Paleogeography and structure of the central Mediterranean: Sicily and its offshore area

The geology of the mainland and offshore of Sicily is illustrated by a few geologic sections and seismic profiles across the late Cenozoic orogenic belt of central and western Sicily and across the Sardinia Channel and Sicily Straits. This belt is the result of several tectonic events. Deformation involved mainly the sedimentary cover of the old African continental margin characterized by a broad basinal domain, flanked along its external (southern) margin by a shallow-water carbonate platform attached to Africa in the Triassic. Compressional deformation started in the more internal basinal rock assemblages overlying a thinned crust. The most important structural characteristic of the early phase of thrusting is the duplex pile forming the bulk of the chain in Central Western Sicily. The structure consists of a basal allochthon, made up of Permian to Middle Triassic layers, an intermediate duplex wedge, composed of competent Mesozoic carbonates, and a roof complex, including Upper Mesozoic-Lower Tertiary less competent rocks. Large-scale clockwise rotation of the thrusts accompanied transpressional movements in the hinterland during the Pliocene. Right oblique reverse faults modified the previous tectonic contacts between the allochthons in the hinterland zones. Contemporaneous south-directed imbrications affected the southern external areas, progressively incorporating foreland and piggyback basins. Development of the Gela Thrust System appears to be linked to the transpressional event; its accretion is also related to contemporaneous underthrusting at deeper levels of Mesozoic carbonate substratum. The older buried thrust sheets were pushed up to the surface breaching the deformed Tertiary cover of the Gela TS. Northwards in the belt post-Messinian normal growth faults opened half graben whose sedimentary fill underwent structural inversion. Alternation of extension and compression tectonics characterizes the Sicilian continental margin in the last million years.     

The 3 June 1994 Java Tsunami: A Post-Event Survey of the Coastal Effects

The paper is a report of the field campaign undertaken by an international team (Italian, French and Indonesian) a few weeks after the occurrence of a tsunami invading the south-eastern coast of Java (Indonesia) and it complements the results of a concurrent field survey by Asian and USA researchers. The tsunamigenic earthquake occurred on 3 of June 1994 in the Indian Ocean about 200 km south of Java. The tsunami caused severe damage and claimed many victims in some coastal villages. The main purpose of the survey was to measure the inundation and the runup values as well as to ascertain the possible morphological changes caused by the wave attacks. Attention was particularly focussed on the most affected districts, that is Lumajang, Jember and Banyuwangi in Java, although also the districts of Negera, Tebanan and Denpasar in Bali were examined. The most severe damage was observed in the Banyuwangi district, where the villages of Rajekwesi, Pancer and Lampon were almost completely levelled by the violent waves. Most places were hit by three significant waves with documented wave height often exceeding 5 m. The maximum runup value (9.50 m) was measured at Rajekwesi, where also the most impressive erosion phenomena could be found. In contrast, only in one place of the neighbouring island of Bali was there a slight tsunami, the rest of the island being practically unaffected.     

Change of crustal gravitational potential energy in the Taiwan orogen by the Chi-Chi earthquake sequence

The active convergence between the northwest corner of the Philippine Sea Plate and the southeast margin of the Eurasian Plate has given rise to the Taiwan mountain-building and produced numerous earthquakes. Among the earthquakes, the 1999 Chi-Chi earthquake is the largest one recorded in the century. In this study, we examine the crustal gravitational potential energy (GPE) change in the Taiwan orogen caused by the Chi-Chi earthquake sequence, which was catalogued by the regional broadband seismometer array for a whole year. As a result, we find that the crust was going up and down randomly during the earthquake sequence, but an overall cumulative gain of the crustal GPE, +1.82×10¹⁶ J, was rapidly achieved in 1 month after the main shock. The crustal GPE was nearly still afterwards and reached +1.90×10¹⁶ J in 1 year. Spatially, although the main surface faulting has occurred in western Taiwan, the crustal GPE gain is mainly distributed in central Taiwan at the area where the existing crustal GPE is high and the existing lithospheric GPE is relatively low. The crustal GPE loss by the Chi-Chi earthquake sequence can also be observed and is generally distributed at both sides of the crustal GPE gain area. The crustal GPE gain mainly found in central Taiwan corroborates that the uplift of the Taiwan orogen is principally taking place in central Taiwan, rather than in the more hazardous western Taiwan.     

