close to the rotation velocity of the white dwarf but is significantly smaller than the Keplerian velocity. We detect a 60-s quasi-periodic oscillation of the X-ray flux, which is likely to be due to the rotation of the boundary layer. The X-ray and the UV flux show strong variability on a time-scale of ∼1500 s. We find that the variability in the two bands is correlated and that the X-ray fluctuations are delayed by ∼100 s. The correlation indicates that the variable UV flux is emitted near the transition region between the disc and the boundary layer and that accretion rate fluctuations in this region are propagated to the X-ray emitting part of the boundary layer within ∼100 s. An orbital modulation of the X-ray flux suggests that the inner accretion disc is tilted with respect to the orbital plane. The elemental abundances in the boundary layer are close to their solar values.     

Elucidation of the Alum Shale kerogen structure using a multi-disciplinary approach

The significance and validity of integrating data obtained from a variety of analytical techniques to understand, elucidate and model kerogen's complex chemical structure is reported here using degradative (open and closed system pyrolysis, chemical oxidation), non-degradative (¹³C CP/MAS NMR) and optical (incident white light and blue light) methods. Seven Cambrian Alum Shale samples, ranging in maturity from immature to post-mature with respect to petroleum generation, were studied and were chosen for their simple geological history, uniform organic matter type and high organic carbon content. The Alum Shale kerogens, which primarily consist of algal organic matter, liberate low molecular weight gaseous and aromatic compounds on pyrolysis and give mostly branched dicarboxylic acids on chemical oxidation. ¹³C NMR spectroscopy shows that the Alum Shale kerogens are anomalously rich in oxygen-bearing functional groups (such as C = O, ArCO, CHO, CH_xO), most of which apparently remain intact within the kerogen macro-molecule (KMM) through the diagenetic and catagenetic stages. Fragments released by different degradative techniques are quantified and the aromaticity (f_a), O/C and relative proportions of various carbon types estimated by ¹³C NMR. A synthesis of these data has allowed us to better understand the chemistry of the Alum Shale kerogen.     

Flood seasonality across Scandinavia—Evidence of a shifting hydrograph?

Fluvial flood events have substantial impacts on humans, both socially and economically, as well as on ecosystems (e.g., hydroecology and pollutant transport). Concurrent with climate change, the seasonality of flooding in cold environments is expected to shift from a snowmelt‐dominated to a rainfall‐dominated flow regime. This would have profound impacts on water management strategies, that is, flood risk mitigation, drinking water supply, and hydro power. In addition, cold climate hydrological systems exhibit complex interactions with catchment properties and large‐scale climate fluctuations making the manifestation of changes difficult to detect and predict. Understanding a possible change in flood seasonality and defining related key drivers therefore is essential to mitigate risk and to keep management strategies viable under a changing climate. This study explores changes in flood seasonality across near‐natural catchments in Scandinavia using circular statistics and trend tests. Results indicate strong seasonality in flooding for snowmelt‐dominated catchments with a single peak occurring in spring and early summer (March through June), whereas flood peaks are more equally distributed throughout the year for catchments located close to the Atlantic coast and in the south of the study area. Flood seasonality has changed over the past century seen as decreasing trends in summer maximum daily flows and increasing winter and spring maximum daily flows with 5–35% of the catchments showing significant changes at the 5% significance level. Seasonal mean daily flows corroborate those findings with higher percentages (5–60%) of the catchments showing statistically significant changes. Alterations in annual flood occurrence also point towards a shift in flow regime from snowmelt‐dominated to rainfall‐dominated with consistent changes towards earlier timing of the flood peak (significant for 25% of the catchments). Regionally consistent patterns suggest a first‐order climate control as well as a local second‐order catchment control, which causes inter‐seasonal variability in the streamflow response.     

Exploring hydroclimatic change disparity via the Budyko framework

The Budyko framework characterizes landscape water cycles as a function of climate. We used this framework to identify regions with contrasting hydroclimatic change during the past 50 years in Sweden. This analysis revealed three distinct regions: the mountains, the forests, and the areas with agriculture. Each region responded markedly different to recent climate and anthropogenic changes, and within each region, we identified the most sensitive subregions. These results highlight the need for regional differentiation in climate change adaptation strategies to protect vulnerable ecosystems and freshwater resources. Further, the Budyko curve moved systematically towards its water and energy limits, indicating augmentation of the water cycle driven by changing vegetation, climate and human interactions. This finding challenges the steady state assumption of the Budyko curve and therefore its ability to predict future water cycles. Copyright © 2013 John Wiley & Sons, Ltd.     

