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991.
Stephen B. Castor 《Resource Geology》2008,58(4):337-347
Rare earth elements (REE) have been mined in North America since 1885, when placer monazite was produced in the southeast USA. Since the 1960s, however, most North American REE have come from a carbonatite deposit at Mountain Pass, California, and most of the world’s REE came from this source between 1965 and 1995. After 1998, Mountain Pass REE sales declined substantially due to competition from China and to environmental constraints. REE are presently not mined at Mountain Pass, and shipments were made from stockpiles in recent years. Chevron Mining, however, restarted extraction of selected REE at Mountain Pass in 2007. In 1987, Mountain Pass reserves were calculated at 29 Mt of ore with 8.9% rare earth oxide based on a 5% cut‐off grade. Current reserves are in excess of 20 Mt at similar grade. The ore mineral is bastnasite, and the ore has high light REE/heavy REE (LREE/HREE). The carbonatite is a moderately dipping, tabular 1.4‐Ga intrusive body associated with ultrapotassic alkaline plutons of similar age. The chemistry and ultrapotassic alkaline association of the Mountain Pass deposit suggest a different source than that of most other carbonatites. Elsewhere in the western USA, carbonatites have been proposed as possible REE sources. Large but low‐grade LREE resources are in carbonatite in Colorado and Wyoming. Carbonatite complexes in Canada contain only minor REE resources. Other types of hard‐rock REE deposits in the USA include small iron‐REE deposits in Missouri and New York, and vein deposits in Idaho. Phosphorite and fluorite deposits in the USA also contain minor REE resources. The most recently discovered REE deposit in North America is the Hoidas Lake vein deposit, Saskatchewan, a small but incompletely evaluated resource. Neogene North American placer monazite resources, both marine and continental, are small or in environmentally sensitive areas, and thus unlikely to be mined. Paleoplacer deposits also contain minor resources. Possible future uranium mining of Precambrian conglomerates in the Elliott Lake–Blind River district, Canada, could yield by‐product HREE and Y. REE deposits occur in peralkaline syenitic and granitic rocks in several places in North America. These deposits are typically enriched in HREE, Y, and Zr. Some also have associated Be, Nb, and Ta. The largest such deposits are at Thor Lake and Strange Lake in Canada. A eudialyte syenite deposit at Pajarito Mountain in New Mexico is also probably large, but of lower grade. Similar deposits occur at Kipawa Lake and Lackner Lake in Canada. Future uses of some REE commodities are expected to increase, and growth is likely for REE in new technologies. World reserves, however, are probably sufficient to meet international demand for most REE commodities well into the 21st century. Recent experience shows that Chinese producers are capable of large amounts of REE production, keeping prices low. Most refined REE prices are now at approximately 50% of the 1980s price levels, but there has been recent upward price movement for some REE compounds following Chinese restriction of exports. Because of its grade, size, and relatively simple metallurgy, the Mountain Pass deposit remains North America’s best source of LREE. The future of REE production at Mountain Pass is mostly dependent on REE price levels and on domestic REE marketing potential. The development of new REE deposits in North America is unlikely in the near future. Undeveloped deposits with the most potential are probably large, low‐grade deposits in peralkaline igneous rocks. Competition with established Chinese HREE and Y sources and a developing Australian deposit will be a factor. 相似文献
992.
Elisa Sacchi Gian Maria Zuppi Luca Pizzino Fedora Quattrocchi Salvatore Lombardi 《Aquatic Geochemistry》2008,14(4):301-319
The EC funded Geochemical Seismic Zonation program (EEC GSZ Project 1996–1998) chose Sardinia as a low-seismicity site, in which the relationships between fluid geochemistry and seismo-tectonics
had to be investigated and results compared with outcomes from other selected high-seismicity sites. A first article, examining
the role of fault segmentation and seismic quiescence on the geochemical composition of groundwaters and gases, has already
been presented (Angelone et al. 2005). This article deals with environmental isotopes which, together with selected hydrochemical data, give hints on tectonically-related
fluid circulations. Four water-dominated hydrothermal systems were considered, all located along regional fault systems and
discharging groundwaters belonging to the Na–HCO3 and Na–Cl facies. In the considered systems, groundwater circulation takes place, principally, in the Palaeozoic Crystalline
Basement (PCB), with the exception of the Logudoro system, where hydrological circuits develop in the Mesozoic Carbonate Platform
(MCP). The high CO2 contents, the non-attainment of fluid-rock equilibrium and the large lithological variability prevent the construction of
a unique hydrogeological–geochemical conceptual model. In this case, stable isotopes provide a useful tool to describe the
origin of fluids and their subterranean movements. Stable isotopes of water, integrated with hydrochemical data, indicate
that fluids are derived from three main end members. The dominant component is a relatively recent local meteoric water; the
second one is marine water; and the third one is a fossil freshwater, depleted in heavy isotopes with respect to modern rains.
