Export Production in the Subarctic North Pacific over the Last 800 kyrs: No Evidence for Iron Fertilization?

The subarctic North Pacific is a high nitrate-low chlorophyll (HNLC) region, where phytoplankton growth rates, especially those of diatoms, are enhanced when micronutrient Fe is added. Accordingly, it has been suggested that glacial Fe-laden dust might have increased primary production in this region. This paper reviews published palaeoceanographic records of export production over the last 800 kyrs from the open North Pacific (north of ∼35°N). We find different patterns of export production change over time in the various domains of the North Pacific (NW and NE subarctic gyres, the marginal seas and the transition zone). However, there is no compelling evidence for an overall increase in productivity during glacials in the subarctic region, challenging the paradigm that dust-born Fe fertilization of this region has contributed to the glacial draw down of atmospheric CO₂. Potential reasons for the lack of increased glacial export production include the possibility that Fe-fertilization rapidly drives the ecosystem towards limitation by another nutrient. This effect would have been exacerbated by an even more stable mixed layer compared to today. This revised version was published online in July 2006 with corrections to the Cover Date.     

Non-biological fractionation of stable Ca isotopes in soils of the Atacama Desert, Chile

We measured Ca stable isotope ratios (δ^44/40Ca) in an ancient (2 My), hyperarid soil where the primary source of mobile Ca is atmospheric deposition. Most of the Ca in the upper meter of this soil (3.5 kmol m⁻²) is present as sulfates (2.5 kmol m⁻²), and to a lesser extent carbonates (0.4 kmol m⁻²). In aqueous extracts of variably hydrated calcium sulfate minerals, δ^44/40Ca_E values (vs. bulk Earth) increase with depth (1.4 m) from a minimum of −1.91‰ to a maximum of +0.59‰. The trend in carbonate-δ^44/40Ca in the top six horizons resembles that of sulfate-δ^44/40Ca, but with values 0.1-0.6‰ higher. The range of observed Ca isotope values in this soil is about half that of δ^44/40Ca values observed on Earth. Linear correlation among δ^44/40Ca, δ³⁴S and δ¹⁸O values indicates either (a) a simultaneous change in atmospheric input values for all three elements over time, or (b) isotopic fractionation of all three elements during downward transport. We present evidence that the latter is the primary cause of the isotopic variation that we observe. Sulfate-δ³⁴S values are positively correlated with sulfate-δ¹⁸O values (R² = 0.78) and negatively correlated with sulfate δ^44/40Ca_E values (R² = 0.70). If constant fractionation and conservation of mass with downward transport are assumed, these relationships indicate a δ^44/40Ca fractionation factor of −0.4‰ in CaSO₄. The overall depth trend in Ca isotopes is reproduced by a model of isotopic fractionation during downward Ca transport that considers small and infrequent but regularly recurring rainfall events. Near surface low Ca isotope values are reproduced by a Rayleigh model derived from measured Ca concentrations and the Ca fractionation factor predicted by the relationship with S isotopes. This indicates that the primary mechanism of stable isotope fractionation in CaSO₄ is incremental and effectively irreversible removal of an isotopically enriched dissolved phase by downward transport during small rainfall events.     

On the origin of tunnel valleys of the Saginaw Lobe of the Laurentide Ice Sheet; Michigan,USA

Tunnel valleys are common throughout the terrain of the Saginaw Lobe of the Laurentide Ice Sheet in southern Michigan. The set of valleys described in this paper is regularly spaced in a radial pattern behind the Kalamazoo Moraine, an ice‐marginal position formed during retreat from the Last Glacial Maximum. These valleys are divided into proximal and distal groups lying north and south, respectively, of a major river valley that cross‐cuts the tunnel valleys at right angles. Based on a series of rotasonic borings and core analysis, the proximal valleys are shallow, contain minimal sediment fill, and overlie fine‐grained diamicton and glaciolacustrine sediment, whereas the distal valleys are deeply incised into the substrate and are partially filled with coarse sediment. The distal valleys terminate within a broad zone of high‐relief, hummocky topography representing stagnation and collapse behind the Kalamazoo ice margin. The proximal valleys occur within a more subdued landscape located farther from the ice margin. Although some elements of existing genetic models are consistent with these valleys, none appears to be completely compatible with their stratigraphy and morphology. Initial incision of the valleys could have involved short‐lived moderate‐ to high‐discharge flows, followed by deposition during or after the events. The deep incision and thick, coarse sediment in distal valleys in the stagnant marginal zone probably involved supraglacial meltwater draining to the bed as the margin downwasted. Fining‐upward eskers inset into the valleys were formed by flows of declining energy in small late‐stage conduits.     

