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181.
Diagenetic effects on the distribution of uranium in live and Holocene corals from the Gulf of Aqaba
Boaz Lazar Rivka Enmar Miriam Bar-Matthews Mordechai Stein 《Geochimica et cosmochimica acta》2004,68(22):4583-4593
We investigated the effects of diagenetic alteration (dissolution, secondary aragonite precipitation and pore filling) on the distribution of U in live and Holocene coral skeletons. For this, we drilled into large Porites lutea coral-heads growing in the Nature Reserve Reef (NRR), northern Gulf of Aqaba, a site close to the Marine Biology Laboratory, Elat, Israel, and sampled the core material and porewater from the drill-hole. In addition, we sampled Holocene corals and beachrock aragonite cements from a pit opened in a reef buried under the laboratory grounds. We measured the concentration and isotopic composition of U in the coral skeletal aragonite, aragonite cements, coral porewater and open NRR and Gulf of Aqaba waters.Uranium concentration in secondary aragonite filling the skeletal pores is significantly higher than in primary biogenic aragonite (17.3 ± 0.6 compared to 11.9 ± 0.3 nmol · g−1, respectively). This concentration difference reflects the closed system incorporation of uranyl tri-carbonate into biogenic aragonite with a U/Ca bulk distribution coefficient (KD) of unity, versus the open system incorporation into secondary aragonite with KD of 2.4. The implication of this result is that continuous precipitation of secondary aragonite over ∼1000 yr of reef submergence would reduce the coral porosity by 5% and can produce an apparent lowering of the calculated U/Ca - SST by ∼1°C and apparent age rejuvenation effect of 7%, with no measurable effect on the calculated initial U isotopic composition.All modern and some Holocene corals (with and without aragonite cement) from Elat yielded uniform δ234U = 144 ± 5, similar to the Gulf of Aqaba and modern ocean values. Elevated δ234U values of ∼180 were measured only in mid-Holocene corals (∼5000 yr) from the buried reef. The values can reflect the interaction of the coral skeleton with 234U-enriched ground-seawater that washes the adjacent granitic basement rocks.We conclude that pore filling by secondary aragonite during reef submergence can produce small but measurable effects on the U/Ca thermometry and the U-Th ages. This emphasizes the critical importance of using pristine corals where the original mineralogy and porosity are preserved in paleooceanographic tracing and dating. 相似文献
182.
Summary Re–Os molybdenite ages from the exocontact of the Hnilec granite-greisen body provide temporal constraints for tin, tungsten
and molybdenite mineralisation in the Gemeric Superunit, Slovakia. Two molybdenite separates were taken from a representative
sample of the Sn–W–Mo mineralisation at Hnilec and their Re–Os ages of 262.2 ± 0.9 and 263.8 ± 0.8 Ma (2-sigma) are in excellent
agreement. The obtained Re–Os molybdenite ages are similar to recent but less precise electron microprobe monazite (276 ±
13 Ma) and U–Pb single zircon (250 ± 18 Ma) ages from the Hnilec granite intrusion, supporting a granite-related greisen origin
for the Sn–W–Mo mineralisation. Our precise Re–Os molybdenite ages resolve the long time controversy over the timing of high-temperature
mineralisation in the Gemeric Superunit. These Permian ages eliminate suggestions of an Alpine age. The sulphur isotope composition
of the studied molybdenite is δ34S(CDT) = 1.71 ± 0.2‰ and is consistent with a magmatic sulphur source. Field observations indicate the lack of a broad contact aureole
in the vicinity of the Hnilec granite body. Shallow level granite emplacement in schistose host rocks was accompanied by alteration
and formation of tin-tungsten greisen in the upper part of the granite and exocontact molybdenite mineralisation, both commonly
lacking in other granite bodies within the Gemeric Superunit. 相似文献
183.
