High-resolution CASSINI-VIMS mosaics of Titan and the icy Saturnian satellites

The Visual Infrared Mapping Spectrometer (VIMS) onboard the CASSINI spacecraft obtained new spectral data of the icy satellites of Saturn after its arrival at Saturn in June 2004. VIMS operates in a spectral range from 0.35 to 5.2 μm, generating image cubes in which each pixel represents a spectrum consisting of 352 contiguous wavebands.As an imaging spectrometer VIMS combines the characteristics of both a spectrometer and an imaging instrument. This makes it possible to analyze the spectrum of each pixel separately and to map the spectral characteristics spatially, which is important to study the relationships between spectral information and geological and geomorphologic surface features.The spatial analysis of the spectral data requires the determination of the exact geographic position of each pixel on the specific surface and that all 352 spectral elements of each pixel show the same region of the target. We developed a method to reproject each pixel geometrically and to convert the spectral data into map projected image cubes. This method can also be applied to mosaic different VIMS observations. Based on these mosaics, maps of the spectral properties for each Saturnian satellite can be derived and attributed to geographic positions as well as to geological and geomorphologic surface features. These map-projected mosaics are the basis for all further investigations.     

A combined IR and XRD study of natural well crystalline goethites (α-FeOOH)

Acta Geochimica - Goethite (α-FeOOH) is one of the most abundant minerals on the Earth surface, occurring in temperate, tropical and equatorial climates. Fe in goethite can be substituted by...     

Detrital thermochronologic record of burial heating and sediment recycling in the Magallanes foreland basin,Patagonian Andes

The Patagonian Magallanes retroarc foreland basin affords an excellent case study of sediment burial recycling within a thrust belt setting. We report combined detrital zircon U–Pb geochronology and (U–Th)/He thermochronology data and thermal modelling results that confirm delivery of both rapidly cooled, first‐cycle volcanogenic sediments from the Patagonian magmatic arc and recycled sediment from deeply buried and exhumed Cretaceous foredeep strata to the Cenozoic depocentre of the Patagonian Magallanes basin. We have quantified the magnitude of Eocene heating with thermal models that simultaneously forward model detrital zircon (U–Th)/He dates for best‐fit thermal histories. Our results indicate that 54–45 Ma burial of the Maastrichtian Dorotea Formation produced 164–180 °C conditions and heating to within the zircon He partial retention zone. Such deep burial is unusual for Andean foreland basins and may have resulted from combined effects of high basal heat flow and high sediment accumulation within a rapidly subsiding foredeep that was floored by basement weakened by previous Late Jurassic rifting. In this interpretation, Cenozoic thrust‐related deformation deeply eroded the Dorotea Formation from ca. 5 km burial depths and may be responsible for the development of a basin‐wide Palaeogene unconformity. Results from the Cenozoic Río Turbio and Santa Cruz formations confirm that they contain both Cenozoic first‐cycle zircon from the Patagonian magmatic arc and highly outgassed zircon recycled from older basin strata that experienced burial histories similar to those of the Dorotea Formation.     

Geoacoustic inversion of broad-band acoustic data in shallow water on a single hydrophone

The inversion of broad-band low-frequency acoustic signals received on sparse arrays can lead to robust and efficient estimations of sea-bed properties. This paper describes a shallow-water geoacoustic inversion scheme based on the use of a model-based matched-impulse response on a single hydrophone. Results from the INTIMATE'96 experiment on the Portuguese shelf break are reviewed. In order to minimize the effects of strong time variability due to internal tides, only the time-stable waterborne bottom-surface reflected arrivals are exploited. A quasi-linear inversion algorithm is first applied to refine the geometry of the experiment. Then, inversion of bottom parameters is performed with an objective function that only makes use of the bottom-surface reflected arrivals' amplitudes. The experimental results show that broad-band transmissions (300-800 Hz) received on a single hydrophone, combined with the use of a simple eigenray code, are sufficient to correctly resolve geometrical parameters and bottom features. The analysis of the reflection coefficients both on simulated and real data helps to understand the validity of the inverted parameters and to derive the basis of an equivalent medium concept for geoacoustic inversion based on a "through-the-sensor" approach.     

Nanotopography of synthetic and natural dolomite crystals

Examination with scanning electron microscopy (SEM) and scanning force microscopy (SFM) revealed etch pits, layers and islands on dolomite crystal faces synthesized from calcite in Ca‐Mg‐Cl solutions at 200 °C and a wide variety of natural dolomites. Layers are broad, flat structures bounded by steps less than 100 nm high and greater than 1 μm wide. Islands are rounded topographic highs <20 nm high and <200 nm wide. The nanotopography of synthetic dolomite changed from islands throughout most of the reaction to layers at 100% dolomite. Island nanotopography formed on both Ca‐rich and near‐stoichiometric dolomite. Analyses of reaction products from dolomite synthesis indicates that there are no SFM‐detectable products formed in <10 h. SEM‐detectable products formed in 15 h. X‐ray diffraction (XRD)‐detectable products formed in ≈18 h, and the reaction went to completion in ≈40 h. Based on SFM analyses, the induction period for dolomitization in these experiments accounts for ≈20% of the total reaction time necessary to dolomitize CaCO₃ completely under the experimental conditions used here. Island nano‐ topography is inferred to occur at higher degrees of supersaturation than layer nanotopography for three reasons. First, island nanotopography on synthetic calcite and gypsum forms at higher supersaturations than layer nanotopography. Secondly, island nanotopography formed in solutions with higher degrees of supersaturation with respect to dolomite. Thirdly, the greater surface roughness of a crystal face composed of islands compared with layers indicates that island surfaces have higher surface energy than layer surfaces. Therefore, the stability of island surfaces requires a higher degree of supersaturation. Because islands and layers form under a wide range of conditions, their presence provides broadly applicable criteria for evaluating relative degrees of supersaturation under which ancient dolomite formed. Comparison of synthetic dolomites with natural dolomites demonstrates (1) similar nanotopography on natural and synthetic dolomites and (2) both natural planar and non‐planar dolomite may have island nanotopography.     

Multiproxy Analyses of Stratigraphy and Palaeoenvironment of the Late Palaeolithic Grabow Floodplain Site,Northern Germany

Changing river courses and fluctuations of the water table were some of the most fundamental environmental changes that humans faced during the Late Glacial, particularly as these changes affected areas intensively used for settlement and resource exploitation. Unfortunately, only a few stratigraphies have been documented in the North European plain that show the interaction between river development, vegetation history, and occupation by Late Palaeolithic humans. Here, we present the results of detailed stratigraphical studies (pedology, archaeology, chrono‐, tephra‐, and palynostratigraphy) at the Federmesser site Grabow 15 located in the broad Elbe River valley. The research aimed to produce a model of site formation based on a multiproxy approach, relating the local evidence to the palaeoenvironmental and settlement history of the wider region. After deposition of fluvial sands during the Late Pleniglacial in a braided setting, the river course developed locally toward a meandering system at the transition from the Older Dryas to the Allerød, while periodic flooding led to the deposition of floodplain sediments during the early Allerød. The floodplain was settled by people of the earliest “Federmessergruppen,” who are believed to have chosen this open floodplain area along the river for collecting and processing amber of local origin. Their artifacts became embedded in the aggrading floodplain sediments. In the late Allerød, floodplain sedimentation ceased and a Fluvisol‐type soil developed, indicating a trend toward geomorphic stability. The Fluvisol was then covered by silty floodplain sediments due to a rising water level during the late Younger Dryas resulting in the cessation of human occupation in the area. Subsequent organic‐rich Late Glacial/Holocene sediments preserved the settlement remains to the present.