The latter end member entered the aquifer system in the past, when climatic conditions were greatly different from today.
At least two circulation systems can be recognised, namely a shallow cold system and a deep hydrothermal system, as well as
two distinct hydrological processes: (1) gravity-controlled descent of cold water towards greater depths and (2) convection
linked to a thermal gradient, causing deep fluids to rise up from the hydrothermal reservoir towards the surface. The highly
variable δ13CTDIC values suggest the presence of two distinct CO2 sources, namely, a biogenic one and a thermogenic one. The relation between the isotopic compositions of CO2 and He indicates an increased mantle signature in uprising CO2-rich fluids. 相似文献
993.
Dynamic data integration for structural modeling: model screening approach using a distance-based model parameterization 总被引:2,自引:0,他引:2
This paper proposes a novel history-matching method where reservoir structure is inverted from dynamic fluid flow response.
The proposed workflow consists of searching for models that match production history from a large set of prior structural
model realizations. This prior set represents the reservoir structural uncertainty because of interpretation uncertainty on
seismic sections. To make such a search effective, we introduce a parameter space defined with a “similarity distance” for
accommodating this large set of realizations. The inverse solutions are found using a stochastic search method. Realistic
reservoir examples are presented to prove the applicability of the proposed method. 相似文献
994.
We simulate direct current (DC) borehole resistivity measurements acquired in steel-cased deviated wells for the assessment
of rock formation properties. The assumed data acquisition configuration considers one current (emitter) and three voltage
(collector) electrodes that are utilized to measure the second difference of the electric potential along the well trajectory.
We assume a homogeneous, 1.27-cm-thick steel casing with resistivity equal to 10 − 5 Ω· m. Simulations are performed with two different numerical methodologies. The first one is based on transferring two-dimensional
(2D) axisymmetric optimal grids to a three-dimensional (3D) simulation software. The second one automatically produces optimal
3D grids yielded by a 3D self-adaptive goal-oriented algorithm. Both methodologies utilize high-order finite elements (FE)
that are specially well-suited for problems with high-contrast coefficients and rapid spatial variations of the electric field,
as it occurs in simulations that involve steel-cased wells. The method based on transferring 2D-optimal grids is efficient
in terms of CPU time (few seconds per logging position). Unfortunately, it may produce inaccurate 3D simulations in deviated
wells, even though the error remains below 1% for the axisymmetric (vertical) well. The method based on optimal 3D grids,
although less efficient in terms of CPU time (few hours per logging position), produces more accurate results that are validated
by a built-in a posteriori error estimator. This paper provides the first existing simulations of through-casing resistivity
measurements in deviated wells. Simulated resistivity measurements indicate that, for a 30° deviated well, measurements in
conductive layers 0.01 Ω· m) are similar to those obtained in vertical wells. However, in resistive layers (10,000 Ω· m),
we observe 100% larger readings in the 30° deviated well. This difference becomes 3,000% for the case of a 60° deviated well.
For this highly-deviated well, readings corresponding to the conductive formation layer are about 30% smaller in magnitude
than those in a vertical well. Shoulder effects significantly vary in deviated wells. 相似文献
995.
Analyses of 72 samples from Upper Panjhara basin in the northern part of Deccan Plateau, India, indicate that geochemical
incongruity of groundwater is largely a function of mineral composition of the basaltic lithology. Higher proportion of alkaline
earth elements to total cations and HCO3>Cl + SO4 reflect weathering of primary silicates as chief source of ions. Inputs of Cl, SO4, and NO3 are related to rainfall and localized anthropogenic factors. Groundwater from recharge area representing Ca + Mg–HCO3 type progressively evolves to Ca + Na–HCO3 and Na–Ca–HCO3 class along flow direction replicates the role of cation exchange and precipitation processes. While the post-monsoon chemistry
is controlled by silicate mineral dissolution + cation exchange reactions, pre-monsoon variability is attributable chiefly
to precipitation reactions + anthropogenic factors. Positive correlations between Mg vs HCO3 and Ca + Mg vs HCO3 supports selective dissolution of olivine and pyroxene as dominant process in post-monsoon followed by dissolution of plagioclase
feldspar and secondary carbonates. The pre-monsoon data however, points toward the dissolution of plagioclase and precipitation
of CaCO3 supported by improved correlation coefficients between Na + Ca vs HCO3 and negative correlation of Ca vs HCO3, respectively. It is proposed that the eccentricity in the composition of groundwater from the Panjhara basin is a function
of selective dissolution of olivine > pyroxene followed by plagioclase feldspar.
