Isotopic evidence for the magmatic and tectonic histories of the Carolina terrane: implications for stratigraphy and terrane affiliation

Establishing the age and crustal nature of exotic terranes and their underlying basements helps to determine their paleogeographic origin and tectonic histories. We present U–Pb ages of zircons and Sm–Nd whole rock isotopic data for volcanic and plutonic rocks of the Carolina terrane, one of several peri-Gondwanan terranes that were accreted to the margins of the circum-Atlantic continents during the Paleozoic. Volcanism in this subduction-related arc culminated in the eruption of the Morrow Mountain rhyolite, at ca. 540 Ma; thus, magmatism in the Carolina terrane ceased at the beginning of the Cambrian. The presence of inherited zircons and non-juvenile depleted mantle model ages of Carolina slate belt rocks favor a basement that is, at least in part, composed of evolved continental crust. Ages of inherited xenocrystic zircons cluster at ca. 1000, 2100 and 2500 Ma. These ages, in addition to volcanism at ca. 618–540 Ma, correlate best with well-known tectonic events in present-day northern South America. Specifically, the Orinoquian-Sunsas, the Trans-Amazonian and the Central Amazonian orogenic zones are likely candidates for potential basement correlatives to the Carolina terrane. Sm–Nd isotopic signatures vary significantly, but permit assimilation of Orinoquian age (1000 Ma) crust by magmas derived from the depleted mantle in a subduction (arc-related) setting. Our findings are also consistent with proposed correlations between the Carolina terrane and Avalonia which is likewise believed to have formed along the northern margin of present-day South America.     

Evaluating TCE Abiotic and Biotic Degradation Pathways in a Permeable Reactive Barrier Using Compound Specific Isotope Analysis

A pilot‐scale zero valent iron (ZVI) Permeable Reactive Barrier (PRB) was installed using an azimuth‐controlled ‐vertical hydrofracturing at an industrial facility to treat a chlorinated Volatile Organic Compound (VOC) plume. Following ZVI injection, no significant reduction in concentration was observed to occur with the exception of some multilevel monitoring wells, which also showed high levels of total organic carbon (TOC). These patterns suggested that the zero valent iron was not well distributed in the PRB creating leaky conditions. The geochemical data indicated reducing conditions in these areas where VOC reduction was observed, suggesting that biotic processes, associated to the guar used in the injection of the iron, could be a major mechanism of VOC degradation. Compound‐Specific Isotope Analysis (CSIA) using both carbon and chlorine stable isotopes were used as a complementary tool for evaluating the contribution of abiotic and biotic processes to VOC trends in the vicinity of the PRB. The isotopic data showed enriched isotope values around the PRB compared to the isotope composition of the VOC source confirming that VOC degradation is occurring along the PRB. A batch experiment using site groundwater collected near the VOC source and the ZVI used in the PRB was performed to evaluate the site‐specific abiotic isotopic fractionation patterns. Field isotopic trends, typical of biodegradations were observed at the site and were different from those obtained during the batch abiotic experiment. These differences in isotopic trends combined with changes in VOC concentrations and redox parameters suggested that biotic processes are the predominant pathways involved in the degradation of VOCs in the vicinity of the PRB.     

Geochemical tracers to evaluate hydrogeologic controls on river salinization

The salinization of rivers, as indicated by salinity increases in the downstream direction, is characteristic of arid and semiarid regions throughout the world. Historically, salinity increases have been attributed to various mechanisms, including (1) evaporation and concentration during reservoir storage, irrigation, and subsequent reuse; (2) displacement of shallow saline ground water during irrigation; (3) erosion and dissolution of natural deposits; and/or (4) inflow of deep saline and/or geothermal ground water (ground water with elevated water temperature). In this study, investigation of salinity issues focused on identification of relative salinity contributions from anthropogenic and natural sources in the Lower Rio Grande in the New Mexico-Texas border region. Based on the conceptual model of the system, the various sources of water and, therefore, salinity to the Lower Rio Grande were identified, and a sampling plan was designed to characterize these sources. Analysis results for boron (delta(11)B), sulfur (delta(34)S), oxygen (delta(18)O), hydrogen (delta(2)H), and strontium ((87)Sr/(86)Sr) isotopes, as well as basic chemical data, confirmed the hypothesis that the dominant salinity contributions are from deep ground water inflow to the Rio Grande. The stable isotopic ratios identified the deep ground water inflow as distinctive, with characteristic isotopic signatures. These analyses indicate that it is not possible to reproduce the observed salinization by evapotranspiration and agricultural processes alone. This investigation further confirms that proper application of multiple isotopic and geochemical tracers can be used to identify and constrain multiple sources of solutes in complex river systems.     

Glacier reconstruction and mass‐balance modelling as a geomorphic and palaeoclimatic tool

The reconstruction of former mountain glaciers has long been used to examine the implications of rapid climate shifts, for example at the last glacial–interglacial transition, and for evaluating asynchronous behaviour of mountain glaciers compared with mid‐latitude ice sheets during the Late Quaternary. Glacier reconstruction has also been used as a source of palaeoclimatic information, based on the recognition of empirical relationships between glaciers and climate. This paper reviews the application and implications of a recently revised method of glacier reconstruction (Carr and Coleman, 2007 ), based around glaciological principles of mass‐balance. This study examines how this approach can be used to test geomorphological interpretations of former mountain glaciation and also to infer precipitation fields at sites of former glaciation. Sites of Younger Dryas niche and icefield glaciation in the British Isles demonstrate how this method can verify interpretations of marginal glaciation and begin to understand the different behaviour of outlet glaciers within the same environmental regime. Examination of a site of former niche glaciation in Southern Africa demonstrates how glacier reconstruction may be used to infer annual and seasonal precipitation values and strongly supports the idea that winter precipitation in Lesotho and SE South Africa was substantially greater than present‐day values during the last glacial cycle. Copyright © 2010 John Wiley & Sons, Ltd.     