The Vaikijaur Cu–Au–(Mo) deposit is located in the ca. 1.88 Ga calc-alkaline Jokkmokk granitoid near the Archaean–Proterozoic
palaeoboundary within the Fennoscandian shield of northern Sweden. The Skellefte VMS district lies immediately to the south
and the northern Norrbotten Fe-oxide–Cu–Au deposits to the north. The Vaikijaur deposit occupies an area of 2×3 km within
the Jokkmokk granitoid and includes stockwork quartz-sulphide veinlets and disseminated chalcopyrite, pyrite, gold, molybdenite,
magnetite, and pyrrhotite. Porphyritic mafic dykes were emplaced along fractures in a ring dyke pattern. The Jokkmokk granitoid,
dykes, and the mineralized area are foliated, indicating that mineralization predated the main regional deformation. The mineralized
area is characterized by strong potassic alteration. Phyllic and propylitic alteration zones are also present. A pyrite-rich
inner core is surrounded by a concentric zone with pyrite, chalcopyrite, and gold. Molybdenite is distributed irregularly
throughout the chalcopyrite zone. Geophysical data indicate a strongly conductive central zone in the mineralized area bordered
by conductive and high magnetic zones. Five high precision Re–Os age determinations for three molybdenite occurrences from
outcrop and drill core samples constrain the age of porphyry-style Cu–Au–(Mo) mineralization to between 1889±10 and 1868±6 Ma.
A younger molybdenite is associated with a much later metamorphic event at about 1750 Ma. These data suggest that primary
porphyry-style mineralization was associated with calc-alkaline magmatism within the Archaean–Proterozoic boundary zone at
ca. 1.89–1.87 Ga. 相似文献
184.
The December 26, 2004 Sumatra earthquake and the tsunami that followed killed over 300,000 people. In this paper, we analyze and discuss the geologic causes for this earthquake, the mechanisms that generated it, and follow up with a discussion on ways to prevent this type of disaster in the future. 相似文献
185.
Lithospheric structure of the Tornquist Zone resolved by nonlinear P and S teleseismic tomography along the TOR array 总被引:1,自引:1,他引:1
Z. Hossein Shomali Roland G. Roberts Laust B. Pedersen the TOR Working Group 《Tectonophysics》2006,416(1-4):133
The main aim of the TOR project is to study the lithospheric–asthenospheric boundary structure under the Sorgenfrei–Tornquist Zone, across northern Germany, Denmark and southern Sweden. Relative arrival-time residuals of teleseismic P and S phases from 51 earthquakes, recorded by 150 seismic stations along the TOR array, were used to delineate the transition zone in the studied area. The effects of crustal structures were investigated by correcting the teleseismic residuals for travel-time variations in the crust based on a 3D crustal model derived from other data. The inversion was carried out for S phases. The results were then compared with the corresponding P-wave models. As expected, the derived models show that the relatively old and cold Baltic Shield has higher velocity at depth than the younger lithosphere farther South. The models show two sharp and distinct increases in depth to velocities which are low compared to our reference model, as we move from South to North. The location and sharpness of these boundaries suggests that the features resolved are, at least partially, compositional in origin, presumably related to mantle depletion. A sharp and steep subcrustal boundary is found roughly coincident with the southern edge of Sweden. This is below where the edge of the Baltic Shield is usually placed, based on surface geological evidence (the Sorgenfrei–Tornquist Zone). Another less significant transition is recognised more or less beneath the Elbe-lineament. Relatively high d(Vp / Vs) ratios under the central part of the profile (Denmark) indicate relatively low S-velocity in an area where a gravity high supports the hypothesis of extensive mafic intrusions. 相似文献
186.
Eyjafjallajökull volcano, located in southern Iceland, is characterized by its quiet nature. Only about a handful of earthquakes associated with the volcanic system had been detected prior to the 1990s. Earthquake swarms did, however, occur in 1994 and 1999. Here we investigate the spatio-temporal evolution of a magmatic intrusion associated with the 1999 earthquake swarm via analysis of produced surface deformation. A series of interferometric synthetic aperture radar (InSAR) images, spanning various periods of the intrusion, show that in 1999 surface deformation occurred mainly on the southern flanks of the volcano. The deformation amounts to more than 20 cm of range change. Inverse modeling resolves the deformation source to be a sill intrusion at 6.3 km depth. Sill opening was up to 1 m and the total intruded volume amounts to ~0.03 km3. The InSAR data display a migration of the center of deformation through time, enabling us to create time-dependant sill-opening models. Furthermore, we investigate the spatio-temporal distribution of earthquakes and find that the distribution supports the InSAR derived model and additionally provides indications for a possible site of a feeder channel. Magmatic flow-rate estimates indicate an initial intrusion rate of 4–6 m3/s, declining over a few weeks. 相似文献
187.
