Polarized electronic absorption spectra of synthetic (Mg,Fe)-orthopyroxenes,ferrosilite and Fe3+-bearing ferrosilite

The assignment of spin-allowed Fe²⁺-bands in orthopyroxene electronic absorption spectra is revised by studying synthetic bronzite (Mg_0.8 Fe_0.2)₂Si₂O₆, hypersthene (Mg_0.5 Fe_0.5)₂Si₂O₆ and ferrosilite (Fe₂Si₂O₆). Reheating of bronzite and hypersthene single crystals causes a redistribution of the Fe²⁺-ions over the M1 and M2 octahedra, which was determined by Mössbauer spectroscopy and correlated to the intensity change of the spin-allowed Fe²⁺ d-d bands in the polarized absorption spectra. The 11000 cm^-1 band is caused by Fe²⁺ in M1 (⁵B_2g→⁵A_1g) and Fe²⁺ in M2 (⁵A₁→⁵A₁), the 8500 cm^-1 band by Fe²⁺ in M1 (⁵B_2g→⁵B_1g) and the 5000 cm^-1 band by Fe²⁺ in M2 octahedra (⁵A₁→⁵B₁). The Fe²⁺-Fe³⁺ charge transfer band is identified at 12500cm^-1 in the spectra of synthetic Fe³⁺ -Al bearing ferrosilite. This band shows a strong γ-polarization and therefore is caused by Fe²⁺ -Fe³⁺-ions in edge-sharing octahedra.     

P-T-X conditions of hydrothermal fluids and precipitation mechanism of stibnite-gold mineralization at the Wiluna lode-gold deposits,Western Australia: conventional and infrared microthermometric constraints

The Wiluna lode-gold deposits are located in the Archean Wiluna greenstone belt, in the northern sector of the Norseman-Wiluna belt in the Yilgarn Craton of Western Australia. They are hosted in subgreenschist facies meta-basalts, and controlled by the Wiluna strike-slip fault system and associated shear veins and breccias. The 13 individual lode-gold deposits have produced around 115 t Au from 1901 to 1946 and 1986 to today. Historically, they also produced 38.3 t As and 3.5 t Sb. Gold formed in two stages: stage 1 gold-pyrite-arsenopyrite is finely disseminated in the wallrock and breccia fragments, whereas stage 2 gold-stibnite is located in massive shear veins and breccia matrix, as fracture-fill and in banded-colloform textured veins. Stibnite-gold orebodies only occur in some of the deposits (e.g., Moonlight and northern part of the West Lode) and also display a restricted vertical extent, being preserved only in the uppermost 200 m of stibnite-bearing lodes.Petrographic, conventional, and infrared microthermometric and laser-Raman analysis on stibnite-bearing quartz veins and breccias reveal that the antimony- and gold-rich hydrothermal fluid was of mixed H₂O-NaCl-CO₂±CH₄ type. Microthermometric measurements reveal maximum homogenization temperatures of 340 °C (average 290±25 °C), and a wide range of salinities between 0.2 and 23 eq. wt% NaCl. Aqueous-carbonic fluid inclusions contain variable X_CO2+CH4 (0.03 to 0.82), with the carbonic phase containing a maximum X_CH4 of 0.21.Combined petrographic and microthermometric evidence suggests that the fluid inclusion properties reflect fluid immiscibility of a low-salinity, medium X_CO2+CH4, homogeneous parent fluid at about 290 °C and pressures between 700 and 1,700 bar. Fluid immiscibility was triggered by cyclic pressure release during fault-zone movement. The decompression (adiabatic cooling) of the hydrothermal fluids shifted the ore fluid to lower temperatures, significantly reduced the degree of stibnite undersaturation, and caused stibnite to precipitate. The deposition of stibnite reduced the ore-fluid H₂S concentration, thereby destabilized gold bisulfide complexes in solution, and caused gold precipitation locally. This mechanism explains the intimate spatial association of stibnite and gold in quartz veins and breccias in the stibnite-gold orebodies at Wiluna.Editorial handling: B. Lehmann     

