Soluble organic compounds in fog and cloud droplets: what have we learned over the past few years?

We have recently set up a new procedure for characterising the water soluble organic compounds (WSOC) in fog water, for which information is still rather limited. Fog samples collected during the 1998–1999 fall–winter season in the Po Valley (Italy) were analysed following this procedure, which allows a quantitative determination of three main classes of organic compounds (neutral species, mono- and di-carboxylic acids, polycarboxylic acids), together accounting for ca. 85% of the total WSOC. This procedure also provides information on the main chemical characteristics of these three classes of compounds (functional groups, aliphatic vs. aromatic character, etc.). The enhanced chemical knowledge on fog/cloud chemical composition opens new scenarios as far as chemical and microphysical processes in clouds and fogs are concerned.     

Jurassic stratigraphy of the Belluno Basin and Friuli Platform: a perspective on far-field compression in the Adria passive margin

Anomalous patterns of the sedimentary architecture have been recognized in passive margins, and only recently they have been associated with plate reorganization or compressional deformations propagating from distant margins. With the aim of discussing the sedimentary architecture and the potential tectonic perturbations to the passive margin pattern, we present the revision of the stratigraphy of a fossil passive margin, involved in the retrobelt of the Alpine orogeny. The main events at the transition from rifted to passive margin have been controlled by palaeoceanography, i.e. the trophic state of surface waters that hampered the carbonate photozoan productivity for a long period between Toarcian and Callovian. Toward the latest Bajocian–earliest Bathonian, the platform productivity increased, dominated by ooids. A regressional trend up to the Middle Bathonian allowed the rapid infilling of the previous rift basin. The successive aggradation in the platform was still dominated by non-skeletal grains until the Early Oxfordian. The Middle Oxfordian to Early Kimmeridgian was a time of recovery of the palaeoceanographic conditions allowing the establishment of a hydrozoan/coral rich platform. The sedimentation rates in the platform increased at the margin of the productive Friuli–Adriatic Platform. From Late Kimmeridgian on, the sedimentation rates at the platform margin returned to the pre-Oxfordian values. At the scale of the whole Adriatic Platform, the Middle Oxfordian to Early Kimmeridgian interval is variable in thickness from 0 to 800 m, and it depicts a couple of folds of around 80–100 km of wavelength. The subsidence analysis of wells and composite logs from literature suggests this interval as a perturbation to the passive margin trend of around 3 Myr of duration. We interpret this folding event, superimposed to the passive margin subsidence, as the far field expression of the transition from intraoceanic to continental obduction, occurred at the eastern Adria active margin.     

Families of periodic orbits in Hill’s problem with solar radiation pressure: application to Hayabusa 2

This work studies periodic solutions applicable, as an extended phase, to the JAXA asteroid rendezvous mission Hayabusa 2 when it is close to target asteroid 1999 JU3. The motion of a spacecraft close to a small asteroid can be approximated with the equations of Hill’s problem modified to account for the strong solar radiation pressure. The identification of families of periodic solutions in such systems is just starting and the field is largely unexplored. We find several periodic orbits using a grid search, then apply numerical continuation and bifurcation theory to a subset of these to explore the changes in the orbit families when the orbital energy is varied. This analysis gives information on their stability and bifurcations. We then compare the various families on the basis of the restrictions and requirements of the specific mission considered, such as the pointing of the solar panels and instruments. We also use information about their resilience against parameter errors and their ground tracks to identify one particularly promising type of solution.     