The data suggest siallitization (L < R and R
k) as dominant mechanism of chemical weathering of basalts, stimulating monosiallitic (kaolinite) and bisiallitic (montmorillonite)
products. The chemical denudation rates for Panjhara basin worked out separately for the ground and surface water component
range from 6.98 to 36.65 tons/km2/yr, respectively. The values of the CO2 consumption rates range between 0.18 × 106 mol//km2/yr (groundwater) and 0.9 × 106 mol/km2/yr (surface water), which indicates that the groundwater forms a considerable fraction of CO2 consumption, an inference, that is, not taken into contemplation in most of the studies. 相似文献
996.
A multi-lithology diffusive stratigraphic model is considered, which simulates at large scales in space and time the infill
of sedimentary basins governed by the interaction between tectonics displacements, eustatic variations, sediment supply, and
sediment transport laws. The model accounts for the mass conservation of each sediment lithology resulting in a mixed parabolic,
hyperbolic system of partial differential equations (PDEs) for the lithology concentrations and the sediment thickness. It
also takes into account a limit on the rock alteration velocity modeled as a unilaterality constraint. To obtain a robust,
fast, and accurate simulation, fully and semi-implicit finite volume discre tization schemes are derived for which the existence
of stable solutions is proved. Then, the set of nonlinear equations is solved using a Newton algorithm adapted to the unilaterality
constraint, and preconditioning strategies are defined for the solution of the linear system at each Newton iteration. They
are based on an algebraic approximate decoupling of the sediment thickness and the concentration variables as well as on a
proper preconditioning of each variable. These algorithms are studied and compared in terms of robustness, scalability, and
efficiency on two real basin test cases. 相似文献
997.
We propose a methodology, called multilevel local–global (MLLG) upscaling, for generating accurate upscaled models of permeabilities
or transmissibilities for flow simulation on adapted grids in heterogeneous subsurface formations. The method generates an
initial adapted grid based on the given fine-scale reservoir heterogeneity and potential flow paths. It then applies local–global
(LG) upscaling for permeability or transmissibility [7], along with adaptivity, in an iterative manner. In each iteration of MLLG, the grid can be adapted where needed to reduce
flow solver and upscaling errors. The adaptivity is controlled with a flow-based indicator. The iterative process is continued
until consistency between the global solve on the adapted grid and the local solves is obtained. While each application of
LG upscaling is also an iterative process, this inner iteration generally takes only one or two iterations to converge. Furthermore,
the number of outer iterations is bounded above, and hence, the computational costs of this approach are low. We design a
new flow-based weighting of transmissibility values in LG upscaling that significantly improves the accuracy of LG and MLLG
over traditional local transmissibility calculations. For highly heterogeneous (e.g., channelized) systems, the integration
of grid adaptivity and LG upscaling is shown to consistently provide more accurate coarse-scale models for global flow, relative
to reference fine-scale results, than do existing upscaling techniques applied to uniform grids of similar densities. Another
attractive property of the integration of upscaling and adaptivity is that process dependency is strongly reduced, that is,
the approach computes accurate global flow results also for flows driven by boundary conditions different from the generic
boundary conditions used to compute the upscaled parameters. The method is demonstrated on Cartesian cell-based anisotropic
refinement (CCAR) grids, but it can be applied to other adaptation strategies for structured grids and extended to unstructured
grids. 相似文献
998.
Environmental tracers as indicators of karst conduits in groundwater in South Dakota,USA 总被引:3,自引:1,他引:2
Environmental tracers sampled from the carbonate Madison aquifer on the eastern flank of the Black Hills, South Dakota, USA indicated the approximate locations of four major karst conduits. Contamination issues are a major concern because these conduits are characterized by direct connections to sinking streams, high groundwater velocities, and proximity to public water supplies. Objectives of the study were to estimate approximate conduit locations and assess possible anthropogenic influences associated with conduits. Anomalies of young groundwater based on chlorofluorocarbons (CFCs), tritium, and electrical conductivity (EC) indicated fast moving, focused flow and thus the likely presence of conduits. δ18O was useful for determining sources of recharge for each conduit, and nitrate was a useful tracer for assessing flow paths for anthropogenic influences. Two of the four conduits terminate at or near a large spring complex. CFC apparent ages ranged from 15 years near conduits to >50 years in other areas. Nitrate-N concentrations >0.4 mg/L in groundwater were associated with each of the four conduits compared with concentrations ranging from <0.1 to 0.4 mg/L in other areas. These higher nitrate-N concentrations probably do not result from sinking streams but rather from other areas of infiltration. 相似文献
999.