震后地形变与孔隙压力瞬态变化的相互关系 总被引:1,自引:0,他引:1
大震改变地壳的应力,从而触发地震及其余震。一系列随时间变化的过程,包括余滑、孔隙流体的流动、下地壳和上地幔粘性的张驰、断层附近应力和孔隙压力调整以及地震的触发进程。然而,尽管进行过多次尝试,但通过直接场地的观测,很难将这些过程区分开来。这里我们采用一种星载雷达干涉图和冰岛南部地震带两个6.5级地震地热井水位变化过程结合的测量法。干涉图记录到的形变既不能用余滑也不能用粘-弹性张驰来解释,但它与地震发生后最初两个月孔隙弹性物质的回跳一致,这可以用地震引起水位变化的快速恢复(1—2个月)来证实,相反余震序列的持续时间达到3.5年,这表明余震的持续时间并不是由孔隙流体的流动控制的,但是,因为表面应变是由地壳浅部孔隙压力的变化控制的,因此,我们不能排除在余震发生深度存在较长时间的孔隙压力瞬态变化。余震的持续时间与随速度和状态变化的摩擦定律控制的地震活动变化速率模型是一致的。 相似文献
188.
D.W. Graham L.M. Larsen B.B. Hanan M. Storey A.K. Pedersen J.E. Lupton 《Earth and Planetary Science Letters》1998,160(3-4):241-255
Picrites from the 61 million year old Vaigat Formation of the Nuussuaq Peninsula in West Greenland have 3He/4He ratios trapped in olivine phenocrysts which range up to 30 times the atmospheric ratio. These high values, measured during gas extraction by crushing in vacuum, are similar to the highest magmatic 3He/4He ratios found in young terrestrial volcanic rocks. By analogy with young basalts, in which crushing selectively extracts magmatic helium, any significant cosmogenic 3He appears to be absent in these picrites. Additional evidence for the absence of cosmogenic helium is provided by fusion results on the crushed olivine powders and by a single stepwise crushing experiment, in which only magmatic and radiogenic helium components are resolvable. The West Greenland picrites have Pb, Nd and Sr isotope compositions which overlap those found in picrites from Iceland and in basalts from Loihi Seamount, localities which today also have high 3He/4He ratios. Isotopic variations in He, Pb, Nd and Sr for the West Greenland picrites are interpreted to largely result from interaction of the early Iceland mantle plume with the upper mantle during plume ascent and dispersion beneath the continental lithosphere. The presence of high 3He/4He ratios in West Greenland, and the onset of magmatism across the North Atlantic Volcanic Province near 62 Ma, supports the hypothesis for very rapid dispersion (>1 m/year) of mantle plume head material during the earliest stages of plume impact, as predicted in recent numerical simulations of plume behavior during thermal mantle convection with non-Newtonian rheology. 相似文献
189.
