Trace metals in the North Sea

The distribution of zinc, manganese, nickel, copper and cadmium in water and biological material has been measured in the southern North Sea and Straits of Dover, and off the north-east coast of England. These investigations provide baseline values against which future pollution changes can be measured.     

Preparation,collisional decay and transfer of alignment in C2H2 21

Stimulated Raman scattering is used to prepare ensembles of aligned acetylene molecules in thev ₂=1 excited vibrational level. Decay and transfer of the alignment is followed by laser induced fluorescence. Measurements of the initially excited alignment agree well with theoretical calculations. The rate constants for decay decrease as the rotational quantum numberJ of the excited level increases.     

Dissociative recombination of electrons with NO+ ions

Resonant scattering theory is applied to the calculation of the rate of dissociative recombination in e-NO⁺ collisions. For ground state ions at 300 K, the recombination rate is 4.3 × 10^?7 cm³ s^?1, in good agreement with the afterglow data. At higher electron temperatures, the calculated rate lies between the values measured in afterglow and trapped-ion experiments. A possible explanation of this discrepancy is offered. For vibrationally excited ions, the recombination coefficient is significantly lower than that of the ground state.     

Imbalance in the carbonate budget of surficial sediments in the North Atlantic Ocean: variations over the last millenium?

Fluxes contributing to the particulate carbonate system in deep-sea sediments were investigated at the BENGAL site in the Porcupine Abyssal Plain (Northeast Atlantic). Deposition fluxes were estimated using sediment traps at a nominal depth of 3000 m and amounted to 0.37±0.1 mmol C m⁻² d⁻¹. Dissolution of carbonate was determined using flux of total alkalinity from in situ benthic chambers, is 0.4±0.1 mmol C m⁻² d⁻¹. Burial of carbonate was calculated from data on the carbonate content of the sediment and sedimentation rates from a model age based on ¹⁴C dating on foraminifera (0.66±0.1 mmol C m⁻² d⁻¹). Burial plus dissolution was three times larger than particle deposition flux which indicates that steady-state is not achieved in these sediments. Mass balances for other components (BSi, ²¹⁰Pb), and calculations of the focusing factor using ²³⁰Th, show that lateral inputs play only a minor role in this imbalance. Decadal variations of annual particle fluxes are also within the uncertainty of our average. Long-term change in dissolution may contribute to the imbalance, but can not be the main reason because burial alone is greater than the input flux. The observed imbalance is thus the consequence of a large change of carbonate input flux which has occured in the recent past. A box model is used to check the response time of the solid carbonate system in these sediments and the time to reach a new steady-state is in the order of 3 kyr. Thus it is likely that the system has been perturbed recently and that large dissolution and burial rates reflect the previously larger particulate carbonate deposition rates. We estimate that particulate carbonate fluxes have certainly decreased by a factor of at least 3 and that this change has occurred during the last few centuries.     

青藏高原羌塘盆地东部鄂尔陇巴组火山岩的锆石SHRIMP U-Pb年龄及其地质意义

藏北羌塘盆地东部地区三叠系巴贡组之上沉积超覆了一套火山岩-火山碎屑岩. 该套地层下部玄武岩的锆石SHRIMP U-Pb年龄明显可以分为2组,一组年龄相对年轻 （220.4Ma±2.3Ma）,代表了羌塘东部地区鄂尔陇巴组火山岩的喷发年龄;另外一组 年龄相对较老（241.4Ma±3.6Ma）,可能与中三叠世羌塘地区普遍存在的碰撞隆升事 件有关。羌塘中生代（晚三叠世—早白垩世）盆地演化早期的沉积作用经历了由陆相 至海相的超覆过程,沉积超覆作用从冲洪积相开始,伴随着岩浆侵入、火山爆发及火 山碎屑沉积作用,总体上表现为一个向上变深的海侵序列,显示裂谷盆地的特征。     

The plan shape of current ripples in relation to flow conditions

Two sets of empirical data on the relationship of the plan shape of current ripples to flow conditions previously thought incompatible are reconciled by taking explicit and necessary account of the effects of flow width relative to flow depth. The aspects of plan shape considered are the mean streamwise ripple wavelength and the wavelength, measured across the flow, of longitudinal features due to centrifugal instability formed on the backs of the ripples. A regression analysis connecting these attributes with flow conditions including the width-effect shows that the amount of unexplained variability is of the same order as the accumulated experimental errors, and suggests that the two sets of data are in excellent agreement. The relationship of the plan geometry to flow conditions is less simple than has sometimes been supposed, but ways are suggested in which the experimental results can be used to establish the hydraulics of past environments.