Seasonal variability of soil phosphate stable oxygen isotopes in rainfall manipulation experiments

Phosphorus (P) availability limits productivity in many ecosystems worldwide. As a result, improved understanding of P cycling through soil and plants is much desirable. The use of the oxygen isotopes associated to phosphate can be used to study the cycle of P in terrestrial systems. However, changes with time in the oxygen isotopes associated to available P have not yet been evaluated under field conditions. Here we present the variations in available-P oxygen isotopes, based on resin extractions, in a semi-arid site that included plots in which the amount of rainfall reaching the soil was modified. In addition, the oxygen isotopes in the less dynamic fraction which is extractable by HCl, were also measured. The δ¹⁸O of the HCl-extractable phosphate shows no seasonal pattern and corresponds to the average value of the available phosphate of 16.5‰. This value is in the expected range for equilibration with soil water at the prevailing temperatures in the site. The δ¹⁸O values of resin-extractable P showed a range of 14.5-19.1‰ (SMOW), and evidence of seasonal variability, as well as variability induced by rainfall manipulation experiments. We present a framework for analyzing the isotopic ratios in soil phosphate and explain the variability as mainly driven by phosphate equilibration with soil water, and by the isotopic effects associated with extracellular mineralization. Additional isotopic effects result from fractionation in uptake, and the input to the soil of phosphate equilibrated in leaves. These results suggest that the δ¹⁸O of resin-extractable P is an interesting marker for the rate of biological P transformations in soil systems.     

Attenuation,source parameters and site effects in the Irpinia–Basilicata region (southern Apennines,Italy)

We derive S-wave attenuation characteristics, earthquake source parameters and site amplification functions at seismic stations used for earthquake early warning in the Irpinia–Basilicata region, using non-parametric spectral inversion of seismograms from 49 local events with M _L = 1.5–3.1. We obtain relatively low Q values (Q ₀ = 28 at a frequency of 1 Hz) in conjunction with a strong frequency-dependence (close to linear). The source spectra can be satisfactorily modeled using the omega-square model, with stress drops ranging between 0.01–2 MPa, and in the narrow magnitude range available for analysis, the source spectra seem to scale self-similarly. The local magnitude M _L shows a linear correlation with moment magnitude M _W, however with a systematic underestimation by about 0.5-magnitude units. The results obtained in this work provide important insights into the ground-motion characteristics that are required for appropriate seismic hazard assessment and are of practical relevance for a suite of applications, such as the calibration of ground-motion prediction equations or the correction for site amplification in earthquake early warning and rapid calculation of shake-maps for seismic emergency management.     

High precision tilt observation at Mt. Etna Volcano,Italy

In 2007–2008, we installed on Mt. Etna two deep tilt stations using high resolution, self-leveling instruments. These installations are a result of accurate instrument tests, site selection, drilling and sensor positioning that has allowed detecting variations related to the principal diurnal and semidiurnal tides for first time on Mt. Etna using tilt data.     

Reconstruction of the eruptive activity on the NE sector of Stromboli volcano: timing of flank eruptions since 15 ka

A multidisciplinary geological and compositional investigation allowed us to reconstruct the occurrence of flank eruptions on the lower NE flank of Stromboli volcano since 15 ka. The oldest flank eruption recognised is Roisa, which occurred at ~15 ka during the Vancori period, and has transitional compositional characteristics between the Vancori and Neostromboli phases. Roisa was followed by the San Vincenzo eruption that took place at ~12 ka during the early stage of Neostromboli period. The eruptive fissure of San Vincenzo gave rise to a large scoria cone located below the village of Stromboli, and generated a lava flow, most of which lies below sea level. Most of the flank eruptions outside the barren Sciara del Fuoco occurred in a short time, between ~9 and 7 ka during the Neostromboli period, when six eruptive events produced scoria cones, spatter ramparts and lava flows. The Neostromboli products belong to a potassic series (KS), and cluster in two differently evolved groups. After an eruptive pause of ~5,000 years, the most recent flank eruption involving the NE sector of the island occurred during the Recent Stromboli period with the formation of the large, highly K calc-alkaline lava flow field, named San Bartolo. The trend of eruptive fissures since 15 ka ranges from N30°E to N55°E, and corresponds to the magma intrusions radiating from the main feeding system of the volcano.     