内蒙巴丹吉林沙漠成因的粒度分析和热发光测年新证据

巴丹吉林沙漠位于中国内蒙古自治区的西部,是中国第三大沙漠。过去通常认为该沙漠中沙丘的可能沙源来自附近的各种沉积物和岩石,包括弱水河扇的沉积物,弱固结的二叠纪页岩、白垩纪砂岩和砾岩以及戈壁阿尔泰的古老岩石。根据对风成砂的粒度观测,有证据表明在沙漠内部的风成砂沉积朝东南方向具有较弱的但又确实的变细趋势。这与沙丘横脊线的SW-NE向排列以及坡面的南东指向是一致的。因此,可以认为西北部的弱水河冲积扇是巴丹吉林沙漠风成砂的最可能的沙源。在西北部风成床沙覆盖了较老弱水河扇起源的冲积物。这种沉积物的热发光测年范围在190～100 ka BP之间。由于测量中对沉积物漂白可能不完全以及对其中平均古水含量估算均存在不确定性,同时由于对沙漠该地区风成作用开始之前堆积的沉积物进行了测年,这一数据范围代表了最大的年龄。另外三个风成砂测年结果分别接近133.66和22 ka,代表有关巴丹吉林沙漠西北部风成作用开始的最小年龄。沙漠的沙丘高度平均为200～300m,但在东南部偶尔可达450m。一些学者曾提出风成床沙覆盖了一个陡峭岛山突起的假说,来解释这些异常的空间。本次研究发现,在研究区之下是一个产状水平的白垩纪扇砾岩和砂岩的台地,可以断定在沙漠东南部呈现台地地貌,但进一步向北该台地明显延伸到这些沙丘之下。因此现在可以认为巴丹吉林沙漠中高的沙丘是不同区域气候和地貌因素相互作用的结果,而不是覆盖一个陡峭的岛山突起。对弱水河冲积扇作为巴丹吉林沙漠的主要源区的证实强调区域环境的重要性。在全新世,沿河流的绿洲植被在某种程度上阻碍了冲积扇提供沙源。现在,河西走廊的农业用水量极大地危及沿河森林,因此沿着作为天然拦沙阱的弱水河,维持足够的河水流量来保护区域性密集的沙丘植被,一定会避免具有重大威胁的沙的活动性增加。     

Direct 40Ar/39Ar K‐feldspar dating of Late Permian—Early Triassic brittle faulting in northern Norway

While the offshore post‐Caledonian extensional history of the north Norwegian passive margin is well constrained, the tectonic relationship between onshore and offshore regions is less clear because of limited age constraints on the timing of rifting onshore. ⁴⁰Ar/³⁹Ar dating of K‐feldspar from hydrothermally altered fault rocks in a Precambrian gneiss complex in northern Norway was used to study the timing of extensional faulting onshore. In addition, ⁴⁰Ar/³⁹Ar dating of K‐feldspar from the host rock provided insight into the regional rock cooling history prior to brittle deformation. Results indicated a dominant Late Permian–Early Triassic (~265–244 Ma) faulting event and found no evidence for later reactivation, which has been documented offshore. The region cooled to below the closure temperature for ⁴⁰Ar/³⁹Ar K‐feldspar in the Carboniferous to Early Permian, prior to the main brittle faulting event. ⁴⁰Ar/³⁹Ar dating of fault zone K‐feldspar products provided a means to date brittle faulting events.     

Nearshore circulation over transverse bar and rip morphology with oblique wave forcing

There is a paucity of field data to describe the transition in nearshore circulation between alongshore, meandering and rip current systems. A combination of in‐situ current meters and surf zone drifters are used to characterize the nearshore circulation over a transverse bar and rip morphology at Pensacola Beach, Florida in the presence of relatively low energy oblique waves. Current speeds vary in response to the relative wave height ratio (H_s/h), which defines the degree and extent of breaking over the shoal. In the absence of wave breaking the nearshore circulation was dominated by an alongshore current driven by the oblique waves. As waves begin to break across the shoal (0.2<H_s/ h<0.5) the nearshore circulation is characterized by a meandering alongshore current. As conditions became more dissipative (H_s/h>0.5), the meandering current is replaced by an unsteady rip circulation that moves offshore between the shoals before turning alongshore in the direction of wave advance outside the surf zone. The increase in wave dissipation is associated with an increase in very low frequency (VLF) variations in the current speed across the shoal and in the rip channel that caused the circulation to oscillate between an offshore and an alongshore flow. The unsteady nature of the nearshore circulation is responsible for 55% of all surf zone exits under these more dissipative conditions. In contrast, only 29% of the drifters released from the shoal exited the surf zone and bypassed the adjacent shoal with the alongshore‐meandering current. While the currents had a low velocity (maximum of ~0.4 m s^‐1) and would not pose a significant hazard to the average swimmer, the results of this study suggest that the transverse bar and rip morphology is sufficient to create an alongshore variation in wave dissipation that forces alongshore meandering and low‐energy rip circulation systems under oblique wave forcing. Copyright © 2013 John Wiley & Sons, Ltd.     

Holocene relative sea-level change, isostatic subsidence and the radial viscosity structure of the mantle of northwest Europe (Belgium, the Netherlands, Germany, southern North Sea)