Seven 187Re-187Os ages were determined for molybdenite and pyrite samples from two well-dated Precambrian intrusions in Fennoscandia to examine
the sustainability of the Re-Os chronometer in a metamorphic and metasomatic setting. Using a new 187Re decay constant (1.666 × 10−11y−1) with a much improved uncertainty (±0.31%), we determined replicate Re-Os ages for molybdenite and pyrite from the Kuittila
and Kivisuo prospects in easternmost Finland and for molybdenite from the Kabeliai prospect in southernmost Lithuania. These
two localities contain some of the oldest and youngest plutonic activity in Fennoscandia and are associated with newly discovered
economic Au mineralization (Ilomantsi, Finland) and a Cu-Mo prospect (Kabeliai, Lithuania). Two Re-Os ages for vein-hosted
Kabeliai molybdenite average 1486 ± 5 Ma, in excellent agreement with a 1505 ± 11 Ma U-Pb zircon age for the hosting Kabeliai
granite pluton. The slightly younger age suggests the introduction of Cu-Mo mineralization by a later phase of the Kabeliai
magmatic system. Mean Re-Os ages of 2778 ± 8 Ma and 2781 ± 8 Ma for Kuittila and Kivisuo molybdenites, respectively, are in
reasonable agreement with a 2753 ± 5 Ma weighted mean U-Pb zircon age for hosting Kuittila tonalite. These Re-Os ages agree
well with less precise ages of 2789 ± 290 Ma for a Rb-Sr whole-rock isochron and 2771 ± 75 Ma for the average of six Sm-Nd
TDM model ages for Kuittila tonalite. Three Re-Os analyses of a single pyrite mineral separate, from the same sample of Kuittila
pluton that yielded a molybdenite separate, provide individual model ages of 2710 ± 27, 2777 ± 28, and 2830 ± 28 Ma (Re = 17.4,
12.1, and 8.4 ppb, respectively), with a mean value of 2770 ± 120 Ma in agreement with the Kuittila molybdenite age. The Re
and 187Os abundances in these three pyrite splits are highly correlated (r = 0.9994), and provide a 187Re-187Os isochron age of 2607 ± 47 Ma with an intercept of 21 ppt 187Os (MSWD = 1.1). It appears that the Re-Os isotopic system in pyrite has been reset on the millimeter scale and that the 21 ppt 187Os intercept reflects the in situ decay of 187Re during the ∼160 to 170 m.y. interval from ∼2778 Ma (time of molybdenite ± pyrite deposition) to ∼2607 Ma (time of pyrite
resetting). When the Re-Os data for molybdenites from the nearby Kivisuo prospect are plotted together with the Kuittila molybdenite
and pyrite data, a well-constrained five-point isochron with an age of 2780 ± 8 Ma and a 187Os intercept (−2.4 ± 3.8 ppt) of essentially zero results (MSWD = 1.5). We suggest that the pyrite isochron age records a
regional metamorphic and/or hydrothermal event, possibly the time of Au mineralization. A proposed Re-Os age of ∼2607 Ma for
Au mineralization is in good agreement with radiometric ages by other methods that address the timing of Archean Au mineralization
in deposits worldwide (so-called “late Au model”). Molybdenite, in contrast, provides a robust Re-Os chronometer, retaining
its original formation age of ∼2780 Ma, despite subsequent metamorphic disturbances in Archean and Proterozoic time.
Received: 25 September 1996 / Accepted: 27 August 1997 相似文献
190.
Elisabeth Kastellet Atle Nesje & Einar Solheim Pedersen 《Geografiska Annaler: Series A, Physical Geography》1998,80(1):51-65
Documentary data provide long time series and sometimes high-resolution, detailed data from historical times to the present and can give valuable information about palaeoclimate, and for the prediction of future climates. In this paper, documentary data containing qualitative information on climate, in the form of a diary written by the farmer I.G. Grude, and two newspapers, were used for the reconstruction of the palaeoclimate at Jæren, in the county of Rogaland, in southwestern Norway, during the period 1821–50. An index method to quantify the qualitative climate data was developed and used for a low-resolution reconstruction of winter, summer and annual temperatures. A high-resolution climate reconstruction of temperature and precipitation for the winter of 1837/38 is also presented, making use of a method that keeps the climate data in a qualitative form. The climate reconstructions are compared to an instrumental temperature series from Bergen, for the same period. The two data sets are in good agreement except for summer temperature (annual temperature: r = 0.75, winter temperature: r = 0.77, summer temperature: r = 0.44). Compared to average temperatures during 1961–90, the instrumental data from Bergen during the 1821–50 period show slightly different temperatures: annual average was 0.3°C lower, winter 0.4°C lower, and summer 0.1°C lower than at present, implying conditions consistent with the "Little Ice Age" climate. 相似文献