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41.
Gazzola Laura Ferronato Massimiliano Frigo Matteo Janna Carlo Teatini Pietro Zoccarato Claudia Antonelli Massimo Corradi Anna Dacome Maria Carolina Mantica Stefano 《Computational Geosciences》2021,25(5):1731-1750
Computational Geosciences - Anthropogenic land subsidence can be evaluated and predicted by numerical models, which are often built over deterministic analyses. However, uncertainties and... 相似文献
42.
Pasquale Crea Concetta De Stefano Demetrio Milea Silvio Sammartano 《Marine Chemistry》2008,112(3-4):142-148
The results of a potentiometric investigation (by ISE-H+, glass electrode) on the speciation of phytate ion (Phy12−) in an ionic medium simulating the major components (Na+, K+, Ca2+, Mg2+, Cl− and SO42−) of natural seawater, at different salinities and t = 25 °C, are reported. The work was particularly aimed at determining the possible formation of mixed Ca2+–Mg2+–phytate ion pairs, and to establish how including the formation of these mixed species would affect the speciation modeling in seawater media. After testing various speciation models, that considering the formation of the MgCaH3Phy5−, MgCaH4Phy4−, Mg2CaH3Phy3− and Mg2CaH4Phy2− species was accepted, and corresponding stability constants were determined at two salinities (S = 5, 10). A discussion is reported both on the choice of the experimental conditions and on the possibility to extend these results to those typical of real seawater. A detailed procedure is also described to demonstrate that the stability of these species is higher than that statistically predicted. As reported in literature, a parameter, namely log X, has been determined in order to quantify this extra stability for the formation of each mixed species at various salinities. For example, at S = 10, log X113 = 2.67 and log X114 = 1.37 for MgCaH3Phy5− and MgCaH4Phy4− (statistical value is log Xstat = 0.60), and log X213 = 6.11 and log X214 = 2.15 for Mg2CaH3Phy3− and Mg2CaH4Phy2− (log Xstat = 1.43), respectively. Results obtained also showed that the formation of these species may occur even in conditions of low salinity (i.e. low concentration of alkaline earth cations) and low pH (i.e., more protonated ligand). 相似文献
43.
Together with the main aim of preserving nature, national parks are also expected to play an important role for the local communities, driving economic activities toward the lens of sustainable development. This contribution aims to present an exploratory study on the relationship between the presence of a protected mountain area, the Gran Paradiso National Park(GPNP), in the North West of the Italian Alps, and the classification of tourism destinations, according to Weaver model of destination management. Starting from the model,the authors provide a quantitative analysis using a set of variables and indicators to comprehensively assess the differing patterns assumed by the municipalities within the borders of the GPNP and those that are not.The provisional results illustrate that the municipalities within the border of a protected area are more likely to be grouped alongside the sustainable mountain destinations. Meanwhile,research outcomes confirm that a protected area does not necessarily contrast the tourism industry but instead may boost local development by driving it within the borders of the sustainable development,switching from the area's only preservation function to a flywheel for the local communities. 相似文献
44.
Virender K. Sharma Aurelie Moulin Frank J. Millero Concetta De Stefano 《Marine Chemistry》2006,99(1-4):52
The dissociation constants (pK1, pK2 and pK3) for cysteine have been measured in seawater as a function of temperature (5 to 45 °C) and salinity (S = 5 to 35). The seawater values were lower than the values in NaCl at the same ionic strength. In an attempt to understand these differences, we have made measurements of the constants in Na–Mg–Cl solutions at 25 °C. The measured values have been compared to those calculated from the Pitzer ionic interaction model. The lower values of pK3 in the Na–Mg–Cl solutions have been attributed to the formation of Mg2+ complexes with Cys2− anionsThe stability constants have been fitted toafter corrections are made for the interaction of Mg2+ with H+.The pK1 seawater measurements indicate that H3Cys+ interacts with SO42−. The Pitzer parameters β0(H3CysSO4), β1(H3CysSO4) and C(H3CysSO4) have been determined for this interaction. The formation of CaCys as well as MgCys are needed to account for the values of pK2 and pK3 in seawater.The consideration of the formation of MgCys and CaCys in seawater yields model calculated values of pK1, pK2 and pK3 that agree with the measured values to within the experimental error of the measurements. This study shows that it is important to consider all of the ionic interactions in natural waters when examining the dissociation of organic acids. 相似文献
Mg2+ + Cys2− = MgCys
45.
