Shallow sediment deformation styles in north-western Campeche Knolls,Gulf of Mexico and their controls on the occurrence of hydrocarbon seepage

During German R/V Meteor M67/2 expedition to Campeche Knolls, southern Gulf of Mexico, a set of 2D high resolution seismic data was acquired to study the near-surface sediment structure and its relationship with hydrocarbon seepages in this salt province. The comprehensive survey covered 20 individual bathymetric highs or ridges and identified three principle structural types: Passive Type, Chaopopte Type, and Asymmetric Flap Type. The first type is the result of passive diapirism, whereas the latter two were initialized by a regional compressional event in the Miocene, but are later differently modified by salt tectonism. Chapopote Type structures appear as symmetrical domes, with uplifted coarse-grained Miocene sediments in their cores and rather thin syn-kinematic sediments covering the crests. Asymmetric Flap Type structures are also first folded as domes or ridges, but one flap later subsided together with salt evacuation, resulting in single uplifted monoclines. With the coarse-grained pre-kinematic sediments as reservoir units, both structural types can focus and accumulate hydrocarbons. The geometries of the structures suggest that hydrocarbons are accumulated in the center of the Chapopote Type structures and in the subsided flaps of the Asymmetric Flap Type structures. Hydrocarbon leakage from these thinly sealed reservoirs is regarded as the principle mechanism for the seepage in the study area, and accordingly the most seepage-prone positions are above these reservoirs. The seep locations suggested by analysis of sea-surface oil slick images of SAR satellite data are also examined in this study. These independently derived seep locations confirm the seepage-prone positions to be above the shallow buried reservoirs. This study suggest that the shallow sediment structures control the distribution of the hydrocarbon seeps of the north-western Campeche Knolls, although the hydrocarbons are sourced from the greater depth.     

Effects of variable wind shear on the mesoscale circulation forced by slab‐symmetric diabatic heating

Abstract

We examine the response of stably stratified airflow to a slab‐symmetric diabatic forcing associated with condensation in long‐lasting precipitation bands. The steady‐state linearized Boussinesq equations are used to model the diagnostic relationship between the vertical motion field, the heating source and the ambient flow. The basic‐state flow is assumed to be horizontally uniform and non‐rotating, but the static stability and wind vary in the vertical. Linear theory shows that the speed of the along‐band wind component is unimportant for slab‐symmetric heating since it cannot contribute towards the advection of buoyancy or vertical motion.

For typical atmospheric stratification and a moving heating source associated with a cloud band, the Taylor‐Goldstein equation is solved numerically. The numerical results show that the cross‐band wind shear tilts the updraft core and broadens it. While the magnitude of the shear is increased, the circulation becomes stronger. The details of the wind profile are also important in determining the intensity and structure of the circulation. When the wind profile indicates a convex bulge (i.e. the low‐level shear is weaker than the upper‐level shear), the circulation becomes slightly weaker in comparison with the linear wind profile. Conversely, the circulation becomes stronger when the wind profile has a concave shape. Increasing the concave bulge tends to enhance the circulation but not in a monotonic fashion. This non‐monotonic relation between the vertical motion and the parabolic wind profile is interpreted in terms of kinetic energy changes of parcels that interchange their altitudes.     

In situ LA-ICPMS Isotopic and Geochronological Studies on Carbonatites and Phoscorites from the Guli Massif,Maymecha-Kotuy,Polar Siberia

In this study we present a fresh isotopic data, as well as U–Pb ages from different REE-minerals in carbonatites and phoscorites of Guli massif using in situ LA-ICPMS technique. The analyses were conducted on apatites and perovskites from calcio-carbonatite and phoscorite units, as well as on pyrochlores and baddeleyites from the carbonatites. The ⁸⁷Sr/⁸⁶Sr ratios obtained from apatites and perovskites from the phoscorites are 0.70308–0.70314 and 0.70306–0.70313, respectively; and 0.70310–0.70325 and 0.70314–0.70327, for the pyrochlores and apatites from the carbonatites, respectively.Furthermore, the in situ laser ablation analyses of apatites and perovskites from the phoscorite yield εNd from 3.6 (±1) to 5.1 (±0.5) and from 3.8 (±0.5) to 4.9 (±0.5), respectively; εNd of apatites, perovskites and pyrochlores from carbonatite ranges from 3.2 (±0.7) to 4.9 (±0.9), 3.9 (±0.6) to 4.5 (±0.8) and 3.2 (±0.4) to 4.4 (±0.8), respectively. Laser ablation analyses of baddeleyites yielded an eHf(t)d of +8.5 (± 0.18); prior to this study Hf isotopic characteristic of Guli massif was not known. Our new in situ εNd, ⁸⁷Sr/⁸⁶Sr and eHf data on minerals in the Guli carbonatites imply a depleted source with a long time integrated high Lu/Hf, Sm/Nd, Sr/Rb ratios.In situ U–Pb age determination was performed on perovskites from the carbonatites and phoscorites and also on pyrochlores and baddeleyites from carbonatites. The co-existing pyrochlores, perovskites and baddeleyites in carbonatites yielded ages of 252.3 ± 1.9, 252.5 ± 1.5 and 250.8 ± 1.4 Ma, respectively. The perovskites from the phoscorites yielded an age of 253.8 ± 1.9 Ma. The obtained age for Guli carbonatites and phoscorites lies within the range of ages previously reported for the Siberian Flood Basalts and suggest essentially synchronous emplacement with the Permian-Triassic boundary.     

