On the Measurement of PANs by Gas Chromatography and Electron Capture Detection

A fast, automated, gas chromatographic system for the airborne measurement of PAN and a series of its homologues is described and its performance is evaluated. Response factors for PAN, PPN, APAN, PiBN, and MPAN have been determined and are discussed with regard to ECD response and to potential losses in the analytical system. Calibration methods used for these tasks are described and compared. The results from this work should help investigators who are employing the widely used GC/ECD method for the measurement of peroxyacyl nitrates to evaluate peaks of PAN homologues that cannot be calibrated for by using the reported response factors.     

Three-dimensional simulations and wind-tunnel experiments on airflow over isolated forest stands

Prediction of windthrow risk to individual or groups of retained trees in harvested stands requires an improved understanding of canopy airflow dynamics. Large-eddy simulations were used to simulate wind-tunnel experiments in two and three dimensions to compare with observations for model validation and to address parameter space considerations for the design of subsequent retention pattern experiments. The three-dimensional simulations were similar to the observed wind-tunnel data for the statistical profiles for but there were greater differences in skewness and kurtosis. These results were obtained using a common leaf-area drag formulation without either skin friction or speed dependent drag that enables scaling with U ₀ (ambient wind speed) and h (height of the canopy). This scaling results in a single non-dimensional parameter h/h _c where h _c (x, y, z) is the momentum range resulting from the canopy drag. The validity of the model scaling was tested using two-dimensional simulations. The irrotational component of the flow (potential flow) was found to be important when defining vertical domain limitations and has significant implications for time dependent flow (i.e. turbulent conditions) when considering retention pattern design. The sudden onset of drag associated with the isolated stand presents some unexpected challenges. The horizontal scales of the shearing instabilities were simulated in two dimensions and found to range between 2h for early times to 7h for later times. The early-time horizontal scales are in the range of logical retention pattern scales and as such need to be taken into account as part of the parameter space, i.e. a range of retention pattern lengths need consideration.     

Mapping bedrock lithologies through in situ regolith using retained element ratios: a case study from the Agnew-Lawlers area,Western Australia

Large, high-quality multi-element geochemical datasets are becoming widely available in the exploration industry, and afford excellent opportunities to investigate geochemical processes. A dataset of over 2500 analyses of unweathered and variably weathered mafic and ultramafic rocks for over 50 elements has been collected by Gold Fields Ltd. in the auriferous Agnew-Lawlers area of the eastern Yilgarn Craton of Western Australia. This dataset is used to investigate changes in element abundances and inter-element ratios through varying degrees and styles of weathering in an area of thick regolith characterised by deep in situ weathering. Systematic interrogation of the data, using lithostratigraphic controls derived from regional mapping and geophysics, reveals that a suite of elements, including Ti, Al, Zr, Th, La, Sc and Nb, and to a lesser extent Cr and Ni, behave as essentially immobile components during saprolite formation. In some cases diagnostic element ratios persist into siliceous duricrust. Ratios of these elements are used as reliable discriminants of bedrock type, and delineate features such as cryptic layering within fractionated sills and subtle geochemical variants in a sequence of tholeiitic and komatiitic basalts. Mapping on the basis of discriminant element ratios greatly extends previous trace-element ratio-based schemes for rock type discrimination. The potential to determine several of these elements with adequate precision and accuracy using portable XRF technology opens a potentially useful technique for rapid geochemical bedrock mapping in residual terrains.     

Modeling Solar Spectral Irradiance and Total Magnetic Flux Using Sunspot Areas

We show that daily sunspot areas can be used in a simple, single parameter model to reconstruct daily variations in several other solar parameters, including solar spectral irradiance and total magnetic flux. The model assumes that changes in any given parameter can be treated mathematically as the response of the system to the emergence of a sunspot. Using cotemporal observational data, we compute the finite impulse response (FIR) function that describes that response in detail, and show that the response function has been approximately stationary over the time period for which data exist. For each parameter, the impulse response function describes the physical evolution of that part of a solar active region that is the source of the measured variability. We show that the impulse response functions are relatively narrow functions, no more than 3 years wide overall. Each exhibits a pre-active, active, and post-active region component; the active region component dominates the variability of most of the parameters studied.     