Sinkholes and cavities can represent serious hazards to human safety and urban infrastructures,cause roadbed subsidence,and so on.It is therefore essential to evaluate various sinkholes in different depths and sizes to assess the risk of collapse.This paper evaluates the effect of different cavities on Rayleigh-wave propagation and body(P)wave refraction.Rayleigh(R)wave propagation is analyzed according to the classical multi-channel analysis of surface waves(MASW)method also considering the R-wave backscattering.Synthetic seismic traces are computed by means of finite element modeling(FEM)for cavity and intrusion at different depths and sizes.Furthermore,field acquisition data is used to verify the detection effect of a cavity on R-and P-waves.The results show that the presence of backscattered R-waves and the changes in the R-wave velocity spectrum can help in cavity identification.Additional possible evidence is represented by significant changes in the refraction travel times over the cavity location.It can be concluded that the field data are in good agreement with the synthetic,and it could be effective to consider the results of both R-and P-wave analysis in order to efficiently identify the cavities. 相似文献
46.
47.
The Maldives was severely hit by massive coral bleaching and subsequent mortality in 1998. The results of reef monitoring in the following years have supported contrasting views about their recovery potential, partly because of the scarcity of information on the situation before 1998. Quantitative data on coral assemblages collected in 1993 in the Rasfari region (North Malé Atoll) may provide a base-line for the evaluation of the present status of the Maldivian reefs. Five years before the 1998 mortality, most coral communities appeared to be similar, in terms of both coral cover and growth-form composition, to those described in 1958 and 1964, notwithstanding increased human pressure and local events such as minor bleaching episodes in 1987 and crown-of-thorns starfish (COTS) attacks in 1989. Three lessons can be learnt from these results to help to understand the present situation, some ten years after the 1998 mass mortality. First, Maldivian reefs proved in the past to be capable of maintaining flourishing coral life despite various disturbances. Second, four years had been sufficient for complete reef recovery after a (minor) bleaching event. Third, recovery after both COTS attack and bleaching follows a predictable path suggesting that the presence of a three-dimensional community structure, which should reduce post settlement mortality of coral recruits, is essential for rapid coral recovery. As coral recruitment remains high and large tabular Acropora colonies are now reappearing, it is expected that Maldivian reefs should return to their original condition within the next few years. 相似文献
48.
Lapo Ragionieri Stefano Cannicci Christoph D. Schubart Sara Fratini 《Estuarine, Coastal and Shelf Science》2010
Most marine organisms are characterized by at least one planktonic phase during their life history, potentially allowing interconnection of populations separated by several hundred kilometers. For many years, the idea that marine species are genetically homogenous throughout their range of distribution, due to passive larval transport, has been a paradigm. Nowadays, a growing number of studies underline the existence of boundaries in the marine realm and highlight how larval dispersal is a complex process depending on biotic as well as abiotic factors. Marine fragmented habitats, such as atolls, mangroves and estuaries, are optimal systems for investigating the marine dispersion process under a metapopulation approach, since populations can be geographically defined a priori as opposed to those occupying open marine environments. Within this frame, the present paper investigates the population genetic structure and the demographic history of the mangrove crab Neosarmatium meinerti within the western Indian Ocean by partial sequences of the mitochondrial DNA cytochrome oxidase subunit I. A total of 167 specimens were sampled from six mangrove sites distributed along the East African coast, from Kenya to South Africa, also including a mangrove forest located on Mahé Island, Seychelles. A sharp genetic break between the mainland and the Seychelles is recorded, revealing the existence of two historically distinct groups that can be defined as independent evolutionary units. Gene flow along the East African coast appears to be high enough to form a single metapopulation, probably by means of stepping stone populations. Otherwise, this mainland metapopulation is currently under expansion through a gradual moving front from the subtropical toward the equatorial populations. 相似文献
49.
The MoSE project (construction of mobile barrier to safeguard the Lagoon of Venice) entails changes to the structure of the lagoon's inlets. This could have consequences for the areas near the inlets and for the dynamics of the lagoon ecosystem as a whole. In order to predict the effects of the proposed alterations on the hydrodynamics of the lagoon, a well-tested hydrodynamic-dispersion model was applied. Simulations were carried out considering both idealised and realistic tide and wind scenarios. 相似文献
50.