A comprehensive observational database of Holocene relative sea-level (RSL) index points from northwest Europe (Belgium, the Netherlands, northwest Germany, southern North Sea) has been compiled in order to compare and reassess the data collected from the different countries/regions and by different workers on a common time–depth scale. RSL rise varies in magnitude and form between these regions, revealing a complex pattern of differential crustal movement which cannot be solely attributed to tectonic activity. It clearly contains a non-linear, glacio- and/or hydro-isostatic subsidence component, which is only small on the Belgian coastal plain but increases significantly to a value of ca 7.5 m relative to Belgium since 8 cal. ka BP along the northwest German coast. The subsidence is at least in part related to the Post-Glacial collapse of the so-called peripheral forebulge which developed around the Fennoscandian centre of ice loading during the Last Glacial Maximum. The RSL data have been compared to geodynamic Earth models in order to infer the radial viscosity structure of the Earth's mantle underneath NW Europe (lithosphere thickness, upper- and lower-mantle viscosity), and conversely to predict RSL in regions where we have only few observational data (e.g. in the southern North Sea). A very broad range of Earth parameters fit the Belgian RSL data, suggesting that glacial isostatic adjustment (GIA) only had a minor effect on Belgian crustal dynamics during and after the Last Ice Age. In contrast, a narrow range of Earth parameters define the southern North Sea region, reflecting the greater influence of GIA on these deeper/older samples. Modelled RSL data suggest that the zone of maximum forebulge subsidence runs in a relatively narrow, WNW–ESE trending band connecting the German federal state of Lower Saxony with the Dogger Bank area in the southern North Sea. Identification of the effects of local-scale factors such as past changes in tidal range or tectonic activity on the spatial and temporal variations of sea-level index points based on model-data comparisons is possible but is still complicated by the relatively large range of Earth model parameters fitting each RSL curve, emphasising the need for more high-quality observational data.     

Age constraints on felsic intrusions, metamorphism and gold mineralisation in the Palaeoproterozoic Rio Itapicuru greenstone belt, NE Bahia State, Brazil

U–Pb sensitive high resolution ion microprobe mass spectrometer (SHRIMP) ages of zircon, monazite and xenotime crystals from felsic intrusive rocks from the Rio Itapicuru greenstone belt show two development stages between 2,152 and 2,130 Ma, and between 2,130 and 2,080 Ma. The older intrusions yielded ages of 2,152±6 Ma in monazite crystals and 2,155±9 Ma in zircon crystals derived from the Trilhado granodiorite, and ages of 2,130±7 Ma and 2,128±8 Ma in zircon crystals derived from the Teofilândia tonalite. The emplacement age of the syntectonic Ambrósio dome as indicated by a 2,080±2-Ma xenotime age for a granite dyke probably marks the end of the felsic magmatism. This age shows good agreement with the Ar–Ar plateau age of 2,080±5 Ma obtained in hornblendes from an amphibolite and with a U–Pb SHRIMP age of 2,076±10 Ma in detrital zircon crystals from a quartzite, interpreted as the age of the peak of the metamorphism. The predominance of inherited zircons in the syntectonic Ambrósio dome suggests that the basement of the supracrustal rocks was composed of Archaean continental crust with components of 2,937±16, 3,111±13 and 3,162±13 Ma. Ar–Ar plateau ages of 2,050±4 Ma and 2,054±2 Ma on hydrothermal muscovite samples from the Fazenda Brasileiro gold deposit are interpreted as minimum ages for gold mineralisation and close to the true age of gold deposition. The Ar–Ar data indicate that the mineralisation must have occurred less than 30 million years after the peak of the metamorphism, or episodically between 2,080 Ma and 2,050 Ma, during uplift and exhumation of the orogen.Electronic supplementary material Supplementary material is available for this article at     

Early Holocene environmental history of sunken landscapes: pollen, plant macrofossil and geochemical analyses from the Borkum Riffgrund, southern North Sea

A vibrocore from the sea floor of the southern North Sea provides a ~1,500-year record of early Holocene vegetation history and mire development in a landscape now 33 m below sea-level. Pollen, plant macrofossil and geochemical analyses of an AMS ¹⁴C dated sand–peat–marine mud sequence document the paludification on Pleistocene sands ~10,700 cal BP, the subsequent development of eutraphentic carr vegetation and the gradual inundation by the transgressing sea ~9,350 cal BP. Pinus–Corylus woodland prevailed on terrestrial grounds after hazel had immigrated ~10,700 cal BP. Salix dominated the carr vegetation throughout 1,300 years of peat formation, because Alnus did not spread in the Borkum Riffgrund area until 9,300 BP. Brackish reed vegetation with Phragmites established after inundation and siliciclastic marine sediments were being deposited. This article also examines the detection and suitability of key horizons indicative of marine influence. XRF-Scanning provides the most detailed results in the briefest possible time to pinpoint spectra best suitable for AMS ¹⁴C dating of classical key horizons such as start of peat formation and transgressive contact. The combined application of botanical and geochemical methods allows determining new key horizons indicative of marine influence, namely the earliest marine inundation and the onset of sea-level influence on coastal ground water level.     

Luminescence dating of historical fluvial deposits from the Danube and Ebro

The validity of optically stimulated luminescence (OSL) has been tested on known‐age (historical) fluvial deposits along the rivers Danube (Austria) and Ebro (Spain). As partial bleaching of the OSL signal prior to deposition can interfere with correct age estimates, different approaches to extracting the dose accumulated during burial are compared. Using the finite mixture model gave OSL ages that are internally as well as stratigraphically consistent and in agreement with independent age control. According to these results, fluvial deposition at the Danube River study site can be attributed to different periods ranging from Bronze Age to the 18th century A.D. Fluvial deposits of Roman age and of the late 17th or early 18th century A.D. were found at the Ebro River study site. This is consistent with the morphological subdivision of the valleys and encourages further investigation of the fluvial and archaeological history of the study areas using OSL. © 2009 Wiley Periodicals, Inc.