An integrated procedure to evaluate hydrological models

The growing concern for health‐related problems deriving from pollutants leaching is driving national and international administrations to support the development of tools for evaluating the effects of alternate management scenarios and identifying vulnerable areas. Cropping systems models are powerful tools for evaluating leachates under different environmental, social, and management conditions. As percolating water is the transport vehicle for pollutants transport in soil, a reliable evaluation of water balance models is a fundamental prerequisite for investigating pesticides and nitrate fate. As specific approaches for the evaluation of multi‐layer evolution of state variables are missing, we propose a fuzzy‐based, integrated indicator (I_SWC: 0, best; 1, worst) for a comprehensive evaluation of soil water content (SWC) simulations. We aggregated error metrics with others quantifying the homogeneity of errors across different soil layers, the capability of models to reproduce complex dynamics function of both time and soil depth, and model complexity. We tested I_SWC on a sample dataset where the models CropSyst and CERES‐Wheat were used to simulate SWC for winter wheat systems. I_SWC revealed that, in the explored conditions, the global assessment of the two models' performances allowed identification of CropSyst as the best (average I_SWC = 0·441, with a value of 0·537 obtained by CERES‐Wheat), although each model prevailed for some of the metrics. CropSyst presented the highest accuracy (average agreement module = 0·400), whereas CERES‐Wheat's accuracy was slightly worse, although achieved with a simplified modelling approach (average Akaike Information Criterion = − 230·44), thereby favouring large‐area applicability. The non‐univocal scores achieved by the models for the different metrics support the use of multi‐metric evaluation approaches for quantifying the different aspects of water balance model performances. Copyright © 2010 John Wiley & Sons, Ltd.     

Shaking‐table tests of flat‐bottom circular silos containing grain‐like material

According to Eurocode 8, the seismic design of flat‐bottom circular silos containing grain‐like material is based on a rough estimate of the inertial force imposed on the structure by the ensiled content during an earthquake: 80% of the mass of the content multiplied by the peak ground acceleration. A recent analytical consideration of the horizontal shear force mobilised within the ensiled material during an earthquake proposed by some of the authors has resulted in a radically reduced estimate of this load suggesting that, in practice, the effective mass of the content is significantly less than that specified. This paper describes a series of laboratory tests that featured shaking table and a silo model, which were conducted in order to obtain some experimental data to verify the proposed theoretical formulations and to compare with the established code provisions. Several tests have been performed with different heights of ensiled material – about 0.5 mm diameter Ballotini glass – and different magnitudes of grain–wall friction. The results indicate that in all cases, the effective mass is indeed lower than the Eurocode specification, suggesting that the specification is overly conservative, and that the wall–grain friction coefficient strongly affects the overturning moment at the silo base. At peak ground accelerations up to around 0.35 g, the proposed analytical formulation provides an improved estimate of the inertial force imposed on such structures by their contents. Copyright © 2015 John Wiley & Sons, Ltd.     

Late Quaternary deformation on the island on Pantelleria: New constraints for the recent tectonic evolution of the Sicily Channel Rift (southern Italy)

Structural observations carried out on the volcanic Island of Pantelleria show that the tectonic setting is dominated by NNE trending normal faults and by NW-striking right-lateral strike-slip faults with normal component of motion controlled by a ≈N 100°E oriented extension. This mode of deformation also controls the development of the eruptive fissures, dykes and eruptive centres along NNE–SSW belts that may thus represent the surface response to crustal cracking with associated magma intrusions. Magmatic intrusions are also responsible for the impressive vertical deformations that affect during the Late Quaternary the south-eastern segment of the island and producing a large dome within the Pantelleria caldera complex. The results of the structural analysis carried out on the Island of Pantelleria also improves the general knowledge on the Late Quaternary tectonics of the entire Sicily Channel. ESE–WNW directed extension, responsible for both the tectonic and volcano-tectonic features of the Pantelleria Island, also characterizes, at a greater scale, the entire channel as shown by available geodetic and seismological data. This mode of extension reactivates the older NW–SE trending fault segments bounding the tectonic troughs of the Channel as right-lateral strike-slip faults and produces new NNE trending pure extensional features (normal faulting and cracking) that preferentially develop at the tip of the major strike-slip fault zones. We thus relate the Late Quaternary volcanism of the Pelagian Block magmatism to dilatational strain on the NNE-striking extensional features that develop on the pre-existing stretched area and propagate throughout the entire continental crust linking the already up-welled mantle with the surface.     

The circumnuclear X-ray reflectors in NGC 1068 and the Circinus galaxy

The ASCA and BeppoSAX spectra of the Circinus galaxy and NGC 1068 are analysed and compared with photoionization models based on cloudy . In the case of Circinus, a single, mildly ionized reflector can account for the line spectrum, while in NGC 1068 at least three different reflectors (with different ionization states) are needed. We suggest that the reflector in Circinus and the low ionized one in NGC 1068 are the inner and visible part of the material responsible for the X-ray absorption. With this assumption, we estimate for the inner radius of the absorber a value of 0.2 pc for Circinus and of a few parsecs for NGC 1068.