Zoning and exsolution in alkali feldspars from Laacher See volcano (Western Germany): constraints on temperature history prior to eruption

Compositional zoning and exsolution patterns of alkali feldspars in carbonatite-bearing cognate syenites from the 6.3 km³ (D.R.E) phonolitic Laacher See Tephra (LST) deposit in western Germany (12.9 ka) are reported. These rocks represent the cooler outer portion and crystal-rich products of a cooling magma reservoir at upper crustal levels. Major and trace-element difference between cores and rims in sanidine crystals represent two generations of crystal growth separated by unmixing of a carbonate melt. Trace-element differences measured by LA–ICP–MS are in accordance with silicate–carbonate unmixing. Across the core–rim boundary, we extracted gray-scale profiles from multiple accumulations of back-scattered electron images. Gray scales directly represent K/Na ratios owing to low concentrations of Ba and Sr (<?30 ppm). Diffusion gradients are modeled to solve for temperature using known pre-eruptive U–Th zircon ages (0–20 ky) of each sample (Schmitt et al., J Petrol 51:1053–1085, 2010). Estimated temperatures range from 630 °C to 670 °C. For the exsolution boundaries, a diffusive homogenization model is constrained by the solvus temperature of ~ 712^_725 °C and gives short time scales of only 15–50 days. Based on our results, we present a model for the temperature–time history of these rocks. The model also constrains the thermal variation across the cooling crystal-rich carapace of the magma reservoir over 20 ka and suggests a thermal reactivation of cumulates, the cooling carapace, and probably the entire system only a few years prior to the explosive eruption of the remaining molten core of the phonolitic magma reservoir.     

The effect of bedform dynamics on computing suspended sediment fluxes using optical backscatter sensors and current meters

The sensitivity of the suspended sediment flux is tested with respect to rapid changes in bed-level across the surf zone of a sandy beach. The suspended flux was computed using a fixed instrument array, but bed-level changes due to ripple migration caused the instrument elevations to be significantly changed during the course of the experiment. The nominal elevations of the instruments were adjusted during data processing (using the MOBS array) to maintain a fixed elevation with respect to bed-level changes. The resultant suspended sediment concentrations and fluxes were significantly different from the unadjusted data, and for the present data set O(35%) less when averaged over the tide. The maximum difference between adjusted and unadjusted fluxes may be O(260%). The results indicate that changes in bed-level, particularly those due to bedform migration, must be accounted for when processing OBS data if reliable estimates of suspended sediment transport are to be obtained in the field.     

Stable carbon isotope ratios of plankton carbon and sinking organic matter from the Atlantic sector of the Southern Ocean

The stable carbon isotope composition of particulate organic carbon (POC) from plankton, sediment trap material and surface sediments from the Atlantic sector of the Southern Ocean were determined. Despite low and constant water temperatures, large variations in the δ¹³C values of plankton were measured. ¹³C enrichments of up to 10‰ coincided with a change in the diatom assemblage and a two-fold increase in primary production. Increased CO₂ consumption as a result of rapid carbon fixation may result in diffusion limitation reducing the magnitude of the isotope fractionation. The δ¹³C values of plankton from sea-ice cores display a relationship with the chlorophyll a content. High ‘ice-algae’ biomass, in combination with a limited exchange with the surrounding seawater, results in values of about − 18 to − 20‰. It is assumed that these values are related to a reduced CO₂ availability in the sea-ice system. In comparison with plankton, sinking krill faeces sampled by traps can be enriched by 2–5‰ in ¹³C (e.g. central Bransfield Strait). In contrast, the transport of particles in other faeces, diatom aggregates or chains results in minor isotope changes (e.g. Drake Passage, Powell Basin, NW Weddell Sea). A comparison between the δ¹³C values of sinking matter and those of surface sediments reveals that ¹³C enrichments of up to 3–4‰ may occur at the sediment-water boundary layer. These isotopic changes are attributed to high benthic respiration rates.     

The Allende multicompound chondrule (ACC)—Chondrule formation in a local super‐dense region of the early solar system

In Allende, a very complex compound chondrule (Allende compound chondrule; ACC) was found consisting of at least 16 subchondrules (14 siblings and 2 independents). Its overall texture can roughly be described as a barred olivine object (BO). The BO texture is similar in all siblings, but does not exist in the two independents, which appear as relatively compact olivine‐rich units. Because of secondary alteration of pristine Allende components and the ACC in particular, only limited predictions can be made concerning the original compositions of the colliding melt droplets. Based on textural and mineralogical characteristics, the siblings must have been formed on a very short time scale in a dense, local environment. This is also supported by oxygen isotope systematics showing similar compositions for all 16 subchondrules. Furthermore, the ACC subchondrules are isotopically distinct from typical Allende chondrules, indicating formation in or reaction with a more ¹⁶O‐poor reservoir. We modeled constraints on the particle density required at the ACC formation location, using textural, mineral‐chemical, and isotopic observations on this multicompound chondrule to define melt droplet collision conditions. In this context, we discuss the possible relationship between the formation of complex chondrules and the formation of macrochondrules and cluster chondrites. While macrochondrules may have formed under similar or related conditions as complex chondrules, cluster chondrites certainly require different formation conditions. Cluster chondrites represent a mixture of viscously deformed, seemingly young chondrules of different chemical and textural types and a population of older chondrules. Concerning the formation of ACC calculations suggest the existence of very local, kilometer‐sized, and super‐dense chondrule‐forming regions with extremely high solid‐to‐gas mass ratios of 1000 or more.