Water isotopic composition traces source and dynamics of water supply in a semi-arid agricultural landscape

Changes in seasonality and form of precipitation alter the structure and function of grassland and steppe ecosystems and pose challenges for land management and crop production in regions like the Northern Great Plains, North America. This research uses isotopic composition of water (δ¹⁸O and δ²H) to explore the sources and fate of soil water in lower-elevation agricultural areas of the Judith River watershed, in the headwaters of the Missouri River, USA. Extensive non-irrigated cereal crop production in this area occurs on well-drained soils and depends on careful water management. Our observations indicate that colder precipitation contributes isotopically distinct water to cultivated terrace soils relative to downgradient groundwaters and streams. Riparian waters also exhibit a higher fraction of contributions from colder precipitation relative to terrace groundwaters and streams. Apparent contributions from colder precipitation in terrace and riparian soil waters suggest that snowmelt is a key component of the water supply to these systems. Riparian waters also show evidence of evaporation suggesting that water spends sufficient time in some ponds and open channels in the riparian corridor to reflect fractionation by evaporation. The evolution of water isotopic composition from soils to shallow aquifers to stream corridors indicates source water partitioning as precipitation moves through this semi-arid agricultural landscape. The apparent mixing processes evident in this evolution reveal source water dynamics that are necessary to understand plant transpiration, solute processing, and contaminant leaching processes.     

The global martian volcanic evolutionary history

Viking mission image data revealed the total spatial extent of preserved volcanic surface on Mars. One of the dominating surface expressions is Olympus Mons and the surrounding volcanic province Tharsis. Earlier studies of the global volcanic sequence of events based on stratigraphic relationships and crater count statistics were limited to the image resolution of the Viking orbiter camera. Here, a global investigation based on high-resolution image data gathered by the High-Resolution Stereo Camera (HRSC) during the first years of Mars Express orbiting around Mars is presented. Additionally, Mars Orbiter Camera (MOC) and Thermal Emission Imaging System (THEMIS) images were used for more detailed and complementary information. The results reveal global volcanism during the Noachian period (>3.7 Ga) followed by more focused vent volcanism in three (Tharsis, Elysium, and Circum-Hellas) and later two (Tharsis and Elysium) volcanic provinces. Finally, the volcanic activity became localized to the Tharsis region (about 1.6 Ga ago), where volcanism was active until very recently (200-100 Ma). These age results were expected from radiometric dating of martian meteorites but now verified for extended geological units, mainly found in the Tharsis Montes surroundings, showing prolonged volcanism for more than 3.5 billions years. The volcanic activity on Mars appears episodic, but decaying in intensity and localizing in space. The spatial and temporal extent of martian volcanism based on crater count statistics now provides a much better database for modelling the thermodynamic evolution of Mars.     

UV observations of macrospicules at the solar limb

During the Spacelab 2 mission, the NRL High Resolution Telescope and Spectrograph (HRTS) obtained a time-series of broad-band ultraviolet images of macrospicules at the solar limb inside a polar coronal hole with a temporal resolution of 20 and 60 s. The properties of the macrospicules observed in the Spacelab data are measured and compared with the properties reported for EUV macrospicules observed during Skylab (Bohlin et al., 1975; Withbroe et al., 1976). There is a general agreement between the data sets but several differences. Because of the higher temporal resolution of the Spacelab data, it is possible to see macrospicules with shorter lifetimes than seen during Skylab, as well as variations on faster timescales. The largest (30–60) and fastest (150 km s ^-1) macrospicules seen during Skylab were not found in the Spacelab observations. The Spacelab data support the conclusion that many macrospicules decay by simply fading away.     

Rhyolites at Kerlingarfjöll, Iceland: the evolution and lifespan of silicic central volcanoes

Kerlingarfjöll central volcano is Iceland’s second largest outcrop of Quaternary rhyolite and is part of the Icelandic Western Rift Zone. Geochemical and Ar/Ar age data show that at least 21 different rhyolite eruptions have taken place at Kerlingarfjöll over the last 350 ka. Ar/Ar dating was carried out on samples of obsidian which showed variable reproducibility, illustrating the difficulty in dating young Icelandic volcanics. Nevertheless, reasonable estimates of eruption age have been derived for a number of eruptive units that are consistent with observed stratigraphy, enabling an understanding of the temporal evolution of Kerlingarfjöll. Two rhyolite magma types are present. The first is an older, low-Nb rhyolite that was erupted episodically along a cryptic curved fracture system, to form a discontinuous ring of rhyolite mountains, between 350 and 250 ka. This discontinuous ring is similar to structures observed at other volcanoes in Iceland, suggesting that the development of a curved fracture that acts as a pathway for episodic silicic eruptions is a feature of central volcano development. The second magma is a younger, high-Nb rhyolite that was erupted episodically between 250 and 68 ka in the northern part of Kerlingarfjöll, forming two clusters, both of which have areas of intense hydrothermal activity. Repose periods for rhyolite volcanism are thought to be on the order of tens of thousands of years, and it is possible that Kerlingarfjöll will erupt rhyolite again in the future.