A DNA tracer used in column tests for hydrogeology applications

Tracing techniques are commonly used to investigate groundwater quality and dynamics, as well as to measure the hydrogeological parameters of aquifers. The last decade has seen a growing interest in environmentally friendly tracers, including single-stranded DNA molecules. In this study, an electrolytic tracer and a synthetic DNA tracer are comparatively evaluated in laboratory scale tests to assess their potential application in field studies aimed at investigating groundwater environments. A real-time quantitative Polymerase Chain Reaction assay was developed and optimized to detect and quantify the DNA tracer, while tracer column tests were performed to investigate the DNA tracer behavior and to compare it to the electrolytic tracer. The results show that the DNA tracer has an almost pure convective flow, while the KCl tracer experiences dispersive behavior. The tracing method proposed can be applied in hydrogeological field studies involving calcareous fractured rock systems, with the DNA tracer particularly suitable in tracing karst systems, which are often characterized by several conduits of flow. To test the DNA tracer in operation, a preliminary test was conducted in the field.     

A review of research on seismic behaviour of irregular building structures since 2002

The paper presents an overview of the progress in research regarding seismic response of plan and vertically irregular building structures. Three areas of research are surveyed. The first is the study of the effects of plan-irregularity by means of single-storey and multi-storey building models. The second area encompasses passive control as a strategy to mitigate torsional effects, by means of base isolation and other types of devices. Lastly, the third area concerns vertically irregular structures and setback buildings. Although fewer papers have been published in this last area with respect to the former ones, this state-of-the-art reports extensively on research efforts and progress into the seismic behaviour of irregular buildings in elevation to show the growing interest among specialists in the field.     

Transient processes in Stromboli’s shallow basaltic system inferred from dolerite and magmatic breccia blocks erupted during the 5 April 2003 paroxysm

We describe the mineralogy, geochemistry, and mesomicrostructure of fresh subvolcanic blocks erupted during the 5 April 2003 paroxysm of Stromboli (Aeolian Islands, Italy). These blocks represent ∼50 vol.% of the total erupted ejecta and consist of fine- to medium-grained basaltic lithotypes ranging from relatively homogeneous dolerites to strongly or poorly welded magmatic breccias. The breccia components are represented by angular fragments of dolerites entrapped in a matrix of vesiculated (lava-like to scoriae) crystal-rich (CR) basalt. All of the studied blocks are cognates with the CR basalt of the normal Strombolian activity or lavas and they are often coated by a few-centimeter thick layer of crystal-poor (CP) basaltic pumice erupted during the paroxysm. We suggest that they result from the rapid increase of pressure and related subvolcanic rock failure that occurred shortly before the 5 April 2003 explosion, when the uppermost portion of the edifice inflated and suffered brecciation as the result of the sudden rise of the gas-rich CP basalt that triggered the eruption. Dolerites and magmatic matrix of the breccias show major and trace element compositions that match those of the CR basalts erupted during normal Strombolian activity and effusive events at Stromboli volcano. Dolerites consist of (a) phenocrysts normally found in the CR basalts and (b) late-stage magmatic minerals such as sanidine, An_60-28 plagioclase, Fe–Mn-rich olivines (Fo_68-48), phlogopite, apatite, and opaque mineral pairs (magnetite and ilmenite), most of which are never found both in lava flows and scoriae erupted during the persistent explosive activity that characterizes typical Strombolian behavior. Subvolcanic crystallization of the Stromboli CR magma, leading to slowly cooled equivalents of basalts, could result from transient drainage of the magma from the summit craters to lower levels. Fingering and engulfing of the material that collapsed from the summit crater floor into the shallow basaltic system during the late evening of 28 December 2002 coupled with the short break in the summit persistent explosions between December 2002 and March 2003 permitted the CR magma pockets to solidify as dolerites, which were confined to the uppermost portion of the system and thus not involved in the ongoing flank effusive activity. Crystal size distribution of the basaltic blocks and crystallization of the finer-grained (<0.1 mm) mafic minerals of the dolerites over a time interval of ∼100 days closely agrees with the above interpretation. Vesicle filling (miarolitic cavities) locally found in some dolerites, with minerals deposited as vapor-phase crystallization is a result of continuous gas percolation through the rocks of the uppermost portion of the volcanic system. Poorly welded magmatic breccias formed during syn-eruptive processes of 5 April 2003, when the paroxysm strongly shattered the shallow subvolcanic system and many dolerite fragments were entrapped in the CR magma. In contrast, the high degree of welding between the dolerite clasts and the CR basaltic matrix in the strongly welded magmatic breccias provides a snapshot of subvolcanic intrusions of the CR basalt into the dolerite when, after a 2-month break in activity, CR magmas started to rise again to the summit craters. Blocks similar to these subvolcanic ejecta of 5 April 2003 were also erupted during previous paroxysms (e.g., 1930) suggesting that changes in the usual Strombolian activity (e.g., short breaks in the persistent mild explosions and/or flank effusive activity) lead to transient crystallization of dolerites in the shallow plumbing system.     