Active folding along a rift-flank: The Catania region case history (SE Sicily)

In this paper a new kinematic and dynamic model on the Recent and active contractional deformation of the Catania region, eastern Sicily, is discussed. The study area represents one of the most seismically active region of the Mediterranean, located at the intersection between the front of the Sicily collision belt and the seismogenic Siculo-Calabrian Rift-Zone. The analysed contractional tectonics form an active triangle zone that originated from the tectonic inversion of a Lower-Middle Pleistocene extensional basin, which was located at the northern edge of the African foreland. The triangle zone consists of two antithetic ENE–WSW oriented thrust-ramps that show evidence of motion during the Holocene and bound a folded belt that involves alluvial deposits as young as 40 ka. These contractional structures represent the final product of the positive tectonic inversion of extensional features located, in the Hyblean Plateau in SE Sicily, along the flank of the active rift zone. The Late Quaternary motions along the inverted structures was accommodated to the west by a major N–S oriented left-lateral fault zone, which separates the active contractional domains from the adjacent sectors of the African margin. As a whole, the Late Quaternary contractional tectonics of SE Sicily have been related to a NW-verging crustal stacking, related to a Mantle intrusion beneath the Hyblean Plateau that developed as effect of the rift-flank deformation. The crustal lineaments, which compose the new kinematic model, represents potentially active seismogenic sources that might be considered in the frame of the seismotectonic picture of the Catania region.     

Cretaceous-Eocene compression in the central Southern Alps (N Italy) inferred from Ar/Ar dating of pseudotachylytes along regional thrust faults

The integration of structural analyses with ⁴⁰Ar/³⁹Ar dating of fault-related pseudotachylytes provides time constraints for the reconstruction of the Alpine evolution of the central portion of the South Alpine orogenic wedge. In the northern sector of the belt a Variscan basement is stacked southward on the Permian to Mesozoic cover along regional faults (Orobic and Porcile thrusts). Fault zones, slightly postdating a first folding event of Alpine age, experienced a complex evolution through the ductile and brittle deformation regime, showing greenschist facies mylonites overprinted by a penetrative cataclastic deformation. Generation of fault-related pseudotachylyte veins marks the onset of brittle conditions, lasting up to the youngest episodes of fault activity. ⁴⁰Ar/³⁹Ar dating of the pseudotachylyte matrix of 9 samples give two separated age clusters: Late Cretaceous (80–68 Ma) and latest Palaeocene to Middle Eocene (55–43 Ma). These new data provide evidence that the pre-Adamello evolution of the central Southern Alps was characterised by the superposition of different tectonic events accompanying the exhumation of the deepest part of the belt through the brittle–ductile transition. The oldest pseudotachylyte ages demonstrate that south-verging regional thrusting in the central Southern Alps was already active during the Late Cretaceous, concurrently with the development of a synorogenic foredeep basin where the Upper Cretaceous Lombardian Flysch was deposited.     

Thermohaline variability and Antarctic bottom water formation at the Ross Sea shelf break

