A multi-proxy trophic state reconstruction for shallow Orange Lake, Florida, USA: possible influence of macrophytes on limnetic nutrient concentrations

We retrieved four sediment cores from shallow, eutrophic, macrophyte-dominated Orange Lake (A = 51.4 km2, zmax <5 m, zmean < 2 m), north-central Florida, USA. The 210Pb-dated profiles were used to evaluate spatial and temporal patterns of bulk sediment and nutrient accumulation in the limnetic zone and to infer historical changes in lake trophic state. Bulk density, organic matter, total carbon, total nitrogen, total phosphorus and non-apatite inorganic phosphorus (NAIP) concentrations displayed stratigraphic similarities among three of four cores, as did accumulation rates of bulk sediment, organic matter and nutrients. Accumulation rates were slower at the fourth site. Nutrients showed generally increasing rates of accumulation since the turn of the century. Percentages of periphytic diatom taxa increased progressively in the cores after ~ 1930. Diatom-inferred limnetic total P trends were similar among profiles. Eutrophic conditions were inferred for the period prior to the turn of the century. The lake was hypereutrophic in the early decades of the 1900s, but inferred limnetic total P values declined after ~ 1930. Declining inferred limnetic total P trends for the last 60--70 years were accompanied by concomitant increases in accumulation rates of total P and NAIP on the lake bottom. Several lines of evidence suggest that after ~ 1930, phosphorus entering Orange Lake was increasingly utilized by submersed macrophytes. Paleolimnological records from Orange Lake highlight the importance of using multiple sediment variables to infer past trophic state and suggest that aquatic macrophytes can play a role in regulating water-column nutrient concentrations in shallow, warm-temperate lakes.     

Geochemistry and isotope systematics of calc-alkaline volcanic rocks from the Saar-Nahe basin (SW Germany) – implications for Late-Variscan orogenic development

Late Carboniferous (300–290 Ma) calc-alkaline basalts, andesites, and rhyolites typical of volcanic arc settings occur in the intermontane Saar-Nahe basin (SW Germany) within the Variscan orogenic belt. The volcanic rock suite was emplaced under a regime of tensional tectonics during orogenic collapse and its origin has been explained by melting of mantle and crust in the course of limited lithospheric rifting. We report major, trace and rare-earth-element data (REE), and Nd-Pb-Sr-O isotope ratios for a representative sample suite, which are fully consistent with an origin closely related to plate subduction. Major and trace element data define continuous melt differentiation trends from a precursor basaltic magma involving fractional crystallization of olivine, pyroxene, plagioclase, and magnetite typical of magma evolution in a volcanic arc. This finding precludes an origin of the andesitic compositions by mixing of mafic and felsic melts as can be expected in anorogenic settings. The mafic samples have high Mg numbers (Mg# = 65–73), and high Cr (up to 330 ppm) and Ni (up to 200 ppm) contents indicating derivation from a primitive parental melt that was formed in equilibrium with mantle peridotite. We interpret the geochemical characteristics of the near-primary basalts as reflecting their mantle source. The volcanic rocks are characterized by enrichment in the large ion lithophile elements (LILE), negative Nb and Ti, and positive Pb anomalies relative to the neighboring REE, suggesting melting of a subduction-modified mantle. Initial _Nd values of −0.7 to −4.6, Pb, and ⁸⁷Sr/⁸⁶Sr_(t) isotope ratios for mafic and felsic volcanics are similar and indicate partial melting of an isotopically heterogeneous and enriched mantle reservoir. The enrichment in incompatible trace elements and radiogenic isotopes of a precursor depleted mantle may be attributed to addition of an old sedimentary component. The geochemical characteristics of the Saar-Nahe volcanic rocks are distinct from typical post-collisional rock suites and they may be interpreted as geochemical evidence for ongoing plate subduction at the margin of the Variscan orogenic belt not obvious from the regional geologic context. Received: 3 August 1998 / Accepted: 2 January 1999     

Hydrogeology and geochemistry of near-shore submarine groundwater discharge at Flamengo Bay,Ubatuba, Brazil

Near-shore discharge of fresh groundwater from the fractured granitic rock at Flamengo Bay, Ubatuba, Brazil, is strongly controlled by the local geology. Freshwater flows primarily through a zone of weathered granite to a distance of 24 m offshore. In the nearshore environment this weathered granite is covered by about 0.5 m of well-sorted, coarse sands containing pore water with sea water salinity, with an abrupt transition to much lower salinity once the weathered granite is penetrated. Further offshore, low-permeability marine sediments contain saline porewater, marking the limit of offshore migration of freshwater. Freshwater flux rates based on tidal signal and hydraulic gradient analysis indicate a fresh submarine groundwater discharge of 0.17–1.6 m³/day per m of shoreline. Dissolved inorganic nitrogen and silicate are elevated in the porewater relative to seawater, and appeared to be a net source of nutrients to the overlying water column. The major ion concentrations suggest that the freshwater within the aquifer has a short residence time. Major element concentrations do not reflect in situ alteration of the granitic rocks, possibly because the alteration occurred prior to development of the current discharge zones, or because of large volumes of water discharge in this high rainfall region.     