Estimating source regions for snowmelt runoff in a Rocky Mountain basin: tests of a data‐based conceptual modeling approach

In many mountain basins, river discharge measurements are located far away from runoff source areas. This study tests whether a basic snowmelt runoff conceptual model can be used to estimate relative contributions of different elevation zones to basin‐scale discharge in the Cache la Poudre, a snowmelt‐dominated Rocky Mountain river. Model tests evaluate scenarios that vary model configuration, input variables, and parameter values to determine how these factors affect discharge simulation and the distribution of runoff generation with elevation. Results show that the model simulates basin discharge well (NSCE and R >0.90) when input precipitation and temperature are distributed with different lapse rates, with a rain‐snow threshold parameter between 0 and 3.3 °C, and with a melt rate parameter between 2 and 4 mm °C^?1 d^?1 because these variables and parameters can have compensating interactions with each other and with the runoff coefficient parameter. Only the hydrograph recession parameter can be uniquely defined with this model structure. These non‐unique model scenarios with different configurations, input variables, and parameter values all indicate that the majority of basin discharge comes from elevations above 2900 m, or less than 25% of the basin total area, with a steep increase in runoff generation above 2600 m. However, the simulations produce unrealistically low runoff ratios for elevations above 3000 m, highlighting the need for additional measurements of snow and discharge at under‐sampled elevations to evaluate the accuracy of simulated snow and runoff patterns. Copyright © 2013 John Wiley & Sons, Ltd.     

Phase composition and radiation stability of matrices for isolation of REE-actinide waste

Doklady Earth Sciences -     

Mineralogy, geochemistry and petrogenesis of the recent magmatic formations from Mbengwi, a continental sector of the Cameroon Volcanic Line (CVL), Central Africa

The Mbengwi recent magmatic formations consist of volcanics and syenites belonging to the same magmatic episode. Lavas form a bimodal basanite-rhyolite alkaline series with a gap between 50 and 62?wt.% SiO₂. Mafic lavas (basanite-hawaiite) are sodic while felsic rocks (trachyte-rhyolite-syenites) are sodi-potassic, slightly metaluminous to peralkaline. The geochemical and isotopic characteristics (0.7031?<?(⁸⁷Sr/⁸⁶Sr)_initial?<?0.7043; 1.03?<?ε_Ndi?<?5.17) of these rocks are similar to those of other rocks from the CVL. The main differentiation process is fractional crystallization with two trends of fractionation. Their Rb/Sr isochron age of 28.2?Ma, almost similar to 27.40?±?0.6?Ma?K/Ar age obtained in a trachyte from neighboring Bamenda Mountains system, precludes any local age migration of an hypothetic hotspot. Mafic lavas have OIB features displaying an isotopic signature similar to that of HIMU mantle source different from FOZO known as source of most parental magmas along the CVL.     

Chandra X-ray observations of two unusual BAL quasars

We report sensitive Chandra X-ray non-detections of two unusual, luminous Iron Low-Ionization Broad Absorption Line Quasars (FeLoBALs). The observations do detect a non-BAL, wide-binary companion quasar to one of the FeLoBAL quasars. We combine X-ray-derived column density lower limits (assuming solar metallicity) with column densities measured from ultraviolet spectra and CLOUDY photoionization simulations to explore whether constant-density slabs at broad-line region densities can match the physical parameters of these two BAL outflows, and find that they cannot. In the “overlapping-trough” object SDSS J0300+0048, we measure the column density of the X-ray absorbing gas to be N_H ? 1.8 × 10²⁴ cm^?2. From the presence of Fe ii UV78 absorption but lack of Fe ii UV195/UV196 absorption, we infer the density in that part of the absorbing region to be n_e ? 10⁶ cm^?3. We do find that a slab of gas at that density might be able to explain this object’s absorption. In the Fe iii-dominant object SDSS J2215–0045, the X-ray absorbing column density of N_H ? 3.4 × 10²⁴ cm^?2 is consistent with the Fe iii-derived N_H ? 2 × 10²² cm^?2 provided the ionization parameter is log U > 1.0 for both the n_e = 10¹¹ cm^?3 and n_e = 10¹² cm^?3 scenarios considered (such densities are required to produce Fe iii absorption without Fe iiabsorption). However, the velocity width of the absorption rules out its being concentrated in a single slab at these densities. Instead, this object’s spectrum can be explained by a low density, high ionization and high temperature disk wind that encounters and ablates higher density, lower ionization Fe iii-emitting clumps.