Estimating groundwater evapotranspiration rates using diurnal water-table fluctuations in a semi-arid riparian zone 总被引:2,自引:1,他引:1
Laura K. Lautz 《Hydrogeology Journal》2008,16(3):483-497
In semi-arid climates, phreatophytes draw on shallow aquifers, and groundwater evapotranspiration (ETG) is a principal component of groundwater budgets. Diurnal water table fluctuations, which often are a product of ETG, were monitored in the riparian zone of Red Canyon Creek, Wyoming, USA. These fluctuations were higher in a riparian wetland (2–36 mm) than a grass-covered meadow (1–6 mm). The onset and cessation of water-table fluctuations correspond to daily temperatures relative to freezing. Spatial differences were due to vegetation type and specific yield, while temporal changes were due to vegetation dormancy. Ratios of ETG to potential evapotranspiration (PET), K c,GW, were similar to ratios of actual evapotranspiration (ET) to PET, K c, in semi-arid rangelands. Before vegetation senescence, K c,GW increased between precipitation events, suggesting phreatophytes pull more water from the saturated zone as soil moisture decreases. In contrast, K c decreases with soil moisture following precipitation events as ET becomes increasingly water-limited. Error in ETG is primarily from estimates of specific yield (S y), which is difficult to quantify in heterogeneous sediments. ETG values may be more reliable because the range of acceptable S y is smaller than K c and S y does not change with vegetation type or soil moisture. 相似文献
1000.
Although there are many numerical applications used in aquifer management, few methodologies seem to be sufficiently adapted
to provide solutions for regional-scale problems. Their applications for multilayered aquifers are also too limited. A new
groundwater management tool adapted to such large physical systems has been developed, using the unit response function (URF)
approach. This tool is based on the link between a numerical groundwater flow model and a mathematical optimisation tool.
Pre- and post processing are based on a geographical information system (GIS). The developed tool has been applied to a real
management case—the regional Aquitaine multilayered aquifer (France). A representative hydrodynamic model was built using
MODFLOW 2000 code. First tests show that the linearity condition needed for the application of URF methodology is respected
despite the high complexity of the system. Two management scenarios were tested. Optimal solutions thus obtained allow for
viable exploitation alternatives to be proposed, which integrate complex environmental constraints.
Résumé Malgré un nombre important d’applications existant dans le domaine de la gestion des aquifères, peu de méthodologies semblent adaptées pour proposer des solutions à des problèmes réels de dimension régionale. Leurs application pour des systèmes multicouches sont souvent trop limitées. Un outil de gestion adapté à ces systèmes de large taille a été développé, basé sur la théorie des Fonctions de Réponses Unitaires (FRU). Cet outil est basé sur le couplage d’un modèle numérique d’écoulement et d’un code d’optimisation mathématique. Les entrées et sorties du modèle sont réalisées à l’aide d’un Système d’Information Géographique (SIG). L’outil développé est appliqué à un cas de gestion réel—le système aquifère régional multicouche aquitain (France). Un modèle hydrodynamique représentatif a été construit, basé sur le code MODFLOW 2000. Les premiers tests montrent que les conditions de linéarité nécessaires à l’application de la méthode FRU sont respectées, malgré l’importante complexité du système. Deux scénarii de gestion sont testés. Les solutions optimales ainsi obtenues permettent de proposer des solutions d’exploitation alternatives viables, intégrant des contraintes environnementales complexes.
Resumen Aunque hay muchas aplicaciones numéricas usadas en la gestión de acuíferos, unas pocas metodologías parecen estar adaptadas suficientemente para dar las soluciones a los problemas de escala regional. También son limitadas sus aplicaciones para los acuíferos multicapa. Se ha desarrollado una nueva herramienta para el manejo del agua subterránea, adaptada a tales sistemas físicos grandes, usando el avance de la Función de Respuesta Unitaria (URF). Esta herramienta se basa en la combinación entre un modelo numérico de flujo de agua subterránea y una herramienta de optimización matemática. El pre-proceso y el post-proceso se basan en un Sistema de Información Geográfico (GIS). La herramienta desarrollada se ha aplicado a un caso real de manejo en el acuífero regional multicapa de Aquitania (Francia). Se construyó un modelo hidrodinámico representativo, que usó el código MODFLOW 2000. Las primeras pruebas muestran que la condición de linearidad, necesaria para la aplicación de la metodología URF, se respeta a pesar de la complejidad alta del sistema. Se probaron dos escenarios de manejo. Las soluciones óptimas así obtenidas permiten la proyección de alternativas viables de explotación, las cuales integran restricciones medioambientales complejas.相似文献