Determination of deployment specific chemical uptake rates for SPMD and PDMS using a passive flow monitor

Passive sampling techniques facilitate the time-integrated measurement of pollutant concentrations through the use of a selective receiving phase. Accurate quantification using passive sampling devices rely on the implementation of methods that will negate the effects of environmental factors (flow, temperature, etc.) or that will allow the calculation of the chemical specific rates of uptake (R(s)) into the passive sampler employed. We have applied an in situ calibration technique based on the dissolution of gypsum to measure the average water velocity to which a sampler has been exposed. We demonstrate that the loss of gypsum from the passive flow monitor (PFM) can be applied to predict changes in R(s) dependent on flow when using the absorbent SPMD (semipermeable membrane device) and PDMS (polydimethyl siloxan) passive samplers. The application of the PFM will enhance the accuracy of measurements made when calculating and reporting environmental pollutant concentrations using a passive sampling device.     

Subglacial emplacement of tills and meltwater deposits at the base of overdeepened bedrock troughs

The sedimentary infills of subglacially eroded bedrock troughs in the Alps are underexplored archives for the timing, extent and character of Pleistocene glaciations but may contain excellent records of the Quaternary landscape evolution over several glacial–interglacial cycles. The onset of sedimentation in these bedrock troughs is often reflected by diamicts and gravels directly overlying bedrock in the deepest basin segments. Subglacial or proglacial depositional environments have been proposed for these coarse‐grained basal units but their characteristics and origin remain controversial. This article presents results from drill cores that recovered a coarse‐grained basal unit in a major buried bedrock‐trough system in the Lower Glatt Valley, northern Switzerland. The excellent core recovery allowed a detailed study combining macroscopic, microscopic and geochemical methods and gives unprecedented insights into the transition from erosion to deposition in overdeepened bedrock troughs. These results show that the basal infill comprises diamicts, interpreted as subglacial tills, separated by thin sorted interbeds, originating from subglacial cavity deposition. The stacking of these units is interpreted to represent repeated switching between a coupled and decoupled ice–bed‐interface indicating an ever‐transforming mosaic of subglacial bed conditions. Decoupling in response to high basal water pressures is probably promoted by the confined subglacial hydraulic conditions resulting from the bedrock acting as aquitards, the narrow reverse sloping outlet and a large catchment area. While stratigraphic and lithological evidence suggests that erosion and the onset of basal sedimentation occurred during the same glaciation, different scenarios for the relative timing of infilling in relation to formation and glaciation of the bedrock trough are discussed. Overlying deltaic and glaciolacustrine sediments suggest deposition during subsequent deglaciation of the bedrock trough. The basal sediment characteristics are in agreement with previous reports in hydrogeological and seismic exploration and suggest the occurrence of similar basal successions in other subglacially overdeepened basins in the Alps and elsewhere.     

Diachronous isotopic and sedimentary responses to topographic change as indicators of mid‐Eocene hydrologic reorganization in the western United States

Early Cenozoic terrestrial deposits in the western United States represent well‐preserved archives of climatic and tectonic processes that together shaped the Earth's surface during the demise of a large continental plateau. This study examines a Cenozoic terrestrial sedimentary sequence in the central part of the Cordilleran orogen (Montana) using sedimentologic and geochemical techniques. At ～49 Ma, we observe rapid major shifts in oxygen, carbon and strontium isotope records that are too large to directly reflect changes in meteoric water composition due to simple orographic rainout. The transition to low‐δ¹⁸O values in pedogenic carbonate in concert with changes in the composition of clastic material at ～49 Ma points to the input of evolved meteoric water to the hydrological cycle due to a change in the source of waters reaching Cordilleran intermontane regions in southwestern Montana. This drainage reorganization coincides with the initiation of magmatism and extension to the west in what is now Montana and Idaho. The sedimentological record shows evidence that depositional gradients increased in the study area ～46 Ma, ～3 Myr after the drainage reorganization occurred. This interval is most likely the time it took for extensional deformation to propagate to the study area itself. Evidence of freshening events in Laramide Basins to the southeast suggests that this drainage reorganization diverted waters to progressively fill these basins and highlights the impact of post‐plateau extension‐related landscape reorganization on river networks and lake dynamics. This study also emphasizes the importance of using multiple tools in deciphering topographic history through the study of terrestrial basin deposits, in that interpretation based on any single method employed would have compromised our ability to successfully identify the regional evolution of topography and drainage networks.     