We use hydrological and current meter data collected in the Ross Sea, Antarctica between 1995 and 2006 to describe the spatial and temporal variability of water masses involved in the production of Antarctic Bottom Water (AABW). Data were collected in two regions of known outflows of dense shelf water in this region; the Drygalski Trough (DT) and the Glomar-Challenger Trough (GCT). Dense shelf water just inshore of the shelf break is dominated by High Salinity Shelf Water (HSSW) in the DT and Ice Shelf Water (ISW) in the GCT. The HSSW in the northern DT freshened by ∼0.06 in 11 y, while the ISW in the northern GCT freshened by ∼0.04 in 8 y and warmed by ∼0.04 °C in 11 y, dominated by a rapid warming during austral summer 2001/02. The Antarctic Slope Front separating the warm Circumpolar Deep Water (CDW) from the shelf waters is more stable near GCT than near DT, with CDW and mixing products being found on the outer DT shelf but not on the outer GCT shelf. The different source waters and mixing processes at the two sites lead to production of AABW with different thermohaline characteristics in the central and western Ross Sea. Multi-year time series of hydrography and currents at long-term moorings within 100 km of the shelf break in both troughs confirm the interannual signals in the dense shelf water and reveal the seasonal cycle of water mass properties. Near the DT the HSSW salinities experienced maxima in March/April and minima in September/October. The ISW in the GCT is warmest in March/April and coolest between August and October. Mooring data also demonstrate significant high-frequency variability associated with tides and other processes. Wavelet analysis of near-bottom moored sensors sampling the dense water cascade over the continental slope west of the GCT shows intermittent energetic pulses of cold, dense water with periods from ∼32 h to ∼5 days.     

Use of sedimentary pigments to infer past phosphorus concentration in lakes

We propose a palaeolimnological method for inferring past total phosphorus (TP) concentrations in lake water from spectrophotometrically-measured sedimentary pigments, particularly total carotenoids (TC). Our approach is based on a highly significant statistical correlation (P < 0.0001) between pigment concentrations (total carotenoids) in the surface sediment of 28 Italian lakes (subalpine, large, deep, shallow, volcanic) and TP concentrations measured in these lakes at overturn when the core was collected. A transfer function was developed from this “training” set, and used to estimate past TP concentrations from pigment concentrations in sediment cores. The results generally agreed with TP values as measured by long-term water quality monitoring programs. Contrasting results were obtained by a comparison with diatom-inferred TP. While the diatom model showed a tendency to overestimate TP values higher than 100 μg l⁻¹, the pigment model correctly estimated TP in lakes when TP was <100 μg l⁻¹, but not when lakes were rich in macrophytes. In fact, lakes with extensive populations of aquatic submersed macrophytes and epiphytes are outliers in terms of the TC versus TP relationship. The root mean square error of prediction of the pigment model is lower than those derived from certain diatom—based inference models. The predicted and residual values are not related to the estimated values and their average is not statistically different from zero. Errors were estimated via a ‘leave-one-out’ re-sampling technique. The proposed method permits rapid and relatively inexpensive determination of reference trophic conditions.     

Laboratory modeling of topographic Rossby normal modes

The physical modeling of topographic Rossby normal modes carried out at the “Coriolis” Rotating Platform (Grenoble), is presented. The basic feature of the bottom topography is a linear slope of 4.3 m×2 m delimited by two lateral walls. Since the studied motions are essentially barotropic, homogeneous water was used. Unsheared currents were generated by a simple movement of a wavemaker located in front of the topographic barrier. The conservation of potential vorticity for the currents flowing onto the channel slope produced Rossby waves: reflections at the lateral boundaries then led to the formation of propagating barotropic Rossby normal modes, whose frequencies and spatial structures were selected by the physical system. The currents were measured through the correlation imaging velocimetry (CIV) method, which allowed an extremely detailed synoptic map of the horizontal velocities in an area (13 m²) including the slope to be obtained every 30 s.A variety of experiments were performed in order to provide a complete process study in which the effect of different channel lengths and rotation periods could be tested. Two different lengths of the linear slope, 4.3 and 3.3 m, and rotation periods ranging from 30 to 50 s were considered. The qualitative analysis of the 2D current patterns, and the good agreement found between the measured eigenperiods and the periods obtained by means of a simple analytical model, show that in all cases the first Rossby normal mode was generated. Moreover, numerical simulations based on the shallow-water equations, for a geometry and paddle movements that match closely the experimental setup, allow to calibrate the analytical model and provide useful information on a discrepancy found between experimental and analytical eigenperiods due to an oscillation of the normal mode trajectory.