On estimating frequency-magnitude relations from heterogeneous catalogs

The paper studies the effect of magnitude errors on heterogeneous catalogs, by applying the apparent magnitude theory (seeTinti andMulargia, 1985a), which proves to be the most natural and rigorous approach to the problem. Heterogeneities in seismic catalogs are due to a number of various sources and affect both instrumental as well as noninstrumental earthquake compilations.The most frequent basis of heterogeneity is certainly that the recent instrumental records are to be combined with the historic and prehistoric event listings to secure a time coverage, considerably longer than the recurrence time of the major earthquakes. Therefore the case which attracts the greatest attention in the present analysis is that of a catalog consisting of a subset of higher quality data, generallyS ₁, spanning the interval T ₁ (the instrumental catalog), and of a second subset of more uncertain magnitude determination, generallyS ₂, covering a vastly longer interval T ₂ (the historic and/or the geologic catalog). The magnitude threshold of the subcatalogS ₁ is supposedly smaller than that ofS ₂, which, as we will see, is one of the major causes of discrepancy between the apparent magnitude and the true magnitude distributions. We will further suppose that true magnitude occurrences conform to theGutenberg-Richter (GR) law, because the assumption simplified the analysis without reducing the relevancy of our findings.The main results are: 1) the apparent occurrence rate exceeds the true occurrence rate from a certain magnitude onward, saym _GR; 2) the apparent occurrence rate shows two distinct GR regimes separated by an intermediate transition region. The offset between the two regimes is the essential outcome ofS ₁ being heterogeneous with respect toS ₂. The most important consequences of this study are that: 1) it provides a basis to infer the parameters of the true magnitude distribution, by correcting the bias deriving from heterogeneous magnitude errors; 2) it demonstrates that the double GR decay, that several authors have taken as the incontestable proof of the failure of the GR law and of the experimental evidence of the characteristic earthquake theory, is instead perfectly consistent with a GR-type seismicity.     

Modeling the effects of the variability of temperature-related dynamic viscosity on the thermal-affected zone of groundwater heat-pump systems

Thermal perturbation in the subsurface produced in an open-loop groundwater heat pump (GWHP) plant is a complex transport phenomenon affected by several factors, including the exploited aquifer’s hydrogeological and thermal characteristics, well construction features, and the temporal dynamics of the plant’s groundwater abstraction and reinjection system. Hydraulic conductivity has a major influence on heat transport because plume propagation, which occurs primarily through advection, tends to degrade following conductive heat transport and convection within moving water. Hydraulic conductivity is, in turn, influenced by water reinjection because the dynamic viscosity of groundwater varies with temperature. This paper reports on a computational analysis conducted using FEFLOW software to quantify how the thermal-affected zone (TAZ) is influenced by the variation in dynamic viscosity due to reinjected groundwater in a well-doublet scheme. The modeling results demonstrate non-negligible groundwater dynamic-viscosity variation that affects thermal plume propagation in the aquifer. This influence on TAZ calculation was enhanced for aquifers with high intrinsic permeability and/or substantial temperature differences between abstracted and post-heat-pump-reinjected groundwater.

     

Snow model sensitivity analysis to understand spatial and temporal snow dynamics in a high‐elevation catchment

In this paper, we addressed a sensitivity analysis of the snow module of the GEOtop2.0 model at point and catchment scale in a small high‐elevation catchment in the Eastern Italian Alps (catchment size: 61 km²). Simulated snow depth and snow water equivalent at the point scale were compared with measured data at four locations from 2009 to 2013. At the catchment scale, simulated snow‐covered area (SCA) was compared with binary snow cover maps derived from moderate‐resolution imaging spectroradiometer (MODIS) and Landsat satellite imagery. Sensitivity analyses were used to assess the effect of different model parameterizations on model performance at both scales and the effect of different thresholds of simulated snow depth on the agreement with MODIS data. Our results at point scale indicated that modifying only the “snow correction factor” resulted in substantial improvements of the snow model and effectively compensated inaccurate winter precipitation by enhancing snow accumulation. SCA inaccuracies at catchment scale during accumulation and melt period were affected little by different snow depth thresholds when using calibrated winter precipitation from point scale. However, inaccuracies were strongly controlled by topographic characteristics and model parameterizations driving snow albedo (“snow ageing coefficient” and “extinction of snow albedo”) during accumulation and melt period. Although highest accuracies (overall accuracy = 1 in 86% of the catchment area) were observed during winter, lower accuracies (overall accuracy < 0.7) occurred during the early accumulation and melt period (in 29% and 23%, respectively), mostly present in areas with grassland and forest, slopes of 20–40°, areas exposed NW or areas with a topographic roughness index of ?0.25 to 0 m. These findings may give recommendations for defining more effective model parameterization strategies and guide future work, in which simulated and MODIS SCA may be combined to generate improved products for SCA monitoring in Alpine catchments.     

