Pressure-induced incipient amorphization of α-quartz and transition to coesite in an eclogite from Antarctica: a first record and some consequences

Monocrystalline quartz inclusions in garnet and omphacite from various eclogite samples from the Lanterman Range (Northern Victoria Land, Antarctica) have been investigated by cathodoluminescence (CL), Raman spectroscopy and imaging, and in situ X‐ray (XR) microdiffraction using the synchrotron. A few inclusions, with a clear‐to‐opalescent lustre, show ‘anomalous’ Raman spectra characterized by weak α‐quartz modes, the broadening of the main α‐quartz peak at 465 cm^?1, and additional vibrations at 480–485, 520–523 and 608 cm^?1. CL and Raman imaging indicate that this ‘anomalous’α‐quartz occurs as relicts within ordinary α‐quartz, and that it was preserved in the internal parts of small quartz inclusions. XR diffraction circular patterns display irregular and broad α‐quartz spots, some of which show an anomalous d‐spacing tightening of ～2%. They also show some very weak, hazy clouds that have d‐spacing compatible with coesite but not with α‐quartz. Raman spectrometry and XR microdiffraction characterize the anomalies with respect to α‐quartz as (i) a pressure‐induced disordering and incipient amorphization, mainly revealed by the 480–485 and 608‐cm^?1 Raman bands, together with (ii) a lattice densification, evidenced by d‐spacing tightening; (iii) the cryptic development of coesite, 520–523 cm^?1 being the main Raman peak of coesite and (iv) Brazil micro‐twinning. This ‘anomalous’α‐quartz represents the first example of pressure‐induced incipient amorphization of a metastable phase in a crustal rock. This issue is really surprising because pressure‐induced amorphization of metastable α‐quartz, observed in impactites and known to occur between 15 and 32 GPa during ultrahigh‐pressure (UHP) experiments at room temperature, is in principle irrelevant under normal geological P–T conditions. A shock (due to a seism?) or a local overpressure at the inclusion scale (due to expansion mismatch between quartz and its host mineral) seem the only geological mechanisms that can produce such incipient amorphization in crustal rocks. This discovery throws new light on the modality of the quartz‐coesite transition and on the pressure regimes (non‐lithostatic v. lithostatic) during high‐pressure/UHP metamorphism. In particular, incipient amorphization of quartz could favour the quartz‐coesite transition, or allow the growth of metastable coesite, as already experimentally observed.     

济宁市嘉祥县石灰岩矿山地质环境评价与治理

在对嘉祥县石灰岩矿进行地质灾害危险性评估、矿山环境地质问题评价的基础上,建立了一套评价体系,其中地质灾害危险性评估分为2个评价指标,矿山环境地质问题评价分为2种要素3个指标,同时将矿山恢复治理难易程度也作为一个评价因子。评价过程中对各指标危害性大、中、小程度均单独赋值,然后将各指标的分值进行叠加,确定出矿山环境地质问题的等级,将概划出的13个评价单元分为极差、差、一般3个区。提出了强化矿山管理、植树造林、科学避让、修建拦水坝等保护与治理措施及建议。     

Self-consistent response of a galactic disc to vertical perturbations

We study the self-consistent, linear response of a galactic disc to vertical perturbations, as induced, say, by a tidal interaction. We calculate the self-gravitational potential corresponding to a non-axisymmetric, self-consistent density response of the disc using the Green's function method. The response potential is shown to oppose the perturbation potential because the self-gravity of the disc resists the imposed potential, and this resistance is stronger in the inner parts of a galactic disc. For the   m = 1  azimuthal wavenumber, the disc response opposes the imposed perturbation up to a radius that spans a range of 4–6 disc scalelengths, so that the disc shows a net warp only beyond this region. This physically explains the well known but so far unexplained observation that warps typically set in beyond this range of radii. We show that the inclusion of a dark matter halo in the calculation only marginally changes (by ∼10 per cent) the radius for the onset of warps. For perturbations with higher azimuthal wavenumbers, the net signature of the vertical perturbations can only be seen at larger radii – for example, beyond 7 exponential disc scalelengths for   m = 10  . Also, for the high- m cases, the magnitude of the negative disc response due to the disc self-gravity is much smaller. This is shown to result in corrugations of the mid-plane density, which explains the puzzling scalloping with   m = 10  detected in H  i in the outermost regions ∼30 kpc in the Galaxy.     

P‐wave transmission across fractures with nonlinear deformational behaviour

Stress wave attenuation across fractured rock masses is a great concern of underground structure safety. When the wave amplitude is large, fractures experience nonlinear deformation during the wave propagation. This paper presents a study on normal transmission of P‐wave across parallel fractures with nonlinear deformational behaviour (static Barton–Bandis model). The results show that the magnitude of transmission coefficient is a function of incident wave amplitude, nondimensional fracture spacing and number of fractures. Two important indices of nondimensional fracture spacing are identified, and they divide the area of nondimensional fracture spacing into three parts (individual fracture area, transition area and small spacing area). In the different areas, the magnitude of transmission coefficient has different trends with nondimensional fracture spacing and number of fractures. In addition, the study reveals that under some circumstances, the magnitude of transmission coefficient increases with increasing number of fractures, and is larger than 1. Copyright © 2006 John Wiley & Sons, Ltd.     

The Cosmology of Extra Dimensions and Varying Fundamental Constants

I briefly present the Organizing Committee's and my own motivation for organizing this workshop, and I suggest a few key questions for which we will try to find possible answers in the coming days. This revised version was published online in July 2006 with corrections to the Cover Date.     

邻菲啰啉在测定亚铁中的保护效果

样品在分解过程中 ,亚铁易被空气部分氧化 ,致使测试结果偏低 ,采用在HF H2 SO4溶矿过程中加入邻菲卟罗啉 ,与亚铁形成络合物 ,对保护亚铁具有较好的效果。拟定了在塑料坩埚中加邻菲卟罗啉、H2 SO4及HF ,中高温电热板溶矿 ,容量法测定样品中的亚铁 ,方法精密度为 0 .2 3% ,样品加标准回收率 98.8%～ 10 1.9%。此方法具有较好的应用效果