Nearshore bar migration and sediment-induced buoyancy effects

A 1-D General Ocean Turbulence Model that includes the effects of sediment-induced stratification is shown to simulate the observed onshore and offshore migration of a nearshore sandbar. The only two free parameters of the model, the bed reference concentration and the sediment diffusivity, are taken from the literature, rather than tuned to the data used here. The model results suggest that predictions of onshore bar migration, in which wave-induced sediment transport confined to within a few centimeters of the bottom dominates, are not greatly affected by accounting for buoyancy effects. The model results also suggest that both mean flows and waves transport sediment during offshore bar migration, with different components of transport dominating at different cross-shore locations across the bar-trough bathymetry. Neglecting the effects of sediment-induced stratification results in higher model skill during the largest waves, likely because the excess turbulence production simulated by the non-stratified model is counterbalanced by neglected breaking-wave-generated turbulence. Considering both onshore and offshore migration, the model that includes sediment-induced stratification has higher skill than the model without stratification.     

The impact of extreme heat on morbidity in Milwaukee, Wisconsin

Given predictions of increased intensity and frequency of heat waves, it is important to study the effect of high temperatures on human mortality and morbidity. Many studies focus on heat wave-related mortality; however, heat-related morbidity is often overlooked. The goals of this study are to examine the historical observed relationship between temperature and morbidity (illness), and explore the extent to which observed historical relationships could be used to generate future projections of morbidity under climate change. We collected meteorological, air pollution, and hospital admissions data in Milwaukee, Wisconsin, for the years 1989–2005, and employed a generalized additive model (GAM) to quantify the relationship between morbidity (as measured by hospital admissions) and high temperatures with adjustment for the effects of potential confounders. We also estimated temperature threshold values for different causes of hospital admissions and then quantified the associated percent increase of admissions per degree above the threshold. Finally, the future impact of higher temperatures on admissions for the years 2059–2075 was examined. Our results show that five causes of admission (endocrine, genitourinary, renal, accidental, and self-harm) and three age groups (15–64, 75–84, >85 years) were affected by high temperatures. Future projections indicate a larger number of days above the current temperature threshold leading to an increase in admissions. Our results indicate that climate change may increase heat-related hospital admissions in the US urban mid-West and that health systems should include heat wave planning.     

Organic carbon isotope ratios of recent sediments from coastal lagoons of the Gulf of Mexico,Mexico

The stable carbon isotope composition sedimentary organic carbon was determined in the sediments of seven coastal lagoons of the Gulf of Mexico, Mexico. For most of the lagoons the δ¹³C values for sediments ranged from ?20.1 to ?23.9%. Anomalously low values, ?26.8 to 29.3%. were determined in sediments of two of the studied lagoons, probably due to the presence of organic carbon from anthropogenic sources, naturally absent in these environments. The δ¹³C values determined in the tissues of oysters collected at the same time in the different lagoons were very similar to those recorded in the sediments.     

Consequences of change and variability in sea ice on marine ecosystem and biogeochemical processes during the 2007–2008 Canadian International Polar Year program

Change and variability in the timing and magnitude of sea ice geophysical and thermodynamic state have consequences on many aspects of the arctic marine system. The changes in both the geophysical and thermodynamic state, and in particular the timing of the development of these states, have consequences throughout the marine system. In this paper we review the ??consequences?? of change in sea ice state on primary productivity, marine mammal habitats, and sea ice as a medium for storage and transport of contaminants and carbon exchange across the ocean-sea-ice-atmosphere interface based upon results from the International Polar Year. Pertinent results include: 1) conditions along ice edges can bring deep nutrient-rich ??pacific?? waters into nutrient-poor surface waters along the arctic coast, affecting local food webs; 2) both sea ice thermodynamic and dynamic processes ultimately affect ringed seal/polar bear habitats by controlling the timing, location and amount of surface deformation required for ringed seal and polar bear preferred habitat 3) the ice edges bordering open waters of flaw leads are areas of high biological production and are observed to be important beluga habitat. 4) exchange of climate-active gases, including CO₂, is extremely active in sea ice environments, and the overall question of whether the Arctic Ocean is (or will be) a source or sink for CO₂ will be dependent on the balance of competing climate-change feedbacks.