Monitoring and modelling of pore water pressure changes and riverbank stability during flow events

Pore water pressures (positive and negative) were monitored for four years (1996–1999) using a series of tensiometer‐piezometers at increasing depths in a riverbank of the Sieve River, Tuscany (central Italy), with the overall objective of investigating pore pressure changes in response to ?ow events and their effects on bank stability. The saturated/unsaturated ?ow was modelled using a ?nite element seepage analysis, for the main ?ow events occurring during the four‐year monitoring period. Modelling results were validated by comparing measured with computed pore water pressure values for a series of representative events. Riverbank stability analysis was conducted by applying the limit equilibrium method (Morgenstern‐Price), using pore water pressure distributions obtained by the seepage analysis. The simulation of the 14 December 1996 event, during which a bank failure occurred, is reported in detail to illustrate the relations between the water table and river stage during the various phases of the hydrograph and their effects on bank stability. The simulation, according to monitored data, shows that the failure occurred three hours after the peak stage, during the inversion of ?ow (from the bank towards the river). A relatively limited development of positive pore pressures, reducing the effective stress and annulling the shear strength term due to the matric suction, and the sudden loss of the con?ning pressure of the river during the initial drawdown were responsible for triggering the mass failure. Results deriving from the seepage and stability analysis of nine selected ?ow events were then used to investigate the role of the ?ow event characteristics (in terms of peak stages and hydrograph characteristics) and of changes in bank geometry. Besides the peak river stage, which mainly controls the occurrence of conditions of instability, an important role is played by the hydrograph characteristics, in particular by the presence of one or more minor peaks in the river stage preceding the main one. Copyright © 2004 John Wiley & Sons, Ltd.     

A model for oxygen and sulfur isotope fractionation in sulfate during bacterial sulfate reduction processes

We present a model of bacterial sulfate reduction that includes equations describing the fractionation relationship between the sulfur and the oxygen isotope composition of residual sulfate (δ³⁴S_{SO4_residual}, δ¹⁸O_{SO4_residual}) and the amount of residual sulfate. The model is based exclusively on oxygen isotope exchange between cell-internal sulfur compounds and ambient water as the dominating mechanism controlling oxygen isotope fractionation processes. We show that our model explains δ³⁴S_{SO4_residual} vs. δ¹⁸O_{SO4_residual} patterns observed from natural environments and from laboratory experiments, whereas other models, favoring kinetic isotope fractionation processes as dominant process, fail to explain many (but not all) observed δ³⁴S_{SO4_residual} vs. δ¹⁸O_{SO4_residual} patterns. Moreover, we show that a “typical” δ³⁴S_{SO4_residual} vs. δ¹⁸O_{SO4_residual} slope does not exist. We postulate that measurements of δ³⁴S_{SO4_residual} and δ¹⁸O_{SO4_residual} can be used as a tool to determine cell-specific sulfate reduction rates, oxygen isotope exchange rates, and equilibrium oxygen isotope exchange factors. Data from culture experiments are used to determine the range of sulfur isotope fractionation factors in which a simplified set of equations can be used. Numerical examples demonstrate the application of the equations. We postulate that, during denitrification, the oxygen isotope effects in residual nitrate are also the result of oxygen isotope exchange with ambient water. Consequently, the equations for the relationship between δ³⁴S_{SO4_residual}, δ¹⁸O_{SO4_residual}, and the amount of residual sulfate could be modified and used to calculate the fractionation-relationship between δ¹⁵N_{NO3_residual}, δ¹⁸O_{NO3_residual}, and the amount of residual nitrate during denitrification.     