Magnetic-cloud chamber effects behind flare-generated shock waves

A mechanism explaining the generation of the helium-enriched plasma-condensation colud (HAE-events) behind the front of shock waves associated with mass-ejecting flares is presented. The mechanism is based on the occurence of physical conditions, analogous to those in a Wilson cloud chamber in a magnetic field, behind the front of a flare-generated shock wave propagation out into interplanetary space. Consequently, if the solar atmosphere above the flare active region is saturated with ejected helium plasma, conditions are created for the forming of the helium-enriched plasma-condensation colud in the temperature-depressed region behind the shock wave front.     

Neutrino transport in supernova models: A multigroup,flux limited diffusion scheme

A multigroup, diffusion scheme is derived from the Boltzmann equation for efficient numerical computation of neutrino transport in a collapsing stellar core. This scheme treats all neutrino scattering processes correctly with a Legendre expansion of the scattering rates. Modifications of the diffusion coefficient and the addition of a flux limiter extend the applicability of the scheme to neutrino transparent regimes and improve the agreement of the solution in both opaque and transparent regimes with those obtained analytically for some test problems. In addition, a more accurate treatment of the neutrino flowAcross shock discontinuities is developed through a shock matching condition. The solutions given by this multigroup, flux-limited diffusion scheme are compared with those of a modifiedS _N code.Supported in part by the National Science Foundation (Grant AST75-05012 and AST 77-17572).     

PheniX: a new vision for the hard X-ray sky

We are proposing a mission devoted to high energy X-ray astronomy that is based on a focusing telescope operating in the 1?C200?keV energy range but optimized for the hard X-ray range. The main scientific topics concern: Physics of compact objects: The proximity of compact objects provides a unique laboratory to study matter and radiation in extreme conditions of temperature and density in strong gravitational environment. The emission of high energy photons from these objects is far from being understood. The unprecedented sensitivity in the high energy domain will allow a precise determination of the non-thermal processes at work in the vicinity of compact objects. The full 1?C200?keV energy coverage will be ideal to disentangle the emission processes produced in the spacetime regions most affected by strong-gravity, as well as the physical links: disk?Cthermal emission?Ciron line?Ccomptonisation?Creflection?Cnon-thermal emission?Cjets. Neutron stars?Cmagnetic field?Ccyclotron lines: Time resolved spectroscopy (and polarimetry) at ultra-high sensitivity of AXP, milliseconds pulsars and magnetars will give new tools to study the role of the synchrotron processes at work in these objects. Cyclotron lines?Cdirect measurement of magnetic filed?Cequation of state constraints?Cshort bursts?Cgiant flares could all be studied with great details. AGN: The large sensitivity improvement will provide detailed spectral properties of the high energy emission of AGN??s. This will give a fresh look to the connection between accretion and jet emission and will provide a new understanding of the physical processes at work. Detection of high-redshift active nuclei in this energy range will allow to introduce an evolutionary aspect to high-energy studies of AGN, probing directly the origin of the Cosmic X-ray Background also in the non-thermal range (> 20?keV). Element formation?CSupernovae: The energy resolution achievable for this mission (<0.5?keV) and a large high energy effective area are ideally suited for the 44Ti line study (68 and 78?keV). This radioactive nuclei emission will give an estimate of their quantities and speed in their environment. In addition the study of the spatial structure and spectral emission of SNR will advance our knowledge of the dynamics of supernovae explosions, of particles acceleration mechanisms and how the elements are released in the interstellar medium. Instrumental design: The progress of X-ray focusing optics techniques allows a major step in the instrumental design: the collecting area becomes independent of the detection area. This drastically reduces the instrumental background and will open a new era. The optics will be based on depth-graded multi-layer mirrors in a Wolter I configuration. To obtain a significant effective area in the hundred of keV range a focal length in the 40?C50 meters range (attainable with a deployable mast) is needed. In addition such a mission could benefit from recent progress made on mirror coating. We propose to cover the 1?C200?keV energy range with a single detector, a double-sided Germanium strip detector operating at 80?K. The main features will be: (a) good energy resolution (.150?keV at 5?keV and <.5?keV at 100?keV), (b) 3 dimensional event localization with a low number of electronic chains, (c) background rejection by the 3D localization, (d) polarisation capabilities in the Compton regime.