Exploring Geological and Topographical Controls on Low Flows with Hydrogeological Models

This study investigates how catchment properties influence low-flow dynamics. With 496 synthetic models composed of a bedrock and an alluvial aquifer, we systematically assess the impact of the hydraulic conductivity of both lithologies, of the hillslope and of the river slope on catchment dynamics. The physically based hydrogeological simulator HydroGeoSphere is employed, which allows obtaining a range of low-flow indicators. The hydraulic conductivity of the bedrock K_bedrock, a proxy for transmissivity, is the only catchment property exerting an overall control on low flows and explains 60% of the variance of Q95/Q50. The difference in dynamics of catchments with same K_bedrock depends on hillslope gradients and the alluvial aquifer properties. The buffering capacity of the bedrock is mainly related to K_bedrock and the hillslope gradient. We thus propose the dimensionless bedrock productivity index (BPI) that combines these characteristics with the mean net precipitation. For bedrock only models, the BPI explains 82% of the variance of the ratio of Q95 to mean net precipitation. The alluvial aquifer can significantly influence low flows when the bedrock productivity is limited. Although our synthetic catchment setup is simple, it is far more complex than the available analytical approaches or conceptual hydrological models. The direct application of the results to existing catchments requires nevertheless careful consideration of the local geological topographic and climatic conditions. This study provides quantitative insight into the complex interrelations between geology, topography and low-flow dynamics and challenges previous studies which neglect or oversimplify geological characteristics in the assessment of low flows.     

Origin and evolution of the atmospheres of early Venus,Earth and Mars

We review the origin and evolution of the atmospheres of Earth, Venus and Mars from the time when their accreting bodies were released from the protoplanetary disk a few million years after the origin of the Sun. If the accreting planetary cores reached masses \(\ge 0.5 M_\mathrm{Earth}\) before the gas in the disk disappeared, primordial atmospheres consisting mainly of H\(_2\) form around the young planetary body, contrary to late-stage planet formation, where terrestrial planets accrete material after the nebula phase of the disk. The differences between these two scenarios are explored by investigating non-radiogenic atmospheric noble gas isotope anomalies observed on the three terrestrial planets. The role of the young Sun’s more efficient EUV radiation and of the plasma environment into the escape of early atmospheres is also addressed. We discuss the catastrophic outgassing of volatiles and the formation and cooling of steam atmospheres after the solidification of magma oceans and we describe the geochemical evidence for additional delivery of volatile-rich chondritic materials during the main stages of terrestrial planet formation. The evolution scenario of early Earth is then compared with the atmospheric evolution of planets where no active plate tectonics emerged like on Venus and Mars. We look at the diversity between early Earth, Venus and Mars, which is found to be related to their differing geochemical, geodynamical and geophysical conditions, including plate tectonics, crust and mantle oxidation processes and their involvement in degassing processes of secondary \(\hbox {N}_2\) atmospheres. The buildup of atmospheric \(\hbox {N}_2\), \(\hbox {O}_2\), and the role of greenhouse gases such as \(\hbox {CO}_2\) and \(\hbox {CH}_4\) to counter the Faint Young Sun Paradox (FYSP), when the earliest life forms on Earth originated until the Great Oxidation Event \(\approx \) 2.3 Gyr ago, are addressed. This review concludes with a discussion on the implications of understanding Earth’s geophysical and related atmospheric evolution in relation to the discovery of potential habitable terrestrial exoplanets.     

Resurrecting beach ridge archaeology: Parallel depositional records from St. Lawrence Island and Cape Krusenstern,Western Alaska

Archaeological sites on gravel beach ridge plains offer a treacherously facile method of reconstructing cultural chronology based on the assumption that settlements were preferentially situated nearest the sea. the initial phase of beach ridge methodology in Alaska dates from its 1930s use by Henry Collins at St. Lawrence Island and its 1950s use by Louis Giddings in Kotzebue Sound. Numerous questions of cultural and depositional chronology remain unresolved. At Gambell, on St. Lawrence Island, three sets of ridges span the period since about 2000 B.P., with a prominent disconformity after Punuk culture times at ca. 1100 B.P. Reviewing the ¹⁴C dates (n = 83) we find that the Gambell sequence (n = 50) broadly parallels that of Kotzebue Sound, especially in the similar erosional disconformity at 1200-1000 B.P., related to increased storminess in the North Pacific. the Cape Krusenstern sequence is only loosely constrained by ¹⁴C dates (n = 33) disproportionately concentrated on 7 of the 114 ridge fragments. the dating of early Choris culture is especially problematic, which seems to occur both before and after the Old Whaling culture, well-dated at 2900-2800 B.P. on the 53rd ridge. However, reanalyzing the depositional sequence, we find that some of the more easterly Choris ridges probably represent erosional events after the Old Whaling occupation.