Proximal and distal styles of pegmatite-related metasomatic emerald mineralization at Ianapera,southern Madagascar

The Ianapera emerald deposit is located in the Neoproterozoic Vohibory Block of southern Madagascar. The local geology consists of intercalated migmatitic gneissic units and calcareous metasedimentary rocks, containing boudinaged metamorphosed mafic/ultramafic lenses, all intruded by pegmatite veins. These units occur near the hinge of the tightly folded Ianapera antiform, within a few kilometers of the Ampanihy shear zone. Emerald mineralization is hosted by metasomatic phlogopite veins, and bodies developed within the mafic/ultramafic rocks. Based on field and textural relationships, we distinguish proximal and distal styles of mineralization. Proximal mineralization occurs at the contact of pegmatite veins with mafic/ultramafic units; in the distal style, pegmatites are not observed. Three types of emeralds could be distinguished, mainly on the basis of color and mineral zoning. Some of these emeralds have the most Al-depleted and Cr-rich composition ever recorded. Another characteristic feature to the Ianapera deposit and, to our knowledge, yet unreported, is the association of some emeralds with scapolite in metasomatised mafic rocks. Mineral inclusions are common in most emeralds and include phlogopite, carbonates, barite, K-feldspar, quartz, pyrite, zircon, monazite, bastnaesite, phenakite, plus Fe and Cr oxides. However, feldspar and rare earth element-bearing minerals occur predominantly in proximal emeralds, which also have a more incompatible trace-element signature than distal emeralds. We propose a model related to syn- to post-tectonic magmatic-hydrothermal activity. Pegmatitic bodies intruded units of the Ianapera antiform probably during tectonic relaxation. Exsolution of fluids rich in halogens and incompatible elements from the cooling pegmatites caused hydrothermal metasomatism of Cr-bearing mafic/ultramafic rocks in direct contact with the pegmatites. Local fracturing favored fluid infiltration, permitting the formation of distal mineralization. Emerald composition was controlled by the chemistry of the host rock. The presence of carbonate mineral inclusions in the emeralds and the high F-activity indicated by elevated F-contents in newly formed minerals suggest transport of Be as a fluoride-carbonate complex. It seems likely that beryl formation was triggered by precipitation of F-rich phlogopite, which removed the complexing ligand from the fluid.     

Highly fractionated I-type granites in NE China (II): isotopic geochemistry and implications for crustal growth in the Phanerozoic

NE China is the easternmost part of the Central Asian Orogenic Belt (CAOB). The area is distinguished by widespread occurrence of Phanerozoic granitic rocks. In the companion paper (Part I), we established the Jurassic ages (184–137 Ma) for three granitic plutons: Xinhuatun, Lamashan and Yiershi. We also used geochemical data to argue that these rocks are highly fractionated I-type granites. In this paper, we present Sr–Nd–O isotope data of the three plutons and 32 additional samples to delineate the nature of their source, to determine the proportion of mantle to crustal components in the generation of the voluminous granitoids and to discuss crustal growth in the Phanerozoic.

Despite their difference in emplacement age, Sr–Nd isotopic analyses reveal that these Jurassic granites have common isotopic characteristics. They all have low initial ⁸⁷Sr/⁸⁶Sr ratios (0.7045±0.0015), positive _Nd(T) values (+1.3 to +2.8), and young Sm–Nd model ages (720–840 Ma). These characteristics are indicative of juvenile nature for these granites. Other Late Paleozoic to Mesozoic granites in this region also show the same features. Sr–Nd and oxygen isotopic data suggest that the magmatic evolution of the granites can be explained in terms of two-stage processes: (1) formation of parental magmas by melting of a relatively juvenile crust, which is probably a mixed lithology formed by pre-existing lower crust intruded or underplated by mantle-derived basaltic magma, and (2) extensive magmatic differentiation of the parental magmas in a slow cooling environment.