Predisposition and cause of the catastrophic landslides of August 2005 in Brienz (Switzerland)

Very intensive rainfall in August 2005 (>300 mm/3 days) triggered moderately deep (2–10 m) landslides of about 50'000 m³ volume each in two mountain torrent catchments above the village of Brienz (Berner Oberland, Switzerland). These landslides – originating in Trachtbach and Glyssibach catchments – transformed into extremely rapid (>5 m/s) debris flows, which caused significant damage in inhabited areas; two persons lost their lives and about twenty-five families became homeless. The Brienz case was the most damaging one among many landslide disasters occurring during those rainy days in the Swiss Alps. In this paper we study in detail the predisposition and causes of the 2005 landslides in the Brienz area, based on field mapping, analysis of high resolution images and digital terrain models, derived from LIDAR and infrared measurements taken before and after the event. The features of these landslides are compared with past and dormant landslides in the mid-slope portion of the mountain chain north of Brienz, which has been the source of many catastrophic mass wasting events during the last centuries. Detailed field mapping shows that highly weathered series of strongly overconsolidated Mesozoic marls (Diphyoides Limestone & Vitznau Marls of Valanginian age) and their residual soils form the primary source for the sliding materials. The rupture surfaces of the moderately deep landslides often run at the transition from saprolite to weathered bedrock, with a dip angle of about 40o in the landslide depletion area. These landslides transform into debris flows, where debris slides into strongly convergent hillslopes or directly into headwater channels.     

Developing service-oriented applications in a grid environment

The Open-source Project for a Network Data Access Protocol (OPeNDAP) software framework has evolved over the last 10 years to become a robust, high performance, service oriented architecture for the access and transport of scientific data from a broad variety of disciplines, over the Internet. Starting with version 4.0 of the server release, Hyrax, has at its core, the Back-End Server (BES). The BES offers ease of programming, extensibility and reliability allowing added functionality especially related to high-performance data Grids, that goes beyond its original goal of distributed data access. We present the fundamentals of the BES server as a component based architecture, as well as our experiences using the BES to distribute data processing in Grid-oriented intensive parallel computational tasks.     

Directed movements in probabilistic time geography

This article studies probabilistic time geography for space–time prisms, that is, for situations where observers know the location of an agent at one time and then again at another time. In the intervening period, the agent would have moved freely, according to its time budget. The article demonstrates that the probability of finding the agent somewhere in the space–time prism is not equally distributed, so any attempt of a quantitative time geographic analysis must consider the actual probability distribution. This article develops, implements, and demonstrates this distribution. A preceding article introduced probabilistic time geography for space–time cones. With cones and prisms, the elementary space–time volumes of time geography are provided.     

Induced seismicity during the construction of the Gotthard Base Tunnel, Switzerland: hypocenter locations and source dimensions

A series of 112 earthquakes was recorded between October 2005 and August 2007 during the excavation of the MFS Faido, the southernmost access point of the new Gotthard Base Tunnel. Earthquakes were recorded at a dense network of 11 stations, including 2 stations in the tunnel. Local magnitudes computed from Wood?CAnderson-filtered horizontal component seismograms ranged from ?1.0 to 2.4; the largest earthquake was strongly felt at the surface and caused considerable damage in the tunnel. Hypocenter locations obtained routinely using a regional 3-D P-wave velocity model and a constant Vp/Vs ratio 1.71 were about 2?km below the tunnel. The use of seismic velocities calibrated from a shot in the tunnel revealed that routinely obtained hypocenter locations were systematically biased to greater depth and are now relocated to be on the tunnel level. Relocation of the shot using these calibrated velocities yields a location accuracy of 25?m in longitude, 70?m in latitude, and 250?m in focal depth. Double-difference relative relocations of two clusters with highly similar waveforms showed a NW?CSE striking trend that is consistent with the strike of mapped faults in the MFS Faido. Source dimensions computed using the quasidynamic model of Madariaga (Bull Seismo Soc Am 66(3):639?C666, 1976) range from 50 to 170?m. Overlapping source dimensions for earthquakes within the two main clusters suggests that the same fault patch was ruptured repeatedly. The observed seismicity was likely caused by stress redistribution due to the excavation work in the MFS Faido.     

Archeoseismic study of damage in Roman and Medieval structures in the center of Cologne, Germany

The causes of damage observed in archeological records or preserved monuments are often difficult to be determined unequivocally, particularly when the possibility of secondary earthquake damage exists. Such secondary damage has been previously proposed for the Roman Praetorium, the governor’s palace in the center of Cologne. Ongoing excavations since 2007 revealed additional damage. The existing ground that has been uncovered and documented extends the affected area to 175?×?180 m. We present a comprehensive virtual model of the excavation area based on 200 3D laserscans together with a systematic analysis of the damage patterns and an improved model of the terrain during Roman/Medieval times including geotechnical parameters of the subsurface. Five locations with different damage patterns, including a Roman sewer, the octagonal central part of the Praetorium, a section with strongly inclined massive walls, a 13 m deep deformed well, a collapsed hypocaust, and damages in the Medieval mikveh are analyzed in detail. We use site-specific synthetic strong ground motion seismograms to test the possibility of earthquake-induced ground failures as a cause for the observed damage. This subsurface model is also used to test the possibility of hydraulically-induced damages by seepage and erosion of fine-grained material from stray sand. Heavy rainstorms can induce a direct stream of surface water through the fine sand layers to the ground water table. Simulated ground motion for assumed worst-case earthquake scenarios do not provoke slope instability at the level necessary to explain the structural damages.