Roughness effect on the correction factor of surface velocity for rill flows

Flow velocity is one of the most important hydrodynamic variables for both channelized (rill and gullies) and interrill erosive phenomena. The dye tracer technique to measure surface flow velocity V_s is based on the measurement of the travel time of a tracer needed to cover a known distance. The measured V_s must be corrected to obtain the mean flow velocity V using a factor α_v = V/V_s which is generally empirically deduced. The V_s measurement can be influenced by the method applied to time the travel of the dye-tracer and α_v can vary in different flow conditions. Experiments were performed by a fixed bed small flume simulating a rill channel for two roughness conditions (sieved soil, gravel). The comparison between a chronometer-based (CB) and video-based (VB) technique to measure V_s was carried out. For each slope-discharge combination, 20 measurements of V_s, characterized by a sample mean V_m, were carried out. For both techniques, the frequency distributions of V_s/V_m resulted independent of slope and discharge. For a given technique, all measurements resulted normally distributed, with a mean equal to one, and featured by a low variability. Therefore, V_m was considered representative of surface flow velocity. Regardless of roughness, the V_m values obtained by the two techniques were very close and characterized by a good measurement precision. The developed analysis on α_v highlighted that it is not correlated with Reynolds number for turbulent flow regime. Moreover, α_v is correlated neither with the Froude number nor with channel slope. However, the analysis of the empirical frequency distributions of the correction factor demonstrated a slope effect. For each technique (CB, VB)-roughness (soil, gravel) combination, a constant correction factor was statistically representative even if resulted in less accurate V estimations compared to those yielded by the slope-specific correction factor.     

The 3 June 1994 Java Tsunami: A Post-Event Survey of the Coastal Effects

The paper is a report of the field campaign undertaken by an international team (Italian, French and Indonesian) a few weeks after the occurrence of a tsunami invading the south-eastern coast of Java (Indonesia) and it complements the results of a concurrent field survey by Asian and USA researchers. The tsunamigenic earthquake occurred on 3 of June 1994 in the Indian Ocean about 200 km south of Java. The tsunami caused severe damage and claimed many victims in some coastal villages. The main purpose of the survey was to measure the inundation and the runup values as well as to ascertain the possible morphological changes caused by the wave attacks. Attention was particularly focussed on the most affected districts, that is Lumajang, Jember and Banyuwangi in Java, although also the districts of Negera, Tebanan and Denpasar in Bali were examined. The most severe damage was observed in the Banyuwangi district, where the villages of Rajekwesi, Pancer and Lampon were almost completely levelled by the violent waves. Most places were hit by three significant waves with documented wave height often exceeding 5 m. The maximum runup value (9.50 m) was measured at Rajekwesi, where also the most impressive erosion phenomena could be found. In contrast, only in one place of the neighbouring island of Bali was there a slight tsunami, the rest of the island being practically unaffected.     

Palynology of Triassic–Jurassic boundary sections in northern Switzerland

A first palynostratigraphic scheme of Upper Triassic deposits in northern Switzerland was established based on spore-pollen associations and dinoflagellate cyst records from the upper part of the Upper Triassic Klettgau Formation and the lower part of the Lower Jurassic Staffelegg Formation. Drill cores from the Adlerberg region (Basel Tabular Jura) and from Weiach (northern part of Canton Zurich) as well as from an outcrop at the Chilchzimmersattel (Basel Folded Jura) were studied and five informal palynological associations are distinguished. These palynological associations correlate with palynological association of the Central European Epicontinental Basin and the Tethyan realm and provide a stratigraphic framework for the uppermost Triassic sediments in northern Switzerland. Throughout the uppermost Triassic to Jurassic palynological succession a remarkable prominence of Classopollis spp. is observed. Besides Classopollis spp. the three Rhaetian palynological associations A to C from the Upper Triassic Belchen Member include typical Rhaetian spore-pollen and dinoflagellate taxa (e.g., Rhaetipollis germanicus, Geopollis zwolinskae, Rhaetogonyaulax rhaetica, and Dapcodinium priscum). Association B differs from association A in a higher relative abundance of the sporomorph taxa Perinopollenites spp. and the consistent occurrence of Granuloperculatipollis rudis and Ricciisporites tuberculatus. Spore diversity is highest in the late Rhaetian palynological association C and includes Polypodiisporites polymicroforatus. A Rhaetian age for the Belchen Member is confirmed by palynological associations A–C, but there is no record of the latest Rhaetian and the earliest Jurassic. In contrast to the Rhaetian palynological associations the Early Jurassic associations W and D include Pinuspollenites spp., Trachysporites fuscus (in association W), and Ischyosporites variegatus. In the view of the end-Triassic mass extinction and contemporaneous environmental changes the described palynofloral succession represents the pre-extinction phase (associations A and B) including a distinct transgression, the extinction phase (association C) associated with a regression, and the post-extinction phase (association W).