The widespread distribution of juvenile granitoids in NE China indicates a massive transfer of mantle material to the crust in a post-orogenic tectonic setting. Several recent studies have documented that juvenile granitoids of Paleozoic to Mesozoic ages are ubiquitous in the Central Asian Orogenic Belt, hence suggesting a significant growth of the continental crust in the Phanerozoic.     

Exploring the impact of diagenesis on (isotope) geochemical and microstructural alteration features in biogenic aragonite

For the Quaternary and Neogene, aragonitic biogenic and abiogenic carbonates are frequently exploited as archives of their environment. Conversely, pre‐Neogene aragonite is often diagenetically altered and calcite archives are studied instead. Nevertheless, the exact sequence of diagenetic processes and products is difficult to disclose from naturally altered material. Here, experiments were performed to understand biogenic aragonite alteration processes and products. Shell subsamples of the bivalve Arctica islandica were exposed to hydrothermal alteration. Thermal boundary conditions were set at 100°C, 175°C and 200°C. These comparably high temperatures were chosen to shorten experimental durations. Subsamples were exposed to different ¹⁸O‐depleted fluids for durations between two and twenty weeks. Alteration was documented using X‐ray diffraction, cathodoluminescence, fluorescence and scanning electron microscopy, as well as conventional and clumped isotope analyses. Experiments performed at 100°C show redistribution and darkening of organic matter, but lack evidence for diagenetic alteration, except in Δ₄₇ which show the effects of annealing processes. At 175°C, valves undergo significant aragonite to calcite transformation and neomorphism. The δ¹⁸O signature supports transformation via dissolution and reprecipitation, but isotopic exchange is limited by fluid migration through the subsamples. Individual growth increments in these subsamples exhibit bright orange luminescence. At 200°C, valves are fully transformed to calcite and exhibit purple‐blue luminescence with orange bands. The δ¹⁸O and Δ₄₇ signatures reveal exchange with the aqueous fluid, whereas δ¹³C remains unaltered in all experiments, indicating a carbonate‐buffered system. Clumped isotope temperatures in high‐temperature experiments show compositions in broad agreement with the measured temperature. Experimentally induced alteration patterns are comparable with individual features present in Pleistocene shells. This study represents a significant step towards sequential analysis of diagenetic features in biogenic aragonites and sheds light on reaction times and threshold limits. The limitations of a study restricted to a single test organism are acknowledged and call for refined follow‐up experiments.     

All-sky Data Assimilation of MWTS-2 and MWHS-2 in the Met Office Global NWP System.

Microwave radiances from passive polar-orbiting radiometers have been, until recently, assimilated in the Met Office global numerical weather prediction system after the scenes significantly affected by atmospheric scattering are discarded.Recent system upgrades have seen the introduction of a scattering-permitting observation operator and the development of a variable observation error using both liquid and ice water paths as proxies of scattering-induced bias. Applied to the Fengyun 3 Microwave Temperature Sounder 2(MWTS-2) and the Microwave Humidity Sounder 2(MWHS-2), this methodology increases the data usage by up to 8% at 183 GHz. It also allows for the investigation into the assimilation of MWHS-2 118 GHz channels, sensitive to temperature and lower tropospheric humidity, but whose large sensitivity to ice cloud have prevented their use thus far. While the impact on the forecast is mostly neutral with small but significant shortrange improvements, 0.3% in terms of root mean square error, for southern winds and low-level temperature, balanced by 0.2% degradations of short-range northern and tropical low-level temperature, benefits are observed in the background fit of independent instruments used in the system. The lower tropospheric temperature sounding Infrared Atmospheric Sounding Interferometer(IASI) channels see a reduction of the standard deviation in the background departure of up to 1.2%. The Advanced Microwave Sounding Unit A(AMSU-A) stratospheric sounding channels improve by up to 0.5% and the Microwave Humidity Sounder(MHS) humidity sounding